Woodruffellis1659

Further, the PFRs contained in biochar did influence the toxicity, along with the physicochemical properties of biochar (i.e. carbon structure, functional group or surface charge). Our results aimed to reflect the toxicity profile of biochar in the natural aquatic environment, without misunderstanding of potential ecological risk of biochar in the future application.The increasing demand for rare earth elements (REEs) for modern industry has led to a surge in mining activities and consequently has released these metals into the environment. Intensifying REEs in a habitat has impacts on its ecosystem, but on the other side, it also provides the opportunity to recover REEs from low-grade minerals. click here Phytomining has emerged as an ecologically sound technique to extract these valuable elements from contaminated soils where traditional mining is not competitive. This paper presents and reviews the concept of REE phytomining from three scientific areas. The accumulation of rare earth metals in plants is the first stage, referred to as the phytoextraction process. This is followed by elevating REE concentrations into bio-ores via the enrichment phase. Ultimately, extraction is the final step to complete the phytomining pathway for reclaiming REEs in brownfield land.Microbiological contamination is one of the riskiest forms of human contamination in seawater, which threaten the stability of ecosystems and human health. In this study, we study the accumulation of a pathogenic bacteria Salmonella spp; isolated from the marine environment, in the soft tissue of Donax trunculus (Mollusca, Bivalvia), a commonly used as a bioindicators species for aquatic ecosystems monitoring, under laboratory conditions during both exposure and recovery periods. These bacteria were added in seawater at three concentrations previously determined against sentinel specie at three exposure periods (24, 48 and 96 h). In a second series of experiments, exposed specimens were afterward transplanted to clean water to assess the recovery pattern. The mortality rate of bivalves was determined as biomarker of general stress. Our findings suggest that microbiological contamination by Salmonella spp was gradually incorporated into the body of D. trunculus causing a significant induction of enzymatic activity of acetylcholinesterase (AChE), Catalase (CAT), glutathione-S-transferase (GST) and malondialdehyde (MDA) levels, as a function of time and concentration. Exposure to a bacterial concentration of 5.104 bacteria/liter resulted in the mortality of more than 80% of the specimens. This study is to test the pathogenicity of Salmonella strains at concentrations close to those of the marine environment, and their effects on biomarkers, thus deducing the existence of an exponential relationship between bacterial concentrations and enzymatic response. The principal component analysis shows that the four biomarkers had similar variation with bacterial concentrations, while two groups were obtained to change following the exposure time (CAT-GST and AChE-MDA). This study provides new findings on the potential accumulation of pathogenic bacteria associated with neurotoxicity and oxidative stress in the wedge clam Donax trunculus.Developing an efficient approach to decompose ground-level O3 in humidity is crucial for preventing O3 pollution in practical application scenes. In this study, MnOx, CuO, and Cu/MnOx were synthesized to investigate the influence of H2O on the variation of active sites during O3 decomposition. The structural characterizations of the as-synthetic catalysts were measured by N2 physisorption, XRD, SEM, O2-TPD, H2-TPR, TG, and FT-IR analyses. In dry conditions, the elimination rate of O3 followed the sequence of MnOx > Cu/MnOx > CuO. The introduction of Cu to MnOx enhanced the surface area and pore volume of Cu/MnOx, accordingly diminishing the amounts of surface defects and the participation of sub-surface lattice oxygen for catalytic cycle, indicating that surface defects and oxygen vacancies (VO) determined the catalytic activity for O3 decomposition. In humid conditions, the elimination rate of O3 changed to the sequence of Cu/MnOx > MnOx > CuO, with a variation rate compared to dry conditions of -62.9% for MnOx, 14.2% for CuO, and 27.7% for Cu/MnOx. The decrease of participant sub-surface lattice oxygen and the accumulation of intermediates in humidity diminished the decomposition of O3 on MnOx, while the active species such as superoxide radicals generating from the reaction of H2O and Cu/MnOx facilitated the participation of VO and the desorption of O2 from the occupied active sites, accelerating the catalytic cycle on Cu/MnOx. This work developed a deeper understanding of the influence of H2O on catalytic activity, promoting the performance of MnOx-based catalysts for practical O3 decomposition.Metal organic frameworks (MOFs) represent the organic and inorganic hybrid porous materials. MOFs are low dense and highly porous materials which in turn provide large surface area that can accumulate and store numerous molecules within the pores. The pore size may also act as a mesh to separate molecules. The porous nature of MOFs is beneficial for altering the intrinsic properties of the materials. Over the past decade, different types of hybrid MOFs have been reported in combination with polymers, carbon materials, metal nanoparticles, metal oxides, and biomolecules for various applications. MOFs have also been used in the fabrication of electronic devices, sensors, energy storage, gas separation, supercapacitors, drug delivery and environmental clean-up. In this review, the unique structural orientation, exceptional properties and recent applications of MOFs have been discussed in the first section along with their porosity, stability and other influencing factors. In addition, various methods and techniques involved in the synthesis and designing of MOFs such as solvothermal, electrochemical, mechanochemical, ultrasonication and microwave methods are highlighted. In order to understand the scientific feasibility of MOFs in developing new products, various strategies have been applied to obtain different dimensional MOFs (0D, 1D, 2D and 3D) and their composite materials are also been conferred. Finally, the future prospects of MOFs, remaining challenges, research gaps and possible solutions that need to be addressed by advanced experimental design, computational models, simulation techniques and theoretical concepts have been deliberated.The practice of burning household waste including different types of plastic is illegal in Hungary, still an existing problem. As environmental consequences are hardly known, this study attempts to give an initial estimation of the ecotoxicity generated during controlled combustion of different waste types. These samples included polystyrene (PS), polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), polyurethane (PU), oriented strand board (OSB) and rag (RAG). Ecotoxicological profiling was completed using the following test battery Vibrio fischeri bioluminescence inhibition assay, Daphnia magna immobility test and the seedling emergence assay. Also, genotoxicity of plastic waste samples was assessed using the SOS Chromotest. Concerning main pollutants in the samples, the samples could be distinguished as 'PAH-type' and 'heavy metal-type' samples. PVC, PU and PS samples showed the highest toxicity in the Vibrio and Daphnia assays. The PVC sample was characterized by an extremely high cadmium concentration (22.4 μg/L), PS, PP and PU samples on the contrary had high total PAH content. While Vibrio and Daphnia showed comparable sensitivity, the phytotoxicity assay had no response for any of the samples tested. Samples originating from the controlled burning of different plastic types such as PU, PVC, PS and PP were classified as genotoxic, PS sample showed extremely high genotoxicity. Genotoxicity expressed as SOSIF showed strong correlation with most of the PAHs detected.Aquaculture wastewater contained a high remnant of oxytetracycline (OTC) and nitrate. In this study, OTC co-metabolized with denitrification/desulfurization was investigated in terms of kinetic analysis, pathway, microbial communities and produces analysis in sulfate-reducing bacteria (SRB) mediated system. Long-term acclimatization with sulfate (300 mg-S/L) could markedly accelerate the removed rate of OTC from 0.9 to 1.4 mg/g-SS/d, with the kinetic constants increasing from 0.2760 to 0.5232 d-1, mainly via enzymes including adenosine-5'-phos-phosulfate reductase and cytochrome P450, and non-enzymatic process related to intermediates (adenosine-5'-phos-phosulfate and S0). Furthermore, OTC was likely detoxified by SRB enriched sludge mainly via hydrolysis, dehydration, oxidation and reduction. The denitrification process would postpone the OTC degradation via outcompeting electron donors with the desulfurization process. Redundancy analysis suggested that sulfur-oxidizing bacteria (Acidithiobacillus, Ochrobactrum) were highly related to OTC degradation processes. This study provides deep insight and a new opportunity for the treatment of aquaculture wastewater containing OTC, sulfate and nitrate by SRB sludge.We evaluated the effects of Mn in juvenile Yunlong groupers (Epinephelus moara ♀ × E. lanceolatus ♂). The groupers were exposed to Mn2+ (0, 0.5, 1, 2, and 4 mg/L) for 30 days after which they were assessed. The results indicate the accumulation of Mn in fish depended on dose and time. Mn2+ accumulation in tissues occurred in the following order liver > gills > intestine > muscle. The concentrations of SOD and CAT in the fish significantly increased after 10 and 20 days of treatment with 4 mg/L Mn2+ but decreased after 30 days. Similarly, GSH and GPx levels increased after 10 days of exposure to 2 and 4 mg/L Mn2+ but decreased after 20 and 30 days of exposure. Additionally, malondialdehyde levels significantly increased after exposing the fish to 2 and 4 mg/L Mn2+ for 10, 20, and 30 days. In addition, liver HSP70 and HSP90 levels significantly increased at days 20 and 30 in all fish exposed to Mn2+. In addition, when Mn2+ concentration was 1, 2, and 4 mg/L, liver C3 and C4 levels were significantly increased after 10, 20, and 30 days. Conversely, the levels of LZM and IgM significantly decreased. Mn2+ also significantly upregulated the expression of genes associated with immunity (tlr3, tnf-α, il-1β, and il-6) in the fish, which suggests that it induces immunotoxicity by altering the immune response. Overall, the findings showed that Mn2+ can disrupt grouper health by bioaccumulating in the fish and subsequently inducing oxidative stress and immune responses. These results can help elucidate the mechanism by which manganese induces toxicity in marine fish. Additionally, they provide a new perspective regarding the detrimental effects of heavy metals in fish.Metronidazole (MET), a recalcitrant antibiotic from the nitro-imidazole family and commercially used Rhodamine B (RhB) dye, contributes a huge to water pollution, which needs to eliminate, preferably by photocatalytic degradation technique. The Cdots@zeolite (CDZ) nanocomposites with different weight ratios (11, 13, 15, 51, 17) were synthesized hydrothermally to degrade MET and RhB molecules. The CDZ composites were characterized by XRD, BET, EDS, and XPS technique which verifies the crystalline nature, incorporation of C-dots into zeolite frameworks with high surface area (∼187 m2/g). The morphology, d-spacing and lattice planes were analyzed by SEM images, HR-TEM and SAED analysis. The maximum degradation (∼79%) was achieved at an optimum catalyst dose of 0.2 g/L and pH 4 for MET and that of RhB was ∼90% at a catalyst dose of 0.4 g/L. The PZC (point of zero charge) value for CDZ composite was about pH 3.4, which justifies the maximum removal of MET at pH 4. The obtained rate constants 'k' were found to be 0.