Wattsguldbrandsen4693

The rule-based AUROC for the grouped categories of patient documented to have family or friends (0.972, 95% CI 0.934-1.000), visit by family/friend (0.882 95% CI 0.820-0.943) and phone call with family/friend (0.975, 95% CI 0.952-0.998) were high.

We report an automated method to quantify communication between healthcare professionals and family members of adult patients from free-text EMRs. A rule-based NLP approach had better overall operating characteristics than a machine learning approach.

NLP can automatically and accurately measure frequency and mode of documented family visitation and communication from unstructured free-text EMRs, to support patient- and family-centered care initiatives.

NLP can automatically and accurately measure frequency and mode of documented family visitation and communication from unstructured free-text EMRs, to support patient- and family-centered care initiatives.We investigate the geometric and electronic properties of single-atom catalysts (SACs) within metal-organic frameworks (MOFs) with respect to electrocatalytic CO2 reduction as a model reaction. A series of mid-to-late 3d transition metals have been immobilised within the microporous cavity of UiO-66-NH2. By employing Rietveld refinement of new-generation synchrotron diffraction, we not only identified the crystallographic and atomic parameters of the SACs that are stabilised with a robust MN(MOF) bonding of ca. 2.0 Å, but also elucidated the end-on coordination geometry with CO2. A volcano trend in the FEs of CO has been observed. In particular, the confinement effect within the rigid MOF can greatly facilitate redox hopping between the Cu SACs, rendering high FEs of CH4 and C2H4 at a current density of -100 mA cm-2. Although only demonstrated in selected SACs within UiO-66-NH2, this study sheds light on the rational engineering of molecular interactions(s) with SACs for the sustainable provision of fine chemicals.Two-dimensional (2D) materials have brought a spectacular revolution in fundamental research and industrial applications due to their unique physical properties of atomically thin thickness, strong light-matter interaction, unity valley polarization and enhanced many-body interactions. To fully explore their exotic physical properties and facilitate potential applications in electronics and optoelectronics, an effective and versatile characterization method is highly demanded. Among the many methods of characterization, optical second harmonic generation (SHG) has attracted broad attention because of its sensitivity, versatility and simplicity. The SHG technique is sufficiently sensitive at the atomic scale and therefore suitable for studies on 2D materials. Tulmimetostat order More importantly, it has the capacity to acquire abundant information ranging from crystallographic, and electronic, to magnetic properties in various 2D materials due to its sensitivity to both spatial-inversion symmetry and time-reversal symmetry. These advantages accompanied by its characteristics of non-invasion and high throughput make SHG a powerful tool for 2D materials. This review summarizes recent experimental developments of SHG applications in 2D materials and also provides an outlook of potential prospects based on SHG.Novel 4,4'-(((2,4,8,10-tetraoxaspiro[5.5]undecane-3,9-diyl)bis(2-methylpropane-2,1-diyl))bis(oxy)) (SUBO) bridged ball-type metallophthalocyanines were synthesized starting from 4,4'-(((2,4,8,10-tetraoxaspiro[5.5]undecane-3,9-diyl)bis(2-methylpropane-2,1-diyl))bis(oxy))diphthalonitrile with convenient metal salts in 2-N,N-dimethylaminoethanol. A new bisphthalonitrile compound was obtained from 2,2'-(2,4,8,10-tetraoxaspiro[5.5]undecane-3,9-diyl)bis(2-methylpropan-1-ol) and 4-nitrophthalonitrile in acetonitrile at reflux temperature in the presence of potassium carbonate as a catalyst. The structural characterization of the compounds was performed by elemental analysis, and infrared, ultraviolet-visible and matrix-assisted laser desorption/ionization time-of-flight mass spectroscopic methods. Nonlinear absorptions of the phthalocyanine complexes were measured using the Z-scan technique with 7 ns pulse duration at a 532 nm wavelength. It is obvious that ball-type copperphthalocyanine has a high nonlinear absorption coeffıcient and imaginary component of the third-order susceptibility compared to other complexes. Therefore, ball-type copperphthalocyanine can be regarded as a very good candidate for optical limiting applications. Density functional theory was used for geometry optimizations and time-dependent density functional theory calculations of electronic transitions in order to compare with the experimental results. Molecular orbital and nonlinear optical analyses were also performed with density functional theory at the CAM-B3LYP/6-31G(d,p)/LANL2DZ level. The nonlinear optical analyses show that ball-type copperphthalocyanine has significantly better nonlinear optical properties in comparison to a common reference compound, urea.Using ultrafast spectroscopy, we investigate the photophysics of water-processable nanoparticles composed of a block copolymer electron donor and a fullerene derivative electron acceptor. The block copolymers are based on a poly[2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b']dithiophene)-alt-4,7-(2,1,3-benzothiadiazole)] rod, which is covalently linked with 2 or 100 hydrophilic coil units. In both samples the photogenerated excitons in the blend nanoparticles migrate in tens of ps to a donor/acceptor interface to be separated into free charges. However, transient absorption spectroscopy indicates that increasing the coil length from 2 to 100 units results in the formation of long living charge transfer states which reduce the charge generation efficiency. Our results shed light on the impact of rod-coil copolymer coil length on the blend nanoparticle morphology and provide essential information for the design of amphiphilic rod-coil block copolymers to increase the photovoltaic performances of water-processable organic solar cell active layers.A graphene/Fe loaded polyester fabric (PET) with robust electrical and catalytic properties has been successfully developed for the first time via a simple coating-incorporation method using hyperbranched poly(amidoamine) (PAMAM) dendrimer as the binder. Both graphene oxide (GO/rGO) and zerovalent iron (Fe0) nanoparticles were loaded on the polyester fabric surface before and after chemical grafting of PAMAM. Full characterization of fabrics before and after modifications has been performed by sessile droplet goniometry, ζ-potential, K/S coating evenness, SEM, XPS, FTIR, TGA and DSC analyses. The results showed successful and uniform coating of GO/rGO and loading of Fe0 on PET and also showed the correlation between the type of chemical moiety responsible for uniform GO coating, high Fe0 loading and their electrical and catalytic activities. Sheet resistance (Rsh) analysis was carried out to measure the conductivity of the samples. The lowest Rsh (corresponding to high conductivity) was found in PET-PAM-rGO-Fe0 (0.