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Among the setups, the bioreactor with Fe3O4 additives was found to be the most efficient, with an average daily biogas production of 40 mL/day and a cumulative yield of 1117 mL/day. The kinetic dynamics were evaluated with the cumulative biogas produced by each bioreactor via the first order modified Gompertz and Chen and Hashimoto kinetic models. The modified Gompertz model was found to be the most reliable, with good predictability.A unique morphological Sesamum radiatum oil/polyvinylpyrrolidone/gold polymeric bionanocomposite film was synthesized using the S. radiatum oil dispersed in a polymeric polyvinylpyrrolidone (PVP) matrix and decorated with gold nanoparticles (AuNPs). The chemical and physical characteristics as well as the thermal stability of the synthesized bionanocomposite film were investigated using various spectroscopic and microscopic techniques. The microscopic analysis confirmed well dispersed AuNPs in the PVP- S. radiatum oil matrix with particle size of 100 nm. Immunomodulatory and antiprotozoal potentials of the suggested bionanocomposite film were evaluated for lipopolysaccharide-induced BV-2 microglia and against L. amazonensis, L. mexicana promastigotes and T. cruzi epimastigotes, respectively. The results exerted outstanding reduction of inflammatory cytokines' (IL-6 and TNFα) secretions after pretreatment of bionanocomposite. The bionanocomposite exhibited large inhibitory effects on certain cell signaling components that are related to the activation of expression of proinflammatory cytokines. Additionally, AuNPs and bionanocomposite exhibited excellent growth inhibition of L. mexicana and L. amazonensis promastigotes with IC50 (1.71 ± 1.49, 1.68 ± 0.75) and (1.12 ± 1.10, 1.42 ± 0.69), respectively. However, the nanomaterials showed moderate activity towards T. cruzi. All outcomes indicated promising immunomodulatory, antiprotozoal, and photocatalytic potentials for the synthesized S. radiatum oil/PVP/Au polymeric bionanocomposite.Tissue engineering has focused on the development of biomaterials that emulate the native extracellular matrix. Therefore, the purpose of this research was oriented to the development of nanofibrillar bilayer membranes composed of polycaprolactone with low and medium molecular weight chitosan, evaluating their physicochemical and biological properties. Two-bilayer membranes were developed by an electrospinning technique considering the effect of chitosan molecular weight and parameter changes in the technique. Subsequently, the membranes were evaluated by scanning electron microscopy, Fourier transform spectroscopy, stress tests, permeability, contact angle, hemolysis evaluation, and an MTT test. From the results, it was found that changes in the electrospinning parameters and the molecular weight of chitosan influence the formation, fiber orientation, and nanoarchitecture of the membranes. Climbazole Likewise, it was evidenced that a higher molecular weight of chitosan in the bilayer membranes increases the stiffness and favors polar anchor points. This increased Young's modulus, wettability, and permeability, which, in turn, influenced the reduction in the percentage of cell viability and hemolysis. It is concluded that the development of biomimetic bilayer nanofibrillar membranes modulate the physicochemical properties and improve the hemolytic behavior so they can be used as a hemocompatible biomaterial.This study is focuses on the investigation of the effect of using TiO2 short nanofibers as a reinforcement of an Al matrix on the corrosion characteristics of the produced nanocomposites. The TiO2 ceramic nanofibers used were synthesized via electrospinning by sol-gel process, then calcinated at a high temperature to evaporate the residual polymers. The fabricated nanocomposites contain 0, 1, 3 and 5 wt.% of synthesized ceramic nanofibers (TiO2). Powder mixtures were mixed for 1 h via high-energy ball milling in a vacuum atmosphere before being inductively sintered through a high-frequency induction furnace at 560 °C for 6 min. The microstructure of the fabricated samples was studied by optical microscope and field emission scanning electron microscope (FESEM) before and after corrosion studies. Corrosion behavior of the sintered samples was evaluated by both electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques (PPT) in 3.5% NaCl solution for one hour and 24-h immersion times. The results show that even though the percentage of ceramic nanofibers added negatively control corrosion resistance, it is still possible to increase resistance against corrosion for the fabricated nanocomposite by more than 75% in the longer exposure time periods.Orthokeratology lenses are commonly used for myopia control, especially in children. Tear lipids and proteins are immediately adsorbed when the lens is put on the cornea, and protein deposition may cause discomfort or infection. Therefore, we established an in vitro protein deposition analysis by mimicking the current cleaning methods for orthokeratology lens wearers for both short-term and long-term period. The results showed that the amounts of tear proteins accumulated daily and achieved a balance after 14 days when the lens was rubbed to clean or not. Protein deposition also affected the optical characteristics of the lens regardless of cleaning methods. Our results provided an in vitro analysis for protein deposition on the lens, and they may provide a potential effective method for developing care solutions or methods that can more effectively remove tear components from orthokeratology lenses.As lactoferrin (LF) plays an essential role in physiological processes, the detection of LF has attracted increasing attention in the field of disease diagnosis. However, most current methods require expensive equipment, laborious pretreatment, and long processing time. In this work, carboxyl-rich carbon dots (COOH-CDs) were facilely prepared through a one-step, low-cost hydrothermal process with tartaric acid as the precursor. The COOH-CDs had abundant carboxyl on the surface and showed strong blue emission. Moreover, COOH-CDs were used as a fluorescent sensor toward Fe3+ and showed high selectivity for Fe3+ with the limit of detection (LoD) of 3.18 nM. Density functional theory (DFT) calculations were performed to reveal the mechanism of excellent performance for Fe3+ detection. Meanwhile, COOH-CDs showed no obvious effect on lactobacillus plantarum growth, which means that COOH-CDs have good biocompatibility. Due to the nontoxicity and excellent detection performance for Fe3+, COOH-CDs were employed as a fluorescent sensor toward LF and showed satisfying performance with an LoD of 0.776 µg/mL, which was better than those of the other methods.Polyether urethane (PU)-based magnetic composite materials, containing different types and concentrations of iron oxide nanostructures (Fe2O3 and Fe3O4), were prepared and investigated as a novel composite platform that could be explored in different applications, especially for the improvement of the image quality of MRI investigations. Firstly, the PU structure was synthetized by means of a polyaddition reaction and then hematite (Fe2O3) and magnetite (Fe3O4) nanoparticles were added to the PU matrices to prepare magnetic nanocomposites. The type and amount of iron oxide nanoparticles influenced its structural, morphological, mechanical, dielectric, and magnetic properties. Thus, the morphology and wettability of the PU nanocomposites surfaces presented different behaviours depending on the amount of the iron oxide nanoparticles embedded in the matrices. Mechanical, dielectric, and magnetic properties were enhanced in the composites' samples when compared with pristine PU matrix. In addition, the investigation of in vitro cytocompatibility of prepared PU nanocomposites showed that these samples are good candidates for biomedical applications, with cell viability levels in the range of 80-90%. Considering all the investigations, we can conclude that the addition of magnetic particles introduced additional properties to the composite, which could significantly expand the functionality of the materials developed in this work.A series of conjugated polymers (CPs) emitting red, green, and blue (RGB) fluorescence were synthesized via the Suzuki coupling polymerization. Polymer dots (Pdots) were fabricated by the reprecipitation method from corresponding CPs, in which the Pdot surface was functionalized to have an allyl moiety. The CP backbones were based on the phenylene group, causing the Pdots to show identical ultraviolet-visible absorption at 350 nm, indicating that the same excitation wavelength could be used. The Pdots were covalently embedded in poly(N-isopropylacrylamide) (PNIPAM) hydrogel for further use as a thermoresponsive moiety in the polymer hydrogel. The polymer hydrogel with RGB emission colors could provide thermally reversible fluorescence changes. The size of the hydrogel varied with temperature change because of the PNIPAM's shrinking and swelling. The swollen and contracted conformations of the Pdot-embedded PNIPAM enabled on-and-off fluorescence, respectively. Fluorescence modulation with 20 to 80% of the hydrogel was possible via thermoreversibility. The fluorescent hydrogel could be a new fluorescence-tuning hybrid material that changes with temperature.In this work, a one-step electrospinning technique has been implemented for the design and development of functional surfaces with a desired morphology in terms of wettability and corrosion resistance by using polycaprolactone (PCL) and zinc oxide nanoparticles (ZnO NPs). The surface morphology has been characterized by confocal microscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM) and water contact angle (WCA), whereas the corrosion resistance has been evaluated by Tafel polarization curves. Strict control over the input operational parameters (applied voltage, feeding rate, distance tip to collector), PCL solution concentration and amount of ZnO NPs have been analyzed in depth by showing their key role in the final surface properties. With this goal in mind, a design of experiment (DoE) has been performed in order to evaluate the optimal coating morphology in terms of fiber diameter, surface roughness (Ra), water contact angle (WCA) and corrosion rate. It has been demonstrated that the solution concentration has a significant effect on the resultant electrospun structure obtained on the collector with the formation of beaded fibers with a higher WCA value in comparison with uniform bead-free fibers (dry polymer deposition or fiber-merging aspect). In addition, the presence of ZnO NPs distributed within the electrospun fibers also plays a key role in corrosion resistance, although it also leads to a decrease in the WCA. Finally, this is the first time that an exhaustive analysis by using DoE has been evaluated for PCL/ZnO electrospun fibers with the aim to optimize the surface morphology with the better performance in terms of corrosion resistance and wettability.Natural polymers have proven to be extremely interesting matrices for the immobilization of microbial biomasses, via various mechanisms, in order to bring them into a form easier to handle-the form of composites. This article aimed to study composites based on a residual microbial biomass immobilized in sodium alginate via an encapsulation technique as materials with adsorbent properties. Thus, this study focused on the residual biomass resulting from beer production (Saccharomyces pastorianus yeast, separated after the biosynthesis process by centrifugation and dried at 80 °C)-an important source of valuable compounds, used either as a raw material or for transformation into final products with added value. Thus, the biosorptive potential of this type of composite was tested-presenting in the form of spherical microcapsules 900 and 1500 μm in diameter-in a biosorption process applied to aqueous solutions containing the reactive dye Brilliant Red HE-3B (16.88-174.08 mg/L), studied in a batch system. The preparation and characterization of the obtained polymeric composites (pHPZC, SEM, EDS and FTIR spectra) and an analysis of different equilibrium isotherms (Langmuir, Freundlich and Dubinin-Radushkevich-D-R) were investigated in order to estimate the quantitative characteristic parameters of the biosorption process, its thermal effects, and its possible mechanisms of action.