Doganmcclure5064

The glass system SiO2-B2O3-Na2O3-ZnO containing 2 wt% CdS and 1 wt% ZnS was synthesized by the conventional melt quench method. Glass transition temperature and crystallization temperature was determined from Differential thermal analysis (DTA) measurement to optimize heat-treatment. The amorphous structure of the glass was confirmed by the X-ray diffraction (XRD) measurement. Glasses were heat-treated by optimized heat-treatment schedule to grow CdS/ZnS QDs and crystalline phases of CdS and ZnS were confirmed by the XRD measurement. High-Resolution Transmission Electron Microscopy (HRTEM) was used to determine the size and shape of quantum dots (QDs) grown in the glass matrix. The optical band gap was calculated from the absorption spectra and found to decrease with increase in size of QDs. Electron-hole recombination rate was studied using a decay time and impedance analyzer. Prepared samples were tested as a photocatalyst under sunlight for the degradation of indigo carmine (IC) dye and photodegradation efficiency was found to be 73.6 % and 87.2 % for samples CZ1 and CZ4 respectively. No significant change is observed in degradation efficiency even for 4 cycles which confirms the stability of prepared glasses for dye degradation.Nowadays, ethanol (ethyl alcohol, bioethanol) is one of the most commonly used liquid biofuels, playing a vital role in industrial development. There are some advanced technologies available to produce ethanol by fermentation of agricultural wastes, fruit wastes, municipal and industrial wastes. Herein, the dried carrot pulp as a source of raw material has been utilized for the production of bioethanol by using the yeast Saccharomyces cerevisiae and beet molasses inoculated at 28 °C for 72 h. The results have revealed that the highest amount of alcohol (10.3 ml (40.63 g/l)) has been obtained in a sample containing 50 ml of inoculum, 150 ml of water, and 10 g of dried waste. This study has proved the potential of dried carrot pulp to be converted into a value-added product such as ethanol.One of the primary drivers of Phosphorus (P) limitation in aquatic systems is P adsorption to sediments. Sediments adsorb more P in freshwater compared to other natural solutions, but the mechanism driving this difference is poorly understood. To provide insights into the mechanism, we conducted batch experiments of P adsorption to calcite in freshwater and seawater, and used computer software to develop complexation models. Our simulations revealed three main reasons that, combining together, may explain the greater P adsorption to calcite in freshwater vs. seawater. First, aqueous speciation of P makes a difference. The ion pair CaPO4- is much more abundant in freshwater; although seawater has more Ca2+ ions, MgHPO40 and NaHPO40 are more thermodynamically favored. Second, the adsorbing species of P make a difference. The ion pair CaPO4- (the preferred adsorbate in freshwater) is able to access adsorption sites that are not available to HPO42- (the preferred adsorbate in seawater), thereby raising the maximum concentration of P that can adsorb to the calcite surface in freshwater. Third, water chemistry affects the competition among ions for surface sites. Other ions (including P) compete more effectively against CO32- when immersed in freshwater vs. seawater, even when the concentration of HCO3-/CO32- is higher in freshwater vs. seawater. In addition, we found that under oligotrophic conditions, P adsorption is driven by the higher energy adsorption sites, and by the lower energy sites in eutrophic conditions. This study is the first to model P adsorption mechanisms to calcite in freshwater and seawater.The chemical changes caused by electron beam and γ irradiations and the biochemical characteristics of degradation products of a frequently used antibiotic oxacillin were investigated and compared with those of cloxacillin by applying pulse radiolysis, chemical and biochemical oxygen demand, total organic carbon content, oxygen uptake rate, toxicity and antibacterial activity measurements. Oxacillin was found to be non-toxic, but poorly biodegradable by the mixed microbial population of the activated sludge of a wastewater treatment plant. Therefore, it can significantly contribute to the spread of β-lactam antibiotic resistant bacteria. However, the products formed by γ-irradiation were more easily biodegradable as they were utilized as nutrient source by the microbes of the activated sludge and the products did not show antibacterial activity. During irradiation treatment of aerated aqueous solutions mainly hydroxyl radicals induce the elimination of antimicrobial activity by making alterations at the bicyclic β-lactam part of these antibiotics. Since the β-lactam part is the same in oxacillin and cloxacillin, the biochemical characteristics of products of the two antibiotics are similar. The attack of hydrated electron takes place on the carbonyl groups. When the irradiation is made under anoxic conditions these reactions may also contribute considerably to alterations at the β-lactam part and thereby to the loss of antibacterial activity.The establishment of vegetation cover is an important strategy to reduce wind and water erosion at metal smelting waste slag sites. However, the mobility of heavy metals in waste slag-vegetation-leachate systems after the application of revegetation strategies is still unclear. Large microcosm experiments were conducted for revegetation of waste slag for 98 d using combined amendments, i.e., phosphate rock and an organic waste coming from the anaerobic digestion of pig manure (named as biogas residue), and by single- and co-planted perennial ryegrass (Lolium perenne L.) and Trifolium repens (T. repens). The results showed that the application of biogas residue slightly increased the concentrations of Zn and Cd in the leachates; however, the establishment of plants could avoid the excessive leaching of heavy metals coming from the biogas residue. The bioavailability of Cu, Zn, and Cd slightly increased, but Pb bioavailability significantly decreased regardless of single- or co-planting patterns. Additionally, the bioavailability of Cu, Zn, and Cd in the waste slag revegetated with perennial ryegrass was lower than that in T. repens under the single-planting pattern. The change in the heavy metals bioavailability under different revegetation strategies was mainly due to the root-induced change in the pH and speciation of heavy metals in the waste slag. The application of biogas residue and phosphate rock tends to the immobilization of Pb. Heavy metals mainly accumulated in the underground parts of the two herbs, and the heavy metal contents in the underground parts of perennial ryegrass were higher than those in T. repens regardless of single- or co-planting patterns. The heavy metals accumulated in T. repens were lower than those in perennial ryegrass in the single-planting pattern. The bioaccumulation and transportation factors of the two herbs were extremely low. Thus, the two herbs are potential candidates for phytostabilization of zinc smelting waste slag sites.The heavy metal accumulated biomass after phytoremediation needs to be decontaminated before disposal. Liquid extraction is commonly used to remove and recycle toxic heavy metals from contaminated biomass. In this study, we examined the cadmium (Cd) removal efficiency using different chemical reagents (hydrochloric acid, nitric acid, sulfuric acid, and ethylenediaminetetraacetic acid disodium) of the post-harvest Amaranthus hypochondriacus L. biomass. The purifications for the extracted liquids and ecological risk assessments for the extracted residues were also investigated. We have found that 77.8% of Cd in stems and 62.1% of Cd in leaves were removed by 0.25 M HCl after 24 h. In addition, K2CO3, KOH, and 4 Å molecular sieve could remove ≥89.0% of Cd in the extracted liquids. Finally, after we returned the extracted residues to the earthworm-incubated soil, the extracted biomass negatively affected the growth (weight loss ≥ 11.0%) and survival (mortality ≥ 33.3%) of Eisenia fetida. It should be noted that earthworms decreased soil available Cd concentrations from 0.14-0.05 mg kg-1 to 0.11-0.04 mg kg-1 and offset the negative effects of the Cd-contaminated biomass on soil microbes. Overall, given the cost of reagents, the Cd removal efficiency, and the ecological risks of the extracted biomass, using 0.25 M HCl for liquid extraction and K2CO3 for purification should be recommended. This work highlights the potential of liquid extraction for immediately and directly removing the Cd from fresh contaminated accumulator biomass and the resource cycling potential of the extracted liquids and biomass after purification.Due to the use of di-isobutyl-phthalate (DiBP) in the production of soft-polyvinyl chloride articles, it is currently a hazardous substance prevalent in human daily life. However, reports on DiBP's toxicokinetics are still very scarce. And no studies have been reported on gender differences in DiBP toxicokinetics. Therefore, this study was conducted in accordance with these research needs. DiBP of 100 mg/kg has been exposed to male and female rats single or multiple times. DiBP and its major metabolite, mono-isobutyl-phthalate (MiBP), were quantified from various biological samples obtained from rats administered with DiBP. Based on these results, several toxicokinetic parameters were estimated. Toxicokinetic results between genders were compared, and from this, existence and extent of gender differences in DiBP's toxicokinetics were explored. Investigation of presence and extent of subacute toxicity in male and female rats following multiple exposures to DiBP were also conducted. BTK inhibitor This study provided comprehensive information on DiBP toxicity and gender differences that have not been reported in detail. Results of these studies imply that subacute toxicity in liver, kidney, lung, and testis of rats at 100 mg/kg of DiBP is modest and that there is little difference in toxicokinetics between genders. And in both male and female rats, the metabolism of DiBP (to MiBP) was significant, and excretion of MiBP into urine was a major indicator of DiBP exposure.The situation of imbalance application of nitrogenous fertilizers in maize production is a serious issue in China, and excessive nitrogen (N) application is hazardous to sustainable agricultural production and environment. In this experiment, two biochar levels (C0 0, C1 2 %), three different N rates (N1 50, N2 100, and N3 200 mg kg-1), and two fertilization methods (T traditional N fertilizer application mode and D deep N fertilizer placement mode) were set up to study the response of different treatments on maize yield, N uptake, and N use efficiency. Herein, we found that fresh and dry biomasses were increased by 292 % and 283 % under C1N3 treatment with the deep application of N fertilizer compared to the control treatment (without nitrogen fertilizers and biochar). According to structural equation modeling (SEM), soil physical and chemical properties, N component and C component in different soil layers were associated with biochar and N fertilizer treatment, especially at 20-40 depth. The combination of N fertilizer and biochar application promoted the effects of biochar on the improving NUE of plants.