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It remains unclear whether excessive nitrogen additions lead to the degradation of Suaeda salsa (S. salsa) by affecting the nitrogen pool, enzyme activities, and bacterial community structure of wetland soils. This study investigated the effect of five added nitrogen concentrations (0, 1, 2, 4, and 6 mmol L-1 N with NH4NO3 = group C, group L, group M, group H, and group G, respectively) on nitrogen uptake by S. salsa and nitrogen transformation in the wetland soils of the Liaohe estuary. The height, weight, and total nitrogen (TN) of S. salsa in group G was significantly lower than in the other groups (p less then 0.05). The NH4+-N concentration in the soil tended to increase with increasing nitrogen addition, but the TN concentration in the soil tended to decrease. The nitrogenase, protease, urease, ammonia monooxygenase (AMO), nitrous oxide reductase (NOR), and dehydrogenase (DHA) activities increased with increasing nitrogen addition within the range of 0 to 4 mmol L-1. We identified 30 phyla and 48 known genera across all five groups. The predominant phyla were Proteobacteria (52.68%), Bacteroidetes (22.58%), and Planctomycetes (3.94%). The most abundant genus was Acinetobacter (13.38%), followed by Proteiniphilum (11.88%) and Brevundimonas (6.03%). The total number of soil bacterial species increased with increasing nitrogen addition. Group G had lower soil bacterial activity and diversity than the other groups. It was concluded that appropriate levels of nitrogen addition could promote nitrogen uptake by S. salsa and nitrogen transformation in the wetland soils of the Liaohe estuary by affecting soil enzyme activities and soil bacterial activity, diversity, abundance, and composition, while excessive nitrogen additions may be one of the reasons for the degradation of S. salsa.The number of daily commuters in Greater Cairo has exceeded 15 million nevertheless personal exposure studies in transport microenvironments are limited. The aim of this study is to quantify PM2.5 exposure during peak hours in four transport modes of Greater Cairo - car (windows-open, windows-closed with recirculation and AC-on), microbus (windows-open), cycling and walking - and understand its underlying drivers. Data was collected using a pDR-1500 monitor and analysed to capture concentration variations, spatial variability, exposure doses, commuting costs versus inhaled doses, health burden and economic losses. Car with recirculation resulted in the least average PM2.5 concentrations (32 ± 6 μg/m3), followed by walking (77 ± 35 μg/m3), car with windows-open (82 ± 32 μg/m3), microbus with windows-open (96 ± 29 μg/m3) and cycling (100 ± 28 μg/m3). Evening hours observed average PM2.5 concentrations by 26-58% lesser than morning. Spatial variability analysis showed that 75th-90th percentile PM2.5 concentratioion-making and better urban planning.Contaminants in groundwater are a major issue worldwide. Temporal trends of such occurrences in French groundwaters were evaluated for several active substances of pesticides belonging to different chemical classes, to identify key factors explaining groundwater contamination. Our study relied on exploitation of a French national database (ADES, created in the mid-1990s and remarkable for the available data, including over 88 million analyses). Temporal changes in the frequency of exceeding a reference value of 0.1 μg/L for several substances were determined at yearly and monthly scales. Such trends were examined by distinguishing different periods according to changes in regulations (new approval, withdrawal, or dose reduction), and were combined with data on effective rainfall as a proxy for groundwater recharge, on aquifer lithology, and on sales of active substances as a proxy for actual applications. A review of monthly data shows that a rapid transfer of pesticides with contrasting physico-chemical properties can occur after application in many aquifers, regardless of their lithology. For substances such as metolachlor, showing a sharp increase in sales, a clear relationship exists between quantities sold and frequency of exceeding the reference value. For other active substances, such as isoproturon or chlortoluron, frequencies of exceedance are governed by both sales and effective rainfall. Finally, the occurrence of active substances in groundwater several years after their withdrawal from the market is explained by at least three major mechanisms the transfer time from soil into groundwater, processes of remobilization from soil and/or unsaturated zone, and no or low degradation in the saturated zone. While these processes are well documented for atrazine and different types of aquifers, they can be virtually unknown for other active substances.The objective of this study was to evaluate the spatiotemporal dynamics of large area mangrove deforestation, aquaculture pond building, and the subsequent abandonment of ponds in a large delta in Indonesia, namely the Mahakam Delta. So, we developed and applied a novel methodology for exploring the lifespan of aquaculture ponds. Using historical multispectral and radar data, the lifespans of aquaculture ponds across the delta were estimated via a chronological analysis of the landscape into four different states primary mangroves → deforested mangroves → ponds → abandoned/inactive ponds. Specifically, a combination of sequential classification and rule-based techniques were used to 1) produce a time series of land cover maps from 1994 to 2015 and 2) quantify lifespans of aquaculture ponds in the delta. Results show that of the 110,000 ha of primary mangrove forests in the delta in 1994, 62% had been deforested by 2015, with a 4.5% annual rate of loss on average. The lifespan of aquaculture ponds in the delta varied between 1 and 22+ years, with most of the ponds having productive lifespans of 10 to 13 years. Ponds with relatively longer lifespans were located near the existing settlements in the delta. This study showed that the productive lifespan of most aquaculture ponds in deforested mangrove lands of Mahakam delta is relatively short, information that should be useful for developing appropriate management plans for the delta or similar coastal mangrove ecosystems. The abandoned ponds can potentially be rehabilitated for shrimp and fish production after applying appropriate restorative treatments or be targeted for mangrove restoration projects.Per- and polyfluoroalkyl substances (PFAS) are ubiquitous in landfill leachate due to their widespread applications in various industrial and consumer products. Yet, there has been no cost-effective technology available for treating PFAS in leachate because of the intrinsic persistency of PFAS and the high matrix strength of landfill leachate. We tested a two-step 'Concentrate-&-Destroy' technology for treating over 14 PFAS from a model landfill leachate through bench- and pilot-scale experiments. learn more The technology was based on an adsorptive photocatalyst (Fe/TNTs@AC), which was able to selectively adsorb PFAS despite the strong matrix effect of the leachate. Moreover, the pre-concentrated PFAS on Fe/TNTs@AC were effectively degraded under UV, which also regenerates the material. The presence of 0.5 M H2O2 during the photocatalytic degradation enhanced the solid-phase destruction of the PFAS. Fresh Fe/TNTs@AC at a dosage of 10 g/L removed >95% of 13 PFAS from the leachate, 86% after first regeneration, and 74% when reused three times. Fe/TNTs@AC was less effective for PFBA and PFPeA partially due to the transformation of precursors and/or longer-chain homologues into these short-chain PFAS. Pilot-scale tests preliminarily confirmed the bench-scale results. Despite the strong interference from additional suspended solids, Fe/TNTs@AC removed >92% of 18 PFAS in 8 h under the field conditions, and when the PFAS-laden solids were subjected to the UV-H2O2 system, ~84% of 16 PFAS in the solid phase were degraded. The 'Concentrate-&-Destroy' strategy appears promising for more cost-effective removal and degradation of PFAS in landfill leachate or PFAS-laden high-strength wastewaters.Investigation of transformation products from novel flame retardants emitted throughout their life cycles is crucial for understanding and predicting environmental and human health risks posed by them during the material and product life cycle. Here, to understand more about the emission of TDBP-TAZTO to the environment, we investigated the presence of novel brominated triazine-based flame retardant 1,3,5-tris-(2,3-dibromopropyl)-1,3,5-triazine-2,4,6-trione (TDBP-TAZTO) and its transformation products in the effluent from a facility manufacturing fire-retarded textiles, and in the influent, effluent, and sludge of its closest downstream sewage treatment plant. To acquire mass spectra data of the transformation products in the influent, effluent, and sludge, non-target analysis was carried out by electrospray ionization-quadrupole time-of-flight-high-resolution mass spectrometry with liquid chromatography (LC-ESI-QTOF-HRMS). Then, the HaloSeeker 2.0 software was used to filter the mass spectrometry data for sil contamination and human health risks posed by TDBP-TAZTO, and for considering appropriate measures to control the emission of TDBP-TAZTO and its transformation products during product life cycles.Many trace contaminants of emerging concern (CECs) including a number of pharmaceutically active compounds are not effectively removed during conventional wastewater treatment processes and instead accumulate in wastewater sludge. Unfortunately, many existing sludge stabilization treatments such as anaerobic digestion (AD) also have limited effectiveness against many of these CECs including the four pharmaceuticals ibuprofen, diclofenac, carbamazepine, and azithromycin which can then enter the environment through the disposal or land application of biosolids. Single-stage AD, single-stage cycling aerobic-anoxic (AERO/ANOX) and sequential digesters (AD followed by an AERO/ANOX digester) at sludge retention times (SRT) of 5 to 20-days were evaluated side-by-side to assess their effectiveness in removing pharmaceuticals and conventional organic matter. Single-stage ADs (35 °C) and AERO/ANOX (22 °C) digesters effectively removed total solids while sequential AD + AERO/ANOX digesters offered further improvements. that different digester configurations can reduce the CEC burden in biosolids while also greatly reducing their volumes for disposal, although none can remove CECs completely.Designing evidence-based policies that regulate harvest levels is essential to avoid unsustainable hunting. This requires a good understanding of the relationship between bag sizes and regulatory mechanisms of harvest, and particularly of how these mechanisms are implemented locally and how they vary between game estates. The European Turtle-dove (Streptopelia turtur) has decreased by 30-49% since the late 1990s. The three main identified threats for the species are habitat loss, illegal killing and unsustainable legal hunting. We assessed how turtle dove estate-level harvest varies in relation to hunter density, number of hunting days, the adopted hunting method, game management intensity and the economic investment of the estate. Additionally, we assessed whether estate-level harvest had declined concomitantly with the population decline, and whether trends had been similar in relation to hunting method. We analysed Hunting Management Plans and Annual Hunting Reports of several thousand estates in central Spain, one of the main breeding and hunting areas of the species.