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57 million, and the net system benefits would be slightly less at $105.91 million. If policymakers strive to achieve the net system benefits of the project, the highest net system benefits would be achieved under pi' = 0.05. At this probability level, the net system benefits would increase to $135.45 million, the system cost would reduce to $138.62 million, but the total amount of CO2 storage would decrease to between 4090.01 and 4653.24 ktpa, which would entail a high risk of system violation. These findings enable policymakers to determine the trade-offs among system reliability, CO2 reduction, and the benefits of the project. The modeling approach can also address interactions among CCUS activities and the dynamics of facility expansion issues as well as help policymakers develop adaptive operational strategies. This study enriches CCUS research through an interval chance-constrained optimization modeling approach for CCUS system management under multiple uncertainties.The canopy layer urban heat island (CLUHI) and surface urban heat island (SUHI) refer to higher canopy layer and land surface temperatures in urban areas than in rural areas, respectively. The long-term trends of CLUHIs are poorly understood at the regional scale. In this study, 1 km resolution air temperature (Ta) data for the 2001-2018 period in the mainland of China were mapped using satellite data and station-based Ta data. Subsequently, the temporal trends of the CLUHI and SUHI intensities (CLUHII and SUHII, respectively) were investigated in 272 cities in the mainland of China. The Ta was estimated with high accuracy, with a root mean square error ranging from 0.370 °C to 0.592 °C. The CLUHII and SUHII increased significantly in over half of the cities in spring and summer, over one-third of the cities in autumn, and over one-fifth of the cities in winter. The trends of the nighttime SUHII were strongly related to the CLUHII calculated using mean and minimum Ta (correlation coefficients ranging from 0.613 to 0.770), whereas the relationships between the trends of the daytime SUHII and CLUHII were relatively weak. Human activities were the major driving forces for the increase in the CLUHII and SUHII. RNA Synthesis inhibitor The difference in impervious surfaces between urban and rural areas was significantly correlated with the CLUHII and SUHII in approximately half of the cities. Meteorological factors were significantly correlated with the CLUHII and SUHII in few cities. This study highlights the trends of the significant increase in the CLUHII and SUHII in the mainland of China, which may have negative effects on humans and the environment.Soil organic matter (SOM) is related to vegetation, soil bacteria, and soil properties; however, not many studies link all these parameters simultaneously, particularly in tundra ecosystems vulnerable to climate change. Our aim was to describe the relationships between vegetation, bacteria, soil properties, and SOM composition in moist acidic tundra by integrating physical, chemical, and molecular methods. A total of 70 soil samples were collected at two different depths from 36 spots systematically arranged over an area of about 300 m × 50 m. Pyrolysis-gas chromatography/mass spectrometry and pyrosequencing of the 16S rRNA gene were used to identify the molecular compositions of the SOM and bacterial community, respectively. Vegetation and soil physicochemical properties were also measured. The sampling sites were grouped into three, based on their SOM compositions Sphagnum moss-derived SOM, lipid-rich materials, and aromatic-rich materials. Our results show that SOM composition is spatially structured and linked to microtopography; however, the vegetation, soil properties, and bacterial community composition did not show overall spatial structuring. Simultaneously, soil properties and bacterial community composition were the main factors explaining SOM compositional variation, while vegetation had a residual effect. Verrucomicrobia and Acidobacteria were related to polysaccharides, and Chloroflexi was linked to aromatic compounds. These relationships were consistent across different hierarchical levels. Our results suggest that SOM composition at a local scale is closely linked with soil factors and the bacterial community. Comprehensive observation of ecosystem components is recommended to understand the in-situ function of bacteria and the fate of SOM in the moist acidic tundra.This study introduced fractions (labile, stable-adsorbed, tight-adsorbed fractions) of organophosphate esters (OPEs) into ecological risk assessment to evaluate the potential risks of organophosphate esters that released from sediment, and conduct a case study to verify it. The content of desorbable fractions was get from adsorption-desorption experiments. Adsorption process can be divided into fast sorption, gradual sorption, and final equilibrium stage, and labile, stable-adsorbed, tight-adsorbed fractions were formed during adsorption. Approximately 86.21% labile, 73.41% stable-adsorbed, and 43.01% tight-adsorbed TPhP-D can be desorbed from sediments in desorption experiments. According to the results, the value of hazard quotient (HQ) that calculated by desorbable fractions reduced by 13.88% than HQ calculated by the sum of fractions, and result of 29.76% decrease for ∑HQs. The isotherm results demonstrated that the contents of labile and stable-adsorbed fractions increased faster than tight-adsorbed fraction when the concentration of contaminant in water increased from 50 to 400 μg/L, which means ecological risk in areas with high concentration of contaminants are higher than the discreet value. In case study, an additional hotspot was found in areas, where characterized with high proportion of labile fraction, when ecological risk was calculated by desorbable fractions. Indicating that revised ecological risk assessment takes both of total content and desorbable content into consideration.Composite fuels made of waste from coal, petroleum and wood processing industries have a high environmental and economic potential. In this research, we experimentally studied the concentrations of the most hazardous gaseous anthropogenic emissions (CO2, SO2, NO) from waste-based fuel combustion. Using two techniques operating in complementary temperature ranges, we obtained data on SO2 and NO emissions in the temperature range from 300 °C to 1000°C, including all the stages of thermochemical conversion of fuels. A quasi-stationary technique was used, based on a setup of thermogravimetric analysis with mass spectrometry, to obtain information in a low-temperature range (300-600°C). This technique allows the conversion at a low controlled rate of heating a sample together with the furnace. To obtain data in a high-temperature range (700-1000°C), a non-stationary technique was used, where the sample was introduced into a pre-heated furnace. The conditions were established in which it was possible to reduce the concentration of flue gases from the combustion of the compositions under study (replacement of the coal part with water, injection of water vapor, addition of biomass, selection of the temperature range). The impact of water vapors was determined when they were injected into the chemical reaction zone together with air and when they were formed naturally by evaporation from the fuel sample. Unlike biomass that reduces the emissions of sulfur oxides from composite fuels due to the mechanical dilution of the mixture, water vapor present in the heterogeneous reaction zone decreases the gaseous anthropogenic emissions through chemical reactions and conversion of a part of fuel sulfur and nitrogen to an inactive form (neutral to the environment).Attributing the changes in the population exposure to global compound hot extremes, which combine daytime-nighttime hot extremes with more severe impacts, is essential for climate change adaptation. Based on daily temperature data from the Coupled Model Intercomparison Project phase 6 (CMIP6) and population data, we estimate the changes in population exposure for two future periods under three scenarios of emission and socio-economic development at global and continental scales, and assess the contributions from climate and population changes. We find that the spatial patterns of exposure to compound hot extremes are similar for different periods and scenarios, and regions with high exposure are mainly located over East Asia, South Asia, Europe, and parts of eastern USA and Africa. The exposure shows an increase from baseline (1980-2014) to mid- and late 21st century periods (2021-2055 and 2056-2090) in most regions worldwide. Under the business-as-usual scenario (SSP2-4.5), the global exposure increases by ~19-fold during the late 21st century, and Africa shows the largest increase while Europe shows the smallest. Early (SSP1-2.6) and no (SSP5-8.5) actions of mitigation would relieve and aggravate the increase rate, respectively. For about 78%-87% of the global land areas, the changes in exposure are mainly caused by climate change (accounting for >69%), followed by the interaction effect (accounting for ~29%) that refers to synergistic changes in climate and population. In parts of mid- to high-latitude regions, the exposure is smaller than expected due to opposite effects of climate change and population change.Coal fire sponges (CFS) are common in coal-fire areas. Due to the enrichment of Hg in CFS, large amounts of Hg are released by CFS into the atmosphere via natural weathering or solar radiation. Therefore, CFS should be of concern in Hg pollution management and control globally. In addition, CFS changes the Hg cycle path by capturing Hg from coal fires that would have entered the atmosphere. In this study, the concentration, distribution, species, and enrichment mechanism of CFS Hg were investigated. The results showed that the Hg concentration in CFS ranged from 1008 to 35,310 ng/g, with an average of 8932 ng/g (CFS number, n = 153). The Hg concentration of CFS in different types of land was found to be significantly inhomogeneous. To determine the status of subterranean spontaneous combustion, the Hg concentration was added, which can improve the effect of coal-fire monitoring. Compared to the background area topsoil, CFS was enriched in Hg, acid, SO42-, and total fluoride. The Hg species in CFS was primarily HgSO4, followed by HgO. However, the primary Hg species in the surrounding topsoil were HgCl2 and HgO. By the simulation experiment, it was determined that hydrofluoric acid (HF) was beneficial to activate the stable species in the coal-fire areas. HgCl2, HgO, or Hg0 were ionized by acid liquor or HF, which can promote Hg migration and increase the adsorbed ratio; in the presence of SO42-, the primary Hg species was HgSO4. Ultimately, Hg was absorbed by clay minerals and organic matter. The high-efficiency activation of steady Hg species by the coal-fire HF should be studied further.To understand the effect mechanisms of iron plaque and fatty acids on the migration of PBDEs from soil to rice (Oryza sativa), pot experiments were conducted in the soil spiked with decabromodiphenyl ether (BDE-209) under the conditions of tourmaline and nano-goethite Fenton-like treatments. The results showed that iron mineral Fenton-like oxidation could effectively remove BDE-209 from rhizosphere soil, the highest removal rate obtained 89.29% with the addition of 0.4 mmol/L H2O2 and 8 g nano-goethite (G + 3H group). Iron mineral Fenton-like oxidation could produce iron plaque (IP) on rice roots and accumulate a part of contaminants on the surface of IP, further weakening BDE-209 uptake in the plants. Additionally, the occurrence of fatty acid variation induced by BDE-209 stress, iron mineral Fenton-like oxidation at high concentrations of H2O2 with 0.4 mmol/L affected the distribution of fatty acids in plant tissues, especially for C180 fatty acid. While the IP on rice roots prevented the BDE-209 into plant, it was also closely related to the distribution of fatty acids in rice, altering BDE-209 accumulation in the rice.