Gibbonsskaaning2541

The three filter substrates evaluated (Teflon, MCE, PVC) performed similarly in most challenges, however, overall, we conclude that MCE media is the most robust collection substrate for soluble platinum measurements. To achieve the lowest detection levels, it is critical to pre-clean the filter substrates. The use of a 0.07 M HCl extractant (in preference to a water extractant) is recommended - platinum recoveries, particularly from real-world samples, are higher and more consistent with the HCl extractant. The outcomes of the extraction kinetics experiments suggest that an extraction time of 60 min may improve the method performance with 0.07 M HCl but degrade the performance with water, in comparison with a 30-min extraction period. The use of sonication in preference to a table-top shaker is recommended for energy input during extraction.Environmental contamination by plastics and its negative effect on biodiversity have been well-documented in several types of organisms, especially in marine environments. Therefore, it is necessary to assess the impacts of plastic on other organisms such as aquatic insects, which predominantly inhabit freshwaters. It is widely known that these organisms are sensitive to environmental change, especially by contamination. Therefore, this study aimed at testing the hypothesis that aquatic insects are impacted by plastic contamination. We made a systematic search for international papers related to plastics and aquatic insects in databases such as Google Scholar, Web of Science, and Scopus. We obtained 1217 studies of which 40 discussed the impacts of contamination by plastics on aquatic insects. We identified two main impacts the first one is caused by the use of black macroplastic to protect crops from contact with the soil in agriculture. These black macroplastics attract tons of adult aquatic insects (terrestrial stage) that mistake the plastic surface for water because they select oviposition sites through phototaxis or polarotaxis. The second one comes from water contamination that can originate from the inadequate disposal of plastics, which harms young aquatic insects (aquatic phase) when they feed, reproduce, and construct shelters. Our results show the negative impacts of plastics on both larvae and adult aquatic insects. Despite the large knowledge gap regarding the impacts of plastic on aquatic insects, the evidence above is sufficient to consider these organisms important in global discussions regarding the impacts of plastic on biodiversity.Landfill leachate (LL), especially the reverse osmosis concentrate (ROC), is a societal burden due to high toxicity but may have intrinsic values attributing to copious nutrients and organics. ROC bioremediation by microalgae has attracted much attentions benefiting from its extra advantage of bioenergy production. However, efficient microalgae cultivation with ROC is still a challenging task attributing to notorious ROC characteristics, like high chromaticity and toxicity. To alleviate these negative influences, a technique integrating granular activated carbon (GAC) pretreatment and microalgae bioremediation was proposed, with which nitrogen and phosphorus removal efficiencies achieved 100% along with an optimized microalgal biomass concentration of 1.44 g/L and lipid yield of 482.4 mg/L. Furthermore, a total volumetric energy yield of 33.6 kJ/L was acquired, which was conducive to realize energy valorization. The visualization evidence of three-dimensional fluorescence spectroscopy revealed chromaticity degradation mechanism of ROC as humic acids reduction and transfer to family of soluble microbial by-products. Meanwhile, contributions of GAC adsorption and microalgae assimilation on nutrients removal were analyzed. Together, this work provides a promising method and valuable information for ROC bioremediation with microalgae.Understanding the chemical make-up of soils and their structure is critical for constraining the role of soil organic matter (SOM) into the global biogeochemical cycles, as well as to understand the capability of SOM to sequester carbon and mitigate greenhouse gas emissions. Here, we use two-dimensional 1H-13C heteronuclear single quantum coherence nuclear magnetic resonance (2D 1H-13C HSQC NMR) spectroscopy to structurally characterize the most refractory component of SOM, the humic acid (HA). The observations from 2D 1H-13C HSQC NMR were coupled with lignin phenol and fatty acid measurements using tetramethylammonium hydroxide (TMAH) thermochemolysis - two-dimensional gas chromatography - mass spectrometry (TMAH-GC × GC-MS). We studied humic acids extracted from an integrated Crop - Livestock - Forest System (CLFS) agricultural area and an undisturbed Atlantic Native Forest (NF) area. We evaluated soils from two different depths the topsoil (0-20 cm) and subsoil (60-100 cm) layers, and reveal the presence orent soil environments.A continuing increase in droughts/floods in Asian monsoon regions and worsening air quality due to aerosols are the two biggest threats to the health and well being of over 60% of the world's population. This study focuses on in-situ observations of atmospheric aerosols and their impact on shortwave direct aerosol radiative forcing (SDARF) during the southwest monsoon season (June-September) from 2015 to 2020 over a semi-arid station in Southern India. The Standardized precipitation index (SPI) is used to identify the droughts and normal monsoon years. Based on the SPI index, 2015, 2016, and 2018 were considered the drought monsoon years, while 2017, 2019, and 2020 were chosen as the normal monsoon years. During the drought monsoon years (normal monsoon years), the monthly mean black carbon (BC) was 1.17 ± 0.25 (0.72 ± 0.18), 1.02 ± 0.31 (0.64 ± 0.17), 1.02 ± 0.38 (0.74 ± 0.28), and 1.28 ± 0.35 μg/m3 (0.88 ± 0.21 μg/m3), for June, July, August and September respectively. The lower BC concentration during the f absorbing BC aerosols during the drought monsoon years in introducing additional heat to the lower atmosphere, particularly over peninsular India.This study investigates the localities of low and high F- groundwaters in the aquifer system on the flanks of Mount Meru to come up with guidelines to provide groundwater that can be used for drinking water supply without health impacts on the population. Our study focuses on parts of the flanks which were only partially or not at all covered by previous research. Results show that the groundwater chemistry of F--rich NaHCO3 alkaline groundwater in the area is controlled by dissolution of weathering aluminosilicate minerals, dissolution of F--bearing minerals, the precipitation of carbonate minerals as secondary products and the dissolution of magmatic gases. The low F- groundwaters which can be used for drinking water supply without health impacts under the WHO limit (1.5 mg/L) are the low-fluoride springs from the high altitude recharge areas on the eastern and north-western flanks of Mount Meru inside Arusha National Park, whereas on the western flank the groundwater meets the Tanzanian limit (4.0 mg/L). On the south-western flank, the shallow aquifer composed of alluvium deposits at lower elevations, shows F- values that meet the Tanzanian limit. One of the three investigated deep boreholes on this flank also meets the Tanzanian limit, suggesting a possibility of finding relatively low F- groundwaters in the deep aquifer. Yet, in general, the deposits at lower elevations are found to contain high to very high F- values, whereas the deposits at high elevations contain groundwater of low F- values. Thus, the internal texture and grain size of geological formations, the burial depth of these formations and the water residence times are the factors determining the groundwater mineralisation and F- concentrations in the area. The study identified that the deep hydrothermal system has influence on the high F- groundwaters on the eastern and north-eastern flanks of Mount Meru.In this study, we investigated the effects of elevation and precipitation on rice (Oryza sativa L.) production using the Crop Environment Resource Synthesis (CERES)-Rice model in Hubei province, China. NPS2143 We divided our study area into four zones based on elevation and precipitation. For each zone, our simulations were conducted using three planting methods dry direct-seeded rice (DDSR), wet direct-seeded rice (WDSR), and transplanted-flooded rice (TFR), with three rice cultivars of different growth duration Yangliangyou6 (long-duration), Huanghuazhan (mid-duration), and Lvhan1 (short-duration). Additionally, the optimal irrigation strategy for WDSR was determined with the CERES-Rice model. Our results indicated that the yields of WDSR with the optimal irrigation strategy were comparable with those of TFR in low-elevation regions but were less than the TFR yields in high-elevation areas. Furthermore, the rice yields increased at first and then decreased with increasing elevation, which was affected by growing period length and photosynthesis rate. Compared with the other two cultivars, the short-duration cultivar may be more suitable for growing in high-elevation regions. In addition, high precipitation could facilitate the cultivation of the long-duration cultivar in low-elevation regions, as it gives DDSR a yield potential comparable to that of WDSR for the short-duration cultivar in high-elevation regions. This study could help farmers choose optimal field management practices based on elevation and precipitation, ensuring sustainable and improved rice production.Response of terrestrial invertebrates to decabromodiphenyl ethane (DBDPE) is an emerging field of research nowadays, while cytotoxicity of DBDPE and self-defense strategies of invertebrates are poorly understood. In this study, earthworms (Eisenia fetida) were incubated in the DBDPE-spiked soil system (10, 30, 50, 70, and 100 mg kg-1 dw) for 28-d uptake. The bioaccumulation and distribution of DBDPE, a series of biomarkers associated with lysosomes/mitochondria, and the apoptosis rate of coelomocytes have been evaluated on the 7th, 14th, 21th, and 28th day. At experimental endpoint, the autophagy/apoptosis phenomena have been observed under transmission electron microscopy and the expression levels of six target genes have been explored. Findings in this paper revealed that bioaccumulation factors decreased with the incremental DBDPE concentrations in the soil. Intestinal ingestion, but not epidermal contact predominated the absorption of DBDPE. The fluctuations of biomarkers and the apoptosis rate were described as the "abnormity-recovery-dysregulation" pattern. Intense oxidative stress, energy demands, membrane-system damage, pathological organelles, and apoptosis were observed in the treated groups. Conclusively, the cytotoxicity of DBDPE initiated the mitochondrial apoptosis pathway which affected the physiological status of lysosomes, autophagy, and the expression of genes. The coping mechanisms of Eisenia fetida to DBDPE included activating mitochondrial electron transport processes, reorganizing actin cytoskeleton, and initiating autophagy. Earthworms resisted the cytotoxicity of DBDPE to a certain extent, while long-term exposure still resulted in apoptosis of coelomocytes. This study works as a laboratory simulation for the environmental safety evaluation of DBDPE and the detoxification mechanisms for earthworm.