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le in emission of this pollutant. A direct correlation between BC concentration and cardiorespiratory related mortality is observed. There are considerable health benefits in reducing BC concentration in this city. Our findings highlight the urgent need to actively curtail emissions of this harmful pollutant. This can be achieved through utilizing control mechanisms such as particulate filters or amending traffic laws. Selenium (Se) at very low doses has important functions for humans. Unfortunately, the low levels of Se in soils in various regions of the world have implemented the agronomic biofortification of crops by applying Se-enriched fertilizers (mainly based on selenate). Lately, the use of nanofertilizers is growing in interest as their low size reduces the amount of chemicals and minimizes nutrient losses in comparison with conventional bulk fertilizers. However, the knowledge on their fate and environmental impact is still scarce. This study aims to evaluate the biotransformation of chitosan-modified Se nanoparticles (Ch-SeNPs) as well as their effect on the metabolism of essential metals (Fe, Cu, Zn and Mo) when applied to hydroponic cultivation of R. sativus and B. juncea. In house-synthesized Ch-SeNPs were characterized in both synthesis and hydroponic culture media by transmission electron microscopy (TEM), dynamic light scattering (DLS) and nanoparticle tracking analysis (NTA). Sunitinib molecular weight The composition of one-tenth strength Hoagland's solution did not affect the size, shape and concentration in number of particles per mL of Ch-SeNPs. The plants were grown inside a box at 25 °C during the months of May-July in 2018. After a week of treatment with Ch-SeNPs, plants were harvested and divided into roots and aerial part. The biotransformation of Ch-SeNPs was evaluated through a process of enzymatic hydrolysis and subsequent analysis by HPLC-ICP-MS and HPLC-ESI-MS/MS. The results confirmed the transformation of Ch-SeNPs to seleno-amino acids Selenomethionine (SeMet), Semethylselenocysteine (SeMetSeCys) and ɣ-glutamyl-Se-MetSeCys. Moreover, Multiple-way analysis of variance (ANOVA) and principal component analysis (PCA) showed that, regardless the plant species, Ch-SeNPs supplementation affected the absorption of Zn. V.When a dam breaks, huge floods will be generated that may inundate urban areas, enterprises, farmlands, and infrastructure and cause giant economic losses. Economic risk criteria are a kind of basis for determining dam risk levels and to decide whether risk control measures should be taken or not. However, compared to loss-of-life risk criteria, much fewer economic risk criteria for dams have been proposed and implemented for two main reasons (a) The ability of most areas to endure economic losses caused by dam breach changes over time because of the constant development of their economic levels; and (b) Economic development levels in an area are distinct from the levels in other areas, resulting in significant differences in the ability of different areas to endure economic losses caused by a dam breach. Therefore, an equivalent economic scale (EES) that indicates the relative economic level of an area to the whole country in a given period of time is a preferred measure. It was shown in this paper that EES has much more stable values than do ordinary economic measures; therefore, it was taken as the basic index for establishing economic risk criteria. Furthermore, due to the distinct economic loss rates of different industries, the index of industrial economic contribution (IEC) was introduced to determine the correction coefficient to modify the ESS to reflect the potential economic loss of the area to be evaluated. This is the first research that pays careful attention to the change of ability to endure economic losses, in which the established economic risk criteria are applicable over a relatively long time and for different areas based on the consideration of the relative level of the economy and the industrial economic contribution. Construction is a sector which produces high greenhouse gas emissions, which cause global warming. As such, it is becoming increasingly important to use sustainable materials which reduce the environmental impacts. The properties of the plant fiber block make it one of the most adequate building materials for the construction of the building envelope. However, there is no in-depth research that encompasses the extraction of the raw material, the transport to the factory and the manufacturing process. The present research analyzes the environmental impact associated with the production of plant fiber blocks as a building material, using the Life Cycle Assessment methodology. In addition to looking at the sustainability of this material, it also compares it with other conventional building materials. The results show that the impact category which made the biggest contribution in the manufacturing of a plant fiber block for its use in construction was that of the total primary energy consumption (9.74 MJ/kg straw). With reference to the emission of the greenhouse gases produced during manufacturing, the main contributors are the nitrogen and urea-based fertilizers used in cereal cultivation (0.73 kg of the total 0.96 kg of CO2 per kg of straw). However, the impacts caused by manufacturing a PFB are much lower than those produced from other insulating materials such as expanded polystyrene, extruded polystyrene or polyurethane foam (4.67E+03 kg CO2 eq. for the PFB compared to 1.23E+04 kg CO2 eq. for the fiberglass and 1.33E+04 kg CO2 eq. for the polyurethane). Biochar and hydrochar have been served as attractive adsorbents for remediation of polluted water and soil, but it is lack of the long-term ageing effects on competitive adsorption of co-existing heavy metals by these carbonized materials. By this, corn stalk was used as carbon precursor to prepare biochar (500 °C) and hydrochar (200 °C). The single-metal and binary-metal Cd(II)/Cu(II) sorption were conducted on biochar and hydrochar before and after ageing using artificial accelerated ageing of 5% H2O2 treatment. The elemental analysis, BET, SEM, FTIR, XRD and Zeta potential were used to characterize the physicochemical properties of carbonized material samples. The results showed that oxidative ageing could increase O content and O-containing functional groups but decrease C content, metal content and aromaticity degree. Ageing hardly affected the SSA and crystallographic structures of biochar and hydrochar. The reduction of metal content in Aged-BC caused a decline of sorption capacity, indicating that cation exchange would be the predominant factor involved in biochar sorption for Cd(II) and Cu(II).

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