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2% capacity retention, 0.044% fading rate per cycle, and approximately 100% Coulombic efficiency after 200 cycles). This work demonstrates that the few-layered ternary MTMSs are highly applicable for the development of advanced SIB anode materials with high performance.We report a nanocomposite coating for lithium metal protection, which consists of nanosized LiF particles embedded into a PEO polymer matrix. The composite offers a large LiF/PEO interface area throughout the coating, promoting an exceptionally high ionic conductivity of 0.97 mS cm-1 and high lithium-ion transference number of 0.77 at room temperature in contact with a carbonate-based liquid electrolyte. Both properties are key to realize uniform lithium plating and stripping and prevent lithium dendrite formation. Lithium metal electrodes coated with this protective coating enable stable lithium plating and stripping at 1 mA cm-2 for over 1000 h. A full cell with the coated lithium metal anode and an NMC622 cathode with an areal capacity of 1 mA h cm-2 shows much improved specific capacity and cycling stability. The cell exhibits a high initial capacity of 135 mA h g-1 and a capacity retention of 83% after 500 cycles at 1 mA cm-2. Even at a high current density of 3 mA cm-2, the full cell shows an initial capacity of 125 mA h g-1 and a capacity retention of 74% after 300 cycles.The stability of microporous metal-organic frameworks (MOFs) in moist environments must be taken into consideration for their practical implementations, which has been largely ignored thus far. Herein, we synthesized a new moisture-stable Zn-MOF, [Zn 2 (SDB) 2 (L) 2 ]·2DMA n , IITKGP-12, by utilizing a bent organic linker 4,4'-sulfonyldibenzoic acid (H2SDB) containing a polar sulfone group (-SO2) and a N, N-donor spacer (L) with a Brunauer-Emmett-Teller surface area of 216 m2 g-1. This material displays greater CO2 adsorption capacity over N2 and CH4 with high IAST selectivity, which is also validated by breakthrough experiments with longer breakthrough times for CO2. Most importantly, the separation performance is largely unaffected in the presence of moisture of simulated flue gas stream. Temperature-programmed desorption (TPD) analysis shows the ease of the regeneration process, and the performance was verified for multiple cycles. In order to understand the structure-function relationship at the atomistic level, grand canonical Monte Carlo (GCMC) calculation was performed, indicating that the primary binding site for CO2 is between the sulfone moieties in IITKGP-12. Selleckchem Romidepsin CO2 is attracted to the bonded structure (V-shape) of the sulfone moieties in a perpendicular fashion, where CCO2 is aligned with S, and the CO2 axis bisects the SO2 axis. Thus, the strategic approach to immobilize the polar sulfone moiety with a high number of inherent stronger M-N coordination and the absence of coordination unsaturation made this MOF potential toward practical CO2 separation applications.Paget disease of bone is a benign disorder characterized by focal areas of increased bone turnover in one or more skeletal sites. It usually affects older adults, and men are at a higher risk than women. Any bone may be affected, but the disease has a high preference for the pelvis, spine, skull, and long bones. Pain is the most common symptom, and presentation of the disease may depend on which bones are affected, the extent of involvement, and the presence of complications. Paget disease of bone may be asymptomatic, and suspicion arises from incidental findings of elevated serum alkaline phosphatase levels on routine blood work or abnormalities on imaging tests performed for an unrelated cause. Evidence-based guidelines recommend the use of plain radiography and serum alkaline phosphatase testing for initial diagnosis and radionuclide scans for delineation of the extent of disease. Treatment with nitrogen-containing bisphosphonates is recommended in active disease or when risk of complications is possible. Complications of the disease include arthritis, gait changes, hearing loss, nerve compression syndromes, and osteosarcoma. Total serum alkaline phosphatase is the suggested marker for assessing treatment response when high bone turnover occurs, and it should be measured at three to six months to evaluate initial response. Early diagnosis of Paget disease of bone remains key to its management because patients generally have a good prognosis if treatment is initiated before major complications arise. The primary care physician may need to consult with a specialist for confirmation of diagnosis and initiation of treatment.The demand for house calls is increasing because of the aging U.S. population, an increase in patients who are homebound, and the acknowledgment of the value of house calls by the public and health care industry. Literature from current U.S. home-based primary care programs describes health care cost savings and improved patient outcomes for older adults and other vulnerable populations. Common indications for house calls are management of acute or chronic illnesses, coordination of a post-hospitalization transition of care, health assessments, and end-of-life care. House calls may also include observation of activities of daily living, medication reconciliation, nutrition assessment, evaluation of primary caregiver stress, and the evaluation of patient safety in the home. Physicians can use the INHOMESSS mnemonic (impairments/immobility, nutrition, home environment, other people, medications, examination, safety, spiritual health, services) as a checklist for providing a comprehensive health assessment. This article reviews key considerations for family physicians when preparing for and conducting house calls or leading teams that provide home-based primary care services. House calls, with careful planning and scheduling, can be successfully and efficiently integrated into family medicine practices, including residency programs, direct primary care practices, and concierge medicine.Henoch-Schönlein purpura, now called immunoglobulin A (IgA) vasculitis, is a systemic, immune complex-mediated, small-vessel leukocytoclastic vasculitis characterized by nonthrombocytopenic palpable purpura, arthritis, and abdominal pain. It is the most common vasculitis in children but can also occur in adults. Diagnostic testing is required only to exclude other etiologies of purpura, to identify renal involvement, and, if indicated, to determine its extent with biopsy. Imaging or endoscopy may be needed to assess organ complications. IgA vasculitis spontaneously resolves in 94% of children and 89% of adults, making supportive treatment the primary management strategy. However, a subset of patients experience renal involvement that can persist and relapse years later. Additional complications can include gastrointestinal bleeding, orchitis, and central nervous system involvement. Systematic reviews have shown that steroids do not prevent complications and should not be used prophylactically. However, randomized trials have demonstrated success with high-dose steroids, cyclosporine, and mycophenolate in treating glomerulonephritis and other complications.