Hendriksenhermansen4465

Plastic crystals (PCs), formed by certain types of molecules or ions with reorientational freedom, offer both exceptional mechanical plasticity and long range order, hence they are attractive for many mechano-adaptable technologies. While most classic PCs belong to simple globular molecular systems, a vast number of examples in the literature with diverse geometrical (cylindrical, bent, disk, etc.) and chemical (neutral, ionic, etc.) natures have proven their wide scope and opportunities. All the recent reviews on PCs aim to provide insights into a particular application, for instance, organic plastic crystal electrolytes or ferroelectrics. This tutorial review presents a holistic view of PCs by unifying the recent excellent progress in fundamental concepts from diverse areas as well as comparing them with liquid crystals, amphidynamic crystals, ordered crystals, etc. We cover the molecular and structural origins of the unique characteristics of PCs, such as exceptional plasticity, facile reversible switching of order-to-disorder states and associated colossal heat changes, and diffusion of ions/molecules, and their attractive applications in solid electrolytes, opto-electronics, ferroeletrics, piezoelectrics, pyroelectrics, barocalorics, magnetics, nonlinear optics, and so on. The recent progress not only demonstrates the diversity of scientific areas in which PCs are gaining attention but also the opportunities one can exploit using a crystal engineering approach, for example, the design of novel dynamic functional soft materials for future use in flexible devices or soft-robotic machines.A series of RuII (1), RhIII (2), IrIII (3, 4), IrI (5) and PdII (6-9) complexes of the 'instant carbene' nitron were prepared and characterized by 1H- and 13C-NMR, FT-IR and elemental analysis. The molecular structures of complexes 1-4 and 6 were determined by X-ray diffraction studies. The catalytic activity of the complexes (1-9) was evaluated in alpha(α)-alkylation reactions of ketones with alcohol via the borrowing hydrogen strategy under mild conditions. These complexes were able to perform this catalytic transformation in a short time with low catalyst and base amounts under an air atmosphere. Also, the PdII-nitron complexes (6-9) were applied in the Suzuki-Miyaura C-C coupling reaction and these complexes successfully initiated this reaction in a short time (30 minutes) using the H2O/2-propanol (1.5  0.5) solvent system. The DFT calculations revealed that the Pd0/II/0 pathway was more preferable for the mechanism.As a metabolic disease, gout, which seriously affects the normal life of patients, has become increasingly common in modern society. However, the existing medicines cannot completely meet the clinical needs. In the current study, a novel short peptide (named rice-derived-peptide-2 (RDP2), AAAAGAMPK-NH2, 785.97 Da) was isolated and identified from water extract of shelled Oryza sativa fruits, without toxic side effects but excellent stability. Our results indicated that RDP2 (the minimum effective concentration is 5 μg kg-1) induced a significant reduction in serum uric acid levels in hyperuricemic mice via suppressing xanthine oxidase activity and urate transporter 1 expression, as well as alleviated renal damage through inhibiting the activation of NLRP3 inflammasome. In addition, RDP2 can also alleviate paw swelling and inflammatory reactions in mice after subcutaneous injection of monosodium urate crystals. As mentioned above, we obtained a novel peptide which could work through all stages of gout, not only reducing uric acid levels and renal damage in hyperuricemic mice, but also alleviating inflammatory responses associated with acute gout attack, and thus provided a new peptide molecular template for the development of anti-gout drugs.A two-dimensional Dirac half-metal system, in which the 100% spin polarization and massless Dirac fermions can coexist, will show more advantages on the efficient spin injection and high spin mobility in spintronic devices. Moreover, it is attractive to achieve out-of-plane electric polarization in addition to the Dirac half-metal behavior, because this will open a new horizon in the field of multifunctional devices. In this work, a systematic study is made of Janus monolayers of Mn2X3Y3 (X, Y = Cl, Br and I, X ≠ Y) with asymmetric out-of-plane structural configurations, based on first-principles calculations. We demonstrate that monolayer Mn2X3Y3 freestanding films will remain stable experimentally by using the stability analysis. All the Janus monolayers show a ferromagnetic ground state and maintain their original DHM behavior. However, due to the large electric polarization, the hybridization intensities of Mn and the halogen atoms on both sides of Mn2Cl3I3 are very different, resulting in an obvious distortion of the spin-polarized Dirac cone. The distorted Dirac cone is repaired by the compression, indicating that strain can improve the orbital distortion induced by the electric polarization. All Mn2X3Y3 monolayer have in-plane magnetization anisotropy, which is mainly contributed by heavy halogen elements (Br and I), and the polarized substitution and biaxial strain will not change the easy magnetization orientation of the system. Thus, the electrically polarized Dirac half-metal system has potential for application in multifunctional spintronic devices.From an environmental perspective, silver recovery through a green process is imperative. In this work, a green supramolecular separation process of Ag has been developed by using a highly charged anionic Ti4L6 (L = embonate) cage as the extractant. SLx-2119 Such a Ti4L6 cage has unique selectivity toward [Ag(NH3)2]+ ions, because only linear [Ag(NH3)2]+ ions can be trapped into the windows of the Ti4L6 cage, which is demonstrated by single-crystal X-ray diffraction analysis. To further illustrate the efficiency and mechanism of the herein constructed silver separation method, three co-crystals of the Ti4L6 cage with various [Ag(NH3)2]+ ions were prepared and structurally characterized, annotating the stepwise recognition of [Ag(NH3)2]+ ions by the Ti4L6 extractant. However, it failed to trap larger tetrahedral [Zn(NH3)4]2+ and quadrilateral [Pb(NH3)4]2+ ions under the same reaction conditions, indicating that configuration matching contributes to the high selectivity of the above-mentioned silver separation procedure.