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We developed a mass balance model at a single site to relate seasonal floodplain processes with water column SRP export, above and below the study reach, using measurements in this study combined with data from the literature. Grab sample data suggest that the reach retained 26% of incoming SRP, which the mass balance model attributed to seasonal synergy between plant assimilation in spring and summer (removing P from floodplain soils) and abiotic P sorption during winter and spring inundation (adding SRP to the floodplain). Retention of SRP was higher in floodplain soils compared to stream sediments based on the modeled SRP budget. Thus, we suggest that these constructed floodplains will maximize SRP retention from the water column if they inundate regularly, have floodplain soils with FeP > 3-6, and that promote sustained plant life.The agribusiness contributes significantly to the Brazilian domestic production, and the search for environmentally friendly systems, exploring the maximum possible use of renewable resources and reducing the use of non-renewable ones, affects the agribusiness' productivity and competitivity. An agribusiness producing corn, eggs, pork and milk was evaluated using emergy accounting. The effects of the (des)integration of the production processes on the efficiency and environmental sustainability of the system were assessed using seven scenarios. The first is the existing integrated system and the others are scenarios in which one of the productive subsystems is removed. Efficiency is measured by the global productivity relative to the amount of protein produced. The most environmentally advantageous scenario, in terms of sustainability and productivity, is the one in which pork production is increased and egg production is ceased. This result suggests that increasing integration per se cannot assure gains in environmental sustainability. The integrated management of the residues of the poultry and pig production as organic fertilizer resulted an advantage for the seven scenarios. The scenarios presented should help to evaluate organizational innovations and to identify trade-offs that could influence the environmental performance of agricultural integrated systems.The long-term trend of air pollutants was studied in Chandigarh, located in Indo-Gangetic Plains of India. The SPM, PM10, NOx, and SO2 depict site-specific variation having different anthropogenic activities. The results indicate that PM10 levels in Chandigarh remain higher than the prescribed annual ambient air quality standards (60 μg m-3) of India. Seasonal Kendall test indicates a declining trend of PM10 for the year 2003 to 2018 at an industrial and commercial site (1996-2016). There is a significant increase in NOx levels at all locations except at commercial sites. The results of the linear regression model and Theil-Sen slope show that SPM is declining at all locations, but results are not statistically significant. Interestingly, PM10 levels at the industrial site display a significant declining trend (1.3% year-1). Similarly, NOx levels are increasing at all sites but having a statistically significant trend at a rural location (8.9% year-1) and residential site (15.2% year-1). Air pollutants show strong seasonal variability having a higher concentration in post-monsoon and winter season, which found to be linked with regional anthropogenic activities such as crop residue burning and use of solid biomass fuel for cooking and other purposes. Lowest PM10 levels were observed during the monsoon and having a decline of 47.4-66.4% as compared to winter levels. Site-specific variations in air pollutants were found to be associated with air quality improvement policies such as shifting of an interstate bus terminal, ban on diesel autos, including strict implementation of air quality norms on industries. selleck chemicals As the relative contribution of various pollution sources is still unknown, the seasonal pattern of pollutants will help in knowing the background concentration of pollutants and could help to formulate evidence-based policies to mitigate air pollution under National Clean Air Programme (NCAP).Biogas is a renewable energy fuel that can be treated to increase purity so that the resulting "biomethane" can be injected into the natural gas pipeline grid. The trace contaminants in biogas and biomethane make up a small fraction of the total gas but they still have the potential to cause adverse health effects and pipeline corrosion. link2 This study investigates the statistical distributions of 17 trace metals, six mercaptans, hydrogen sulfide, ammonia, and six additional trace organic compounds. Twelve of these 31 trace contaminants have been previously identified as constituents of concern based on their toxicity profiles and through health risk assessment studies. Untreated and treated samples of biogas were collected from 12 different biogas production facilities using diverse feedstocks throughout California. Results show that most biogas trace contaminants follow a single log-normal distribution or a bi-modal lognormal distribution depending on the type of production facility. link3 Treatment of biogas demonstrates some removal for all trace contaminants, but four constituents of concern (copper, lead, hydrogen sulfide, and methyl mercaptan) are predicted to have a >1% probability of exceeding trigger levels even after common treatments. This finding suggests that enhanced monitoring may be warranted for these contaminants. Several trace metals and volatile organic compounds (VOCs) were found to have seasonal trends with greater concentrations in the summer and lower concentrations in the winter suggesting that seasonal variation should be considered in future monitoring plans.Cyanobacteria and microalgae are abundant biota groups in eutrophic freshwater ecosystems, serving as a food source for many aquatic organisms, including the larvae of non-biting midges (Chironomidae). Many species of cyanobacteria are toxin producers, which can act as stressors to other organisms. The present study aimed to analyze and compare the effects of dietary exposure to the common toxic cyanobacteria Anabaena sp. and non-toxic microalgae Chlorella sp. in Chironomus riparius larvae. Microcystin was detected and quantified in the methanolic extract of Anabaena sp. using the HPLC-DAD technique, and it was identified as microcystin-LR. Both Anabaena sp. and Chlorella sp. were suitable food sources to enable the survival of C. riparius larvae in laboratory conditions, causing negligible mortality and significant differences in the larval mass (ANOVA and Post hoc LSD test; p less then 0.05) and hemoglobin concentration (Student's t-test; p less then 0.05). Oxidative stress parameters such as advanced oxidation protein products (AOPP), thiobarbituric acid reactive substances (TBARS), catalase (CAT) and superoxide dismutase (SOD) activity, and DNA damage, were also investigated. One-way ANOVA, followed by the Post hoc LSD test, showed a significant increase in AOPP and CAT for the group of larvae fed with Chlorella sp. The same test showed moderate DNA damage in both groups of larvae, with greater damage in the group fed with Anabaena sp. Thus, Chlorella sp. and microcystin-LR producing Anabaena sp. are food sources that did not result in any drastic acute effect on the population level of C. riparius larvae. However, sub-individual-level endpoints revealed significant effects of the treatments, since they caused oxidative stress and DNA damage that may pose a danger to successive generations of test organisms.Accurate estimation of evapotranspiration (ET) over regional scale is essential for ecohydrological research, agricultural production, and water resources management. However, few studies have been done to estimate regional ET in data lacking, highly heterogeneous arid areas such as the Agricultural-Pastoral Ecotone in Northwest China (APENC). In this study, we compared three actual ET-estimation methods driven by Weather Research and Forecasting (WRF) model in a semi-arid region. We selected the state of the art Weather Research and Forecasting-Community Land Model 4.0 (WRF-CLM4.0) model, the widely used WRF-Noah model and an empirical Complementary Relationship (CR) model to compare their model structures and mechanisms of estimating daily ET in the study region. The WRF model was chosen to address the problem of data scarcity in the study region and to derive model input for ET estimation with high spatial resolution. The seasonal and pooled performances of the three models were verified with in situ observations. Results indicate that the WRF-CLM4.0 model shows a better applicability in the study region, with a superior performance for the pooled datasets (Pearson correlation coefficient [r] = 0.89, root-mean-square error [RMSE] = 0.66 mm/d and Nash-Sutcliffe efficiency coefficient [NSE] = 0.90), while the CR model has a comparable performance (r = 0.91, RMSE = 0.86 mm/d and NSE = 0.85) and the WRF-Noah model shows the worst performance (r = 0.82, RMSE = 0.94 mm/d and NSE = 0.81). The differences are mainly caused by different representations of the land surface characteristics and hydrology of the study region by the three different models. Our analysis shows that the WRF-CLM4.0 model and the CR model are more applicable to the APENC than the WRF-Noah model. For regional applications, the CR model, with fewer parameters and simpler structure, is able to capture the local characteristic and well-suited for data lacking, highly heterogeneous landscapes such as the APENC.This study has two goals. The first is to explain the geo-environmental determinants of the accelerated diffusion of COVID-19 that is generating a high level of deaths. The second is to suggest a strategy to cope with future epidemic threats similar to COVID-19 having an accelerated viral infectivity in society. Using data on sample of N = 55 Italian province capitals, and data of infected individuals at as of April 7th, 2020, results reveal that the accelerate and vast diffusion of COVID-19 in North Italy has a high association with air pollution of cities measured with days exceeding the limits set for PM10 (particulate matter 10 μm or less in diameter) or ozone. In particular, hinterland cities with average high number of days exceeding the limits set for PM10 (and also having a low wind speed) have a very high number of infected people on 7th April 2020 (arithmetic mean is about 2200 infected individuals, with average polluted days greater than 80 days per year), whereas coastal cities also having days excine, healthcare and health sector.Urban surface runoff from storms impacts the water quality dynamics of downstream ecosystems. While these effects are well-documented in mesic regions, they are not well constrained for arid watersheds, which sustain longer dry periods, receive intense but short-lived storms, and where stormwater drainage networks are generally isolated from sewage systems. We used a network of high-frequency in situ water quality sensors located along the Middle Rio Grande to determine surface runoff origins during storms and track rapid changes in physical, chemical, and biological components of water quality. Specific conductivity (SpCond) patterns were a reliable indicator of source, distinguishing between runoff events originating primarily in urban (SpCond sags) or non-urban (SpCond spikes) catchments. Urban events were characterized by high fluorescent dissolved organic matter (fDOM), low dissolved oxygen (including short-lived hypoxia less then 2 mg/L), smaller increases in turbidity and varied pH response. In contrast, non-urban events showed large turbidity spikes, smaller dissolved oxygen sags, and consistent pH sags.

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