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As the individual's forgiveness increases, their emotional reactivity decreases, and as the emotional reactivity decreases, the individual's level of happiness increases.The current study investigated whether and how each component of the working memory model was associated with kindergarten children's arithmetic performance. A total of 103 Chinese kindergarten children were administered tests of the visuospatial sketchpad, the phonological loop, the central executive, and basic number processing (i.e., number line estimation, nonverbal numerosity estimation and numerical magnitude comparison). The results showed that among the three working memory components, the central executive accounted for a significant proportion of the variance in young children's arithmetic performance. In terms of basic number processing, number line estimation and numerical magnitude comparison had significant influences on young children's arithmetic performance. Furthermore, numerical magnitude comparison played a mediating role between the visuospatial sketchpad and early arithmetic skills. These findings highlight the importance of working memory and basic number processing in early arithmetic skills and reveal different pathways through which the three working memory components influence young children's arithmetic performance.School climate consistently relates to adolescent adjustment across academic, socioemotional, and behavioral domains. Although past research highlights the impact of school climate on youths' experience of internalizing symptoms and violent behavior, examination of potential links with specific externalizing processes is limited. The current study examined associations between middle school students' perceived school climate and internalizing and externalizing mental health symptoms. A positive school climate was hypothesized to be inversely related to all mental health measures. Seventh grade students (N = 2768; 50% female) were recruited from 24 Texas middle schools. Participants completed baseline self-reports of perceived school climate across three dimensions (student-student relationships, student-teacher relationships, and awareness/need of reporting violence) as well as self-reports of internalizing (i.e., depression and anxiety) and externalizing (i.e., impulsivity and hostility) symptoms. Multilevel regression analyses were implemented to test all hypotheses, controlling for participant sex and race/ethnicity. Results indicated student-student relationships were negatively related to depressive symptoms, student-teacher relationships were positively related to anxiety and negatively linked to hostility, and help-seeking/reporting awareness was inversely related to all four indices of mental health. The current research underscores the impact of school climate on adolescents' psychological adjustment and emphasizes the need to address awareness and responsivity in reporting concerning school behavior.Distance education programs have become the preferred option for most higher education institutions to continue teaching during the COVID-19 pandemic, but the effectiveness of some online courses, especially those engineering courses with experimentation activities, remains disputed. The main challenge is fostering collaborative problem solving skills for novice students as online collaboration increases their cognitive load. This research thus tapped into novice engineering students' cognitive load to develop a more granular, multimodal view of how cognitive load influences student performance in collaborative problem solving during virtual experimentation activities. The findings of this research provided significant implications for the future design and implementation of virtual laboratories in computer science engineering education.Synthesis of several N-oxides with tungsten exchanged hydroxyapatite (W/HAP) in the presence of 30% hydrogen peroxide (H2O2) as an oxidant is presented. A process with aqueous H2O2, a cheap and clean oxidant with an active catalyst is developed to reduce waste production and meet the requirements of green chemistry. Several tertiary amines have been efficiently oxidized to their corresponding N-oxides with excellent yields. The as-synthesized catalyst (W/HAP) is characterized using BET, FTIR, SEM, ICP-OES and XRD. Effect of catalyst loading , temperature and oxidants were studied. A kinetic model has been developed to determine the reaction rate at different temperatures and activation energy for the model reaction.

Synthesis of several

-oxides using tungsten exchanged hydroxyapatite (W/HAP) in the presence of 30% hydrogen peroxide (H

O

) as an oxidant is presented. A process with aqueous H

O

, a cheap and clean oxidant with an active catalyst is developed to reduce waste production and meet the requirements of green chemistry.

The online version contains supplementary material available at 10.1007/s12039-022-02038-0.

The online version contains supplementary material available at 10.1007/s12039-022-02038-0.Crop diversification provides an opportunity for farmers to maximize their profits, fulfilling multiple needs, avoid monsoon threats, and make the crop production system sustainable. Inclusion of various pulse/oilseed/vegetables/cereals/medicinal/aromatic crops with sugarcane brings forth cultivation of these crops in irrigated agro-system and improves the yields of component crops. Besides, the component crops improve soil fertility and create a favorable environment for the further growth of sugarcane crops. Sprouting in winter-initiated sugarcane ratoon could be enhanced by adopting fodder legumes such as Indian clover and Egyptian clover. Intercropping vegetables provides an ample opportunity for mid-season income generation and improves profitability. Besides, high-value medicinal and aromatic crops such as tulsi (holy basil), mentha could also be included in the sugarcane-based system. Crop residue management has been recognized as a critical issue in managing the crops in the various cropping systems. s intercrops with spring-planted cane increase the pool of soil microbial biomass nitrogen capitalize allelopathic effects and sustain soil health. In the present paper, these issues have been discussed. Due to the adoption of location-specific and farmers-centric systems, farmers' profitability could be increased, providing sustainability to the sugarcane-based systems.Thrombotic complications following balloon atrial septostomy (BAS) are unusual. We report a patient with thrombus formation at the site of BAS, extending into the inferior vena cava (IVC), following BAS for transposition of great arteries with intact ventricular septum (TGA-IVS). An urgent arterial switch operation (ASO) with removal of the thrombus was performed.

The online version contains supplementary material available at 10.1007/s12055-022-01331-4.

The online version contains supplementary material available at 10.1007/s12055-022-01331-4.About a third of all marine fish in the world are caught in Small-Scale Fisheries (SSF). selleck chemicals SSF are increasingly recognised as essential for food security and livelihoods for vulnerable and economically fragile communities globally. Although individual SSF vessels are usually perceived as having little impact on the ecosystem, the cumulative impact of gear type and number of vessels may be substantial. Bottom trawling is a common fishing method that can greatly influence the marine ecosystem by damaging the seafloor and generating high levels of discards. However, appropriate sampling coverage using on-board observer programmes to collect these data from SSF are rare, as they are expensive and pose logistical constraints. A mobile App was used to assess whether self-reporting by fishers could provide reliable fine-scale information on fishing effort and discards over time in an illegal shrimp trawling fishery in northern Peru. Maps depicting the spatial distribution of trawling effort and the proportion of discards from observers and fishers were compared using the Similarity in Means (SIM) Index, which ranges from 0 when spatial patterns differ completely to 1 when spatial patterns are very similar. High levels of agreement between spatio-temporal patterns of effort (SIM Index = 0.81) and discards (0.96) were found between fisher and observer maps. Moreover, far greater spatial coverage was accomplished by fishers, suggesting that self-reporting via an App represents a useful approach to collect reliable fisheries data as an initial step for effective monitoring and management of these fisheries.

The online version contains supplementary material available at 10.1007/s11160-022-09708-9.

The online version contains supplementary material available at 10.1007/s11160-022-09708-9.The lack of medical treatments and vaccines upon the arrival of the SARS-CoV-2 virus has made non-pharmaceutical interventions the best allies in safeguarding human lives in the face of the COVID-19 pandemic. Here we propose a self-organized epidemic model with multi-scale control policies that are relaxed or strengthened depending on the extent of the epidemic outbreak. We show that optimizing the balance between the effects of epidemic control and the associated socio-economic cost is strongly linked to the stringency of control measures. We also show that non-pharmaceutical interventions acting at different spatial scales, from creating social bubbles at the household level to constraining mobility between different cities, are strongly interrelated. We find that policy functionality changes for better or worse depending on network connectivity, meaning that some populations may allow for less restrictive measures than others if both have the same resources to respond to the evolving epidemic.In its revised bioeconomy strategy, the European Union (EU) has extended the scope of activities to include services. Employing an output-based approach, this study quantifies the contribution of bioeconomy services to gross domestic product and employment in the EU Member States over 2008-2017. Moreover, it also identifies the main sectoral sources of employment and growth within bioeconomy services. The choice of Eurostat statistics ensures data harmonisation across countries and continuity for future updates, although important data needs are identified to enhance the representation of bioeconomy services within European statistical frameworks. In 2015-2017, economic growth was stronger in bioeconomy services than in the total EU economy. Bioeconomy services accounted for between 5.0-8.6% and 10.2-16.9% of EU gross domestic product and the EU labour force, respectively, whilst three service sectors account for more than 60% of bioeconomy services employment and value added. Interestingly, in the decade up to 2017, labour productivity in bioeconomy services improved.Can the pandemic measures be used to advance particular political means? The question of correlation between illiberal legal changes adopted amongst the wave of legislation focused on battling COVID has arisen in a number of countries around the world; as an increasing number of states finds leaving restrictions behind in 2022, however, Hong Kong is still battling the Omicron wave of the pandemic. Ever since its transition to China in 1997, Hong Kong has retained its place on the world stage as an international business hub and, while getting closer to the Mainland, enjoyed the freedoms provided by its SAR status. At the same time, by the end of the second decade of the twenty-first century the tensions between the pro-democratic inclinations of the large part of the city's population and pro-Mainland disposition of the SAR's political elite began to rise, with proposals of various legal acts put forward by the local government often perceived as encroaching freedoms. The street-level 'standoff' between the authorities and the people was brought to a halt by the COVID-19 pandemic; and, with protesting rendered virtually impossible, a number of controversial legal changes were introduced by the government taking advantage of the situation, which, together with the anti-pandemic measures have continued to negatively impact the city's financial hub status.