Mcculloughhubbard7916

Cross-treatment experiments using one type of AS to treat the other two kinds of wastewater were conducted. The results of the cross-treatment experiments and qPCR both suggest the functional adaptation of the microbial community. We revealed selection strategies for the adaptation of bacteria and archaea in AS during environmental changes, providing a theoretical basis for petrochemical wastewater treatment.The mechanism of surfactants in surfactant-in situ chemical oxidation (S-ISCO) coupled process for trichloroethene (TCE) degradation was firstly reported. The performance of TCE solubilization and inhibition of TCE degradation in three nonionic surfactants (TW-80, Brij-35, TX-100) in PS/Fe(II)/citric acid (CA) system was compared and TW-80 was evaluated to be the optimal surfactant in S-ISCO coupled process due to the best TCE solubilizing ability and minimal inhibition for TCE degradation (only 31.8% TCE inhibition in the presence of 1 g L-1 TW-80 surfactant). The inhibition mechanism in TCE degradation was also demonstrated by comparing the strength of ROSs and PS utilization. In the presence of TW-80 (1 g L-1), over 97.5% TCE was removed at the PS/Fe(II)/CA/TCE molar ratio of 30/4/4/1, in which more than 86.7% TCE was dechlorinated. The result of scavenger experiments revealed that the dominant radicals were HO• and SO4-• in PS/Fe(II)/CA system in TW-80 containing aqueous solution, among which SO4-• performed a greater role in TCE removal. Moreover, over 85.3% TCE degradation in actual groundwater revealed the potential of PS/Fe(II)/CA process for actual groundwater remediation in containing TW-80 of TCE contaminant. This research provided a novel alternative technology for groundwater remediation with TCE contaminant when containing surfactants.Carbonyl sulfide (COS), the organic sulfur generated in the chemical industry, has been receiving more attention due to its environmental and economic influence. In this study N-doped MgAl-LDO catalyst was successfully prepared and tested for the COS hydrolysis reaction at low temperature, it was observed that the N species can be formed both in surface and bulk. Moreover, the basicity property and the H2O adsorption-desorption property were remarkably improved due to the N-doping. Besides, the hydroxyl group can be formed more easily and more abundantly on N modified catalyst surface, which was beneficial to the COS adsorption and the remarkable improvement of catalytic performance. The catalytic hydrolysis performance can proceed for almost 1440 min without any deactivation at 70 °C. However, further increase of temperature was not beneficial to improve the catalytic performance due to the occurrence of H2S oxidation side reaction. Furthermore, it was revealed that the surface hydroxyl groups were responsible for the adsorption of COS and then the formed surface transitional species reacted with the H2O molecules. Trametinib cell line Hydrogen thiocarbonate and bicarbonate were the main reaction intermediate. The rate-determining step was IM6→IM7 i.e., a type transformation of bicarbonate.In recent decades, harmful algal blooms (HABs) induced by eutrophication have caused organisms in freshwater ecosystems to become surrounded by toxic cells and dissolved toxins. In this study, the toxic effects of fresh algae solution (FAS) and rotten algae solution (RAS) were investigated. The results showed that the composition of RAS was predominantly organic acids, ketones, polypeptides, esters, phenols, amino acids and intermediate metabolic products. The safety concentrations (SCs) of FAS to Carassius auratus, Ctenopharyngodon idellus and Hypophthalmichthys molitrix were 1.92 × 1010 cells/L, 1.58 × 1011 cells/L and 1.30 × 1011 cells/L, respectively. The SCs of the RAS were significantly lower than those of the FAS (p less then 0.05), with the values of 1.25 × 109 cells/L, 8.8 × 109 cells/L and 9.7 × 109 cells/L, for each species, respectively. The toxic algae solutions caused congestion inside the gills, intestinal lesions and high infection rates in the tested fish. FAS and RAS exposure also activated the antioxidant defense system and changed the intestinal microbial structure, resulting in the damage to the microbial balance in the body, and eventually the death of the fish. By studying the acute toxicity to fish, the harm of HABs to aquatic organisms can be predicted.Micropollutants such as pharmaceuticals and pesticides are still found in treated municipal effluent and are discharged into the natural environment. Natural direct photodegradation may be one pathway for removing these micropollutants in treatment processes such as free-water surface constructed wetlands (CW). This work was set out to evaluate the half-life (t1/2) of direct photodegradation of 36 micropollutants under controlled conditions of light exposure close to solar radiation. The results allowed to classify the micropollutants into three groups (fast, medium and slow). Seven micropollutants were classified in the fast group with t1/2 between 0.05 h and 0.79 h, 24 in the medium group with t1/2 between 5.3 h and 49.7 h, and five in the slow group with t1/2 between 56 h and 118 h. The t1/2 values obtained in laboratory were compared with those from a CW receiving treated wastewater. Correction factors were calculated to adjust the in situ data for the light intensity in laboratory and improved the correspondence especially for the micropollutants of the fast and medium groups. Finally, an innovative method based on statistical tests highlighted the chemical functions characteristic of micropollutants sensitive to photodegradation (OH-C˭O, C˭N-O-, =N-OH, -CH=N, -O-P˭O, -C˭C-) and with low sensitivity (-O-R, -Cl).Nitrated aromatic compounds (NACs) are toxic and allergenic airborne pollutants from both primary emissions and atmospheric reactions of aromatics with NO2. A comprehensive investigation of NACs is challenging given their low ambient levels. By applying gas chromatography and tandem mass spectrometry coupled with an electron capture negative ionization source, this study achieved a comprehensive high-throughput and standard-independent detection of nonpolar NACs in fine particulate matter (PM2.5) sampled over 2 years in Beijing, China. Overall, 1047 NACs were detected, among which, the elemental composition of 128 species were derived using time-of-flight mass spectrometry, and 25 species were confirmed using reference standards. In addition to mono-nitrated polycyclic aromatic hydrocarbons (NPAHs), di-nitrated PAHs and alkylated and oxygenated NPAHs were found. Cluster analysis suggested these compounds were derived from various sources particularly atmospheric reactions. We found that the annual levels of primary NPAHs decreased by 46.