Fordthomas8677

The main dietary contributors of selenium, chromium, arsenic and cadmium were meat, edible fungi and algae, rice, and rice, respectively. The study supported the consumption of selenium-rich agro-food for effective selenium supplement, but also emphasized potential risk from associated metals in selenium-rich agro-food, especially chromium.A novel GAC-Fe-Cu ternary micro-electrolysis system was synthesized for the removal of p-chloronitrobenzene (p-CNB) under oxic conditions. p-CNB could be efficiently removed by GAC-Fe-Cu at a wide initial pH range of 1.0-9.0. In particular, the p-CNB removal efficiency of 96.96 % was obtained at initial pH of 7.2, and the degradation (44.96 %) was the major removal pathway. Additionally, reduction and oxidation simultaneously contributed to the degradation of p-CNB. The results indicated that OH was the prime reactive species under acidic conditions while O2- dominated the degradation of p-CNB under neutral conditions. Reduction reaction was remarkably enhanced in the presence of dissolved oxygen and the iron corrosion could be accelerated by in-situ generated H2O2. Furthermore, XPS analysis of GAC-Fe-Cu revealed the surface-mediated electron transfer and oxidant generation process. The excellent degradation efficiency of p-CNB at initial pH of 7.2 was attributed to the enhanced electron selectivity of GAC-Fe-Cu as well as the high selectivity of near-surface generated O2- toward p-CNB and its intermediate products.Colored photonic TiO2 photoelectrodes have been prepared by a simple anodizing-annealing method. Traditionally, the photoelectrocatalytic (PEC) properties of the film are obtained by measuring the actual decomposition of organic pollutants under ultraviolet or visible light, which may take tens of minutes or even hours. Here, through the combined analysis of the apparent features and PEC properties, we found that the structure would affect the color and optical performance, and the films with different colors showed different PEC performance. Interestingly, after repeated verifications, we got a rule that the PEC performance of the TiO2 films decreased in the order with typical color of yellow, blue-green, dark yellow, blue, yellow-grey, and purple. Therefore, we provide a new idea for the visualization screening of PEC performance for the film photoelectrodes, that is, color can be used as a quick selection indicator for TiO2 films.This paper comprises several assays aiming to identify the basis for the bioremediation of mine-impacted water (MIW). To do so, the conditions for build anoxic microcosms for treating this effluent were varied, containing MIW, and a source of chitin, to biostimulate sulfate-reducing bacteria (SRB). The chitin sources were commercial chitin (CHIT) and shrimp shell (SS), which in addition to chitin, contains CaCO3, and proteins in its composition. The CHIT assays were not successful in sulfate-reduction, even when the pH was increased with CaCO3. However, in all SS assays the SRB development was successful (85% sulfate removal for assay 3), including the metal-free (MF-SS) assay (75% for assay 5). selleck chemicals llc High-throughput sequencing analysis revealed the structure of bacterial community in the SS assay the most abundant genera were Clostridium and Klebsiella, both fermentative and chitinase producers; a few SRB from the genera Desulfovibrio and Desulfosporosinus were also detected. In the MF-SS assay, Desulfovibrio genuswas detected but Comamonas was dominant. It could be deduced that SS is a suitable substrate for SRB development, but CHIT is not. The sulfate-reduction process was provided by the cooperation between fermentative/chitinase-producer bacteria together with SRB, which leads to efficient MIW treatment, removing sulfate and metallic ions.Polycyclic aromatic hydrocarbons (PAHs) are one of the most widespread persistent organic pollutants (POPs) in marine environment. Benzo[a]pyrene (B[a]P), the most toxic carcinogen of PAHs, is widely studied as a representative that interferes with lipid metabolism. However, the underlying molecular mechanisms of lipid metabolism by B[a]P interference towards bivalve, one of the marine-pollution bio-indicators have not been elucidated yet, especially during gonadal development which is closely associated with lipids. In this study, female scallops Chlamys farreri were cultured with natural and 4 μg/L B[a]P exposed seawater, respectively, and a multi-stage (proliferative, growth, mature, and spawn stage) ovarian transcriptome profiling was performed to decipher the reproductive stage-dependence disturbing mechanisms on lipid metabolism caused by B[a]P in bivalves. The results revealed the potential molecular mechanism of B[a]P-induced triglycerides (TGs) accumulation, which probably resulted from the collaboraive mechanisms of bivalves under POPs stress.Tralopyril, an antifouling biocide, widely used in antifouling systems to prevent underwater equipment from biological contamination, which can pose a potential risk to aquatic organisms and human health. However, there is little information available on the toxicity of tralopyril to aquatic organisms. Herein, zebrafish (Danio rerio) were used to investigate the toxicity mechanisms of tralopyril and a series of developmental indicators, thyroid hormones, gene expression and metabolomics were measured. Results showed that tralopyril significantly decreased the heart-beat and body length of zebrafish embryos-larvae exposed to 4.20 μg/L or higher concentrations of tralopyril and also induced developmental defects including pericardial hemorrhage, spine deformation, pericardial edema, tail malformation and uninflated gas bladder. Tralopyril decreased the thyroid hormone concentrations in embryos and changed the transcriptions of the related genes (TRHR, TSHβ, TSHR, Nkx2.1, Dio1, TRα, TRβ, TTR and UGT1ab). Additionally, metabolomics analysis showed that tralopyril affected the metabolism of amino acids, energy and lipids, which was associated with regulation of thyroid system. Furthermore, this study demonstrated that alterations of endogenous metabolites induced the thyroid endocrine disruption in zebrafish following the tralopyril treatment. Therefore, the results showed that tralopyril can induce adverse developmental effects on zebrafish embryos by disrupting the thyroid system and metabolism.