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These results shed light on the rich polymorphism of Na3PS4 and are relevant for a range host of high-performance materials deriving from the Na3PS4 structural archetype.In many countries, statistics from household consumption and expenditure surveys are increasingly being used to inform policies and programs. In household surveys, foods are typically reported as they are acquired (the majority are raw). However, the micronutrient content of some foods diminishes during processing and cooking. Using food consumption data from the 2015/16 Kenya Integrated Household Budget Survey, this study analyzes whether mean consumption estimates of dietary energy, macronutrients, and eight micronutrients are equivalent (applying a two-side paired equivalence test) when matching foods (1) considering the nutrient content in raw foods (as reported in the survey), and (2) considering the nutrient content in foods as typically consumed, thus applying yield and retention factors as needed. Both food matching approaches rendered statistically equivalent mean consumption estimates, at national and county levels, for dietary energy, protein, fats, available carbohydrates, total fiber, calcium and zinc. Non-equivalent means were found for iron, vitamins A, B1, B2, B12, and C. The higher differences between the means were, in percentage change, for vitamin C (47 %), B1 (34 %) and B12 (26 %).In 2021, it is thirty years since the dissolution of the Soviet Union. This paper examines the evolution of Central Asia's five national economies since 1991 and their economic prospects. The 1990s were dominated by nation-building and the transition from central planning. By 2000, the transition from central planning was essentially complete and the varieties of market-based economies have changed little in the 21st century. Political systems, established in the 1990s around a general pattern of strong presidencies, also changed little, apart from in Kyrgyzstan. Between 1999 and 2014, national economic fortunes were largely shaped by the resource boom. Since the end of the boom, to re-orient Central Asia from dependence on primary product exports and remittances to more diversified outward-oriented economies, domestic change will be necessary. This paper assesses the pressures for economic reform and the forces resistant to change. The economic context includes an improved infrastructure for overland trade across Eurasia as well as an uncertain global trading system and the consequences of the COVID-19 epidemic. The political context includes autocratic non-democracies with an elite that may be content with the unreformed economy, and generational change in leadership. Whereas the initial presidents had spent their entire lives in the planned economy, the current presidents have spent most of their adult lives in market-based economies, mirroring similar changes in the wider population, and may be less resistant to market-based reform and integration into the global economy.ZnO is a worldwide used activator for a rubber vulcanization process, which promotes fast curing kinetics and high cross-linking densities of rubber nanocomposites (NCs). However, its extended use together with leaching phenomena occurring during the production and life cycle of rubber products, especially tires, entails potential environmental risks, as ecotoxicity toward aquatic organisms. Pushed by this issue, a novel activator was developed, which introduces highly dispersed and active zinc species in the vulcanization process, reducing the amount of employed ZnO and keeping high the curing efficiency. The activator is constituted by Zn(II) single sites, anchored on the surface of SiO2 nanoparticles (NPs) through the coordination with functionalizing amino silane groups. It behaves as a double-function material, acting at the same time as a rubber reinforcing filler and a curing activator. The higher availability and reactivity of the single-site Zn(II) centers toward curative agents impart faster kinetics and higher efficiency to the vulcanization process of silica/isoprene NCs, compared to conventionally used ZnO activators. Moreover, the NCs show a high cross-linking degree and improved dynamic mechanical properties, despite the remarkably lower amount of zinc employed than that normally used for rubber composites in tires. Finally, the structural stability of Zn(II) single sites during the curing reactions and in the final materials may represent a turning point toward the elimination of zinc leaching phenomena.Associated to a finite measure on the real line with finite moments are recurrence coefficients in a three-term formula for orthogonal polynomials with respect to this measure. These recurrence coefficients are frequently inputs to modern computational tools that facilitate evaluation and manipulation of polynomials with respect to the measure, and such tasks are foundational in numerical approximation and quadrature. Although the recurrence coefficients for classical measures are known explicitly, those for nonclassical measures must typically be numerically computed. We survey and review existing approaches for computing these recurrence coefficients for univariate orthogonal polynomial families and propose a novel "predictor-corrector" algorithm for a general class of continuous measures. We combine the predictor-corrector scheme with a stabilized Lanczos procedure for a new hybrid algorithm that computes recurrence coefficients for a fairly wide class of measures that can have both continuous and discrete parts. We evaluate the new algorithms against existing methods in terms of accuracy and efficiency.Anomia (word-finding difficulties) is the hallmark of aphasia, an acquired language disorder most commonly caused by stroke. Assessment of speech performance using picture naming tasks is a key method for both diagnosis and monitoring of responses to treatment interventions by people with aphasia (PWA). Currently, this assessment is conducted manually by speech and language therapists (SLT). Surprisingly, despite advancements in automatic speech recognition (ASR) and artificial intelligence with technologies like deep learning, research on developing automated systems for this task has been scarce. Here we present NUVA, an utterance verification system incorporating a deep learning element that classifies 'correct' versus' incorrect' naming attempts from aphasic stroke patients. When tested on eight native British-English speaking PWA the system's performance accuracy ranged between 83.6% to 93.6%, with a 10-fold cross-validation mean of 89.5%. This performance was not only significantly better than a baseline created for this study using one of the leading commercially available ASRs (Google speech-to-text service) but also comparable in some instances with two independent SLT ratings for the same dataset.Sleep has clear importance for academic success. However, most research in this area has focused on older children and adolescents and has used narrow measures of academic achievement, overlooking the importance of early sleep problems in shaping children's classroom behaviors that support academic success. Using a community sample (N = 276, 50% female), the current study examined associations between parent-reported preschool sleep problems (M age = 3.84, SD = 0.83) and three dimensions of classroom engagement coded during live classroom observations in the first grade (M age = 6.72, SD = 0.34). The moderating role of family socioeconomic status (SES) was also considered. A multivariate multilevel model found that more preschool sleep problems were associated with less focused engagement (defined as involvement in academic tasks, such as writing or asking questions), but more competing responses (defined as inappropriate or distracting behaviors). Preschool sleep problems were not associated with task management (defined as preparation for academic tasks, such as locating classroom materials). Although family SES did not moderate any of these associations, higher income-to-needs ratios in preschool were associated with more focused engagement and fewer competing responses. Findings highlight the role of early sleep problems in classroom behaviors that facilitate academic success. Targeting sleep problems prior to the school transition may serve as a useful approach to optimizing learning conditions during this key developmental period.The ongoing SARS-CoV-2 pandemic has emphasized the importance of technologies to rapidly detect emerging pathogens and understand their interactions with hosts. Platforms based on the combination of biological recognition and electrochemical signal transduction, generally termed bioelectrochemical platforms, offer unique opportunities to both sense and study pathogens. Improved bio-based materials have enabled enhanced control over the biotic-abiotic interface in these systems. These improvements have generated platforms with the capability to elucidate biological function rather than simply detect targets. This advantage is a key feature of recent bioelectrochemical platforms applied to infectious disease. Here, we describe developments in materials for bioelectrochemical platforms to study and detect emerging pathogens. The incorporation of host membrane material into electrochemical devices has provided unparalleled insights into the interaction between viruses and host cells, and new capture methods have enabled the specific detection of bacterial pathogens, such as those that cause secondary infections with SARS-CoV-2. As these devices continue to improve through the merging of hi-tech materials and biomaterials, the scalability and commercial viability of these devices will similarly improve.The mental health of law enforcement officers (LEO) is critical to the safety and well-being of the officers and the public they serve. L-Kynurenine However, LEO face significant on-the-job stressors that undermine mental health, and there is a lot to be learned about when and how LEO seek and enter mental health services. The present study sought to explore variables related to mental health seeking behavior, the role of social engagement and social pressure in the decision to seek mental health services, and the most common pathways into mental health utilized by LEO. A small sample of 86 LEO were recruited from the social media page of a law enforcement nonprofit support organization to take several self-report measures on past mental health service usage and intentions to seek future services, the Inventory of Attitudes Toward Seeking Mental Health Services, the Professional Quality of Life Survey, and a measure of social engagement on mental health topics. Results indicate that while a number of factors are associated with intentions to seek future services, the primary factor in past mental health seeking behavior was secondary traumatic stress. Those who sought mental health services reported higher social engagement and social pressure to seek help. LEO entered mental health services for a variety of reasons and through a variety of provider options, such that no one provider source was preferred. Though the present study was limited by a small sample size, reliance on self-report measures, and occurred during a time of civil unrest that sparked the "defund the police" movement, the results serve as a starting point for understanding the pathways into mental health services for LEO and the roles of secondary trauma and prior mental health service experience.