Loganankersen2710

The tensile strength, tensile modulus, and flexural modulus of the composites prepared using 10-min treated powder with 20 wt% of 40-min treated fibers improved by 20%, 82%, and 98%, respectively, compared to the pure polyethylene samples.At present, high-performance carbon fibers (CFs) are mainly produced from petroleum-based materials. However, the high costs and environmental problems of the production process prompted the development of new precursors from natural biopolymers. This review focuses on the latest research on the conversion of natural lignocellulosic biomass into precursor fibers and CFs. The influence of the properties, advantages, separation, and extraction of lignin and cellulose (the most abundant natural biopolymers), as well as the spinning process on the final CF performance are detailed. Recent strategies to further improve the quality of such CFs are discussed. The importance and application of CFs in sports equipment manufacturing are briefly summarized. While the large-scale production of CFs from natural lignocellulosic biomass and their applications in sports equipment have not yet been realized, CFs still provide a promising market prospect as green and low-cost materials. Further research is needed to ensure the market entry of lignocellulosic biomass-based CFs.Efficient recycling of crosslinked polyethylene has been challenging due to manufacturing difficulties caused by chemical crosslinking. This study focuses on simple processing via solid waste powder generation and particle fining for the subsequent crosslinked polyethylene inclusion and dispersion in rigid polyurethane foam. In addition, the concentration effects of crosslinked polyethylene in polyurethane were studied, showing a well-controlled foam microstructure with uniform pores, retained strength, better thermal degradation resistance, and, more importantly, increased thermal capabilities. Thus, the simple mechanical processing of crosslinked polyethylene and chemical urethane foaming showed the massive potential of recycling large amounts of crosslinked polyethylene in foams for broad applications in food packaging, house insulation, and sound reduction.Urban agriculture plays a vital role in ensuring the self-sufficiency of a great variety of fresh vegetables and nutrients. It promotes a sustainable food system as well as reducing the dependency on imports for the growing population. Urban farming has made it possible for agriculture practices to be implemented anywhere at any time in a sophisticated way. Hydrogel has been introduced in urban agriculture in the past few decades. However, the application of hydrogel in urban agriculture is still being explored in terms of hydrogel types, structure, physical and chemical properties, change due to external factors, and its suitability for different plant species. This review discusses the potentials and limitations of hydrogel in different application conditions. We present the state of knowledge on hydrogel production and crosslinking methods, hydrogel characteristics, water absorption and release mechanisms of hydrogel, hydrogel advantages and limitations, and current and future applications in urban farming.The main aim of this work is to treat sugarcane bagasse agricultural waste and prepare an efficient, promising, and eco-friendly adsorbent material. Biochar is an example of such a material, and it is an extremely versatile and eco-friendly biosorbent to treat wastewater. Crystal violet (CV)-dye and methylene blue (MB)-dye species are examples of serious organic pollutants. Herein, biochar was prepared firstly from sugarcane bagasse (SCB), and then a biochar biosorbent was synthesized through pyrolysis and surface activation with NaOH. SEM, TEM, FTIR, Raman, surface area, XRD, and EDX were used to characterize the investigated materials. The reuse of such waste materials is considered eco-friendly in nature. After that, the adsorption of MB and CV-species from synthetically prepared wastewater using treated biochar was investigated under various conditions. To demonstrate the study's effectiveness, it was attempted to achieve optimum effectiveness at an optimum level by working with time, adsorbent dose, dye etic model. Finally, the data obtained were compared with some works published during the last four years.A typical ballistic protection helmet for ground military troops has an inside laminate polymer composite reinforced with 19 layers of the aramid, which are neither recyclable or biodegradable and are relatively expensive. The hybridization of synthetic aramid with a natural lignocellulosic fiber (NLF) can provide a lower cost and desirable sustainability to the helmet. In the present work, the curaua fiber, one of the strongest NLFs, is, for the first time, considered in non-woven mat layers to partially replace the aramid woven fabric layers. To investigate the possible advantage of this replacement, the tensile and impact properties of aramid/curaua hybrid laminated composites intended for ballistic helmets, in which up to four layers of curaua were substituted for the aramid, were evaluated. Tensile strength, toughness, and elastic modulus decreased with the replacement of the aramid while the deformation of rupture was improved for the replacement of nine aramid layers by two layers of curaua. Preliminary impact tests corroborate the decreasing tendency found in the tensile properties with the replacement of the aramid by curaua. Novel proposed Reduction Maps showed that, except for the replacement of four aramid layers by one layer of curaua, the decrease percentage of any tensile property value was lower than the corresponding volume percentage of replaced aramid, which revealed advantageous hybridization for the replacement of nine or more aramid layers.To increase the human lifespan, healthcare monitoring devices that diagnose diseases and check body conditions have attracted considerable interest. Commercial AgCl-based wet electrodes with the advantages of high conductivity and strong adaptability to human skin are considered the most frequently used electrode material for healthcare monitoring. However, commercial AgCl-based wet electrodes, when exposed for a long period, cause an evaporation of organic solvents, which could reduce the signal-to-noise ratio of biosignals and stimulate human skin. In this context, we demonstrate a dry electrode for a poly(3,4-ethylenedioxythiophene)poly(styrenesulfonate) (PEDOTPSS)-based blended polymer electrode using a combination of PEDOTPSS, waterborne polyurethane (WPU) and ethylene glycol (EG) that could be reused for a long period of time to detect electrocardiography (ECG) and electromyography (EMG). Both ECG and EMG are reliably detected by the wireless real-time monitoring system. In particular, the proposed dry electrode detects biosignals without deterioration for over 2 weeks. Additionally, a double layer of a polyimide (PI) substrate and fluorinated polymer CYTOP induces the strong waterproof characteristics of external liquids for the proposed dry electrodes, having a low surface energy of 14.49 mN/m. In addition, the proposed electrode has excellent degradability in water; it dissolves in hot water at 60 °C.The development of ultra-high-performance concrete (UHPC) is still practically limited due to the scarcity of robust mixture designs and sustainable sources of local constituent materials. This study investigates the engineering characteristics of Styrene Butadiene Rubber (SBR) polymeric fiber-reinforced UHPC with partial substitution of cement at 0, 5 and 20 wt.% with latex polymer under steam and air curing techniques. The compressive and tensile strengths along with capillary water absorption and sulfate resistance were measured to evaluate the mechanical and durability properties. Scanning Electron Microscopy (SEM) was carried out to explore the microstructure development and hydration products in the designed mixtures under different curing regimes. The results indicated that the mixtures incorporating 20 wt.% SBR polymer achieved superior compressive strength at later ages. Additionally, the tensile strength of the polymeric UHPC without steel fibers and with 20% polymers was enhanced by 50%, which promotes the development of novel UHPC mixtures in which steel fibers could be partially replaced by polymer, while enhancing the tensile properties.Temporary scaffolds that mimic the extracellular matrix's structure and provide a stable substratum for the natural growth of cells are an innovative trend in the field of tissue engineering. The aim of this study is to obtain and design porous 2D fibroin-based cell matrices by femtosecond laser-induced microstructuring for future applications in muscle tissue engineering. Ultra-fast laser treatment is a non-contact method, which generates controlled porosity-the creation of micro/nanostructures on the surface of the biopolymer that can strongly affect cell behavior, while the control over its surface characteristics has the potential of directing the growth of future muscle tissue in the desired direction. The laser structured 2D thin film matrices from silk were characterized by means of SEM, EDX, AFM, FTIR, Micro-Raman, XRD, and 3D-roughness analyses. A WCA evaluation and initial experiments with murine C2C12 myoblasts cells were also performed. The results show that by varying the laser parameters, a different structuring degree can be achieved through the initial lifting and ejection of the material around the area of laser interaction to generate porous channels with varying widths and depths. The proper optimization of the applied laser parameters can significantly improve the bioactive properties of the investigated 2D model of a muscle cell matrix.This paper uses a multi-objective optimization method to optimize the injection-molding defects of automotive pedals. Compared with the traditional automotive pedal material, aluminum alloy, the polymer pedal containing glass fibers not only reduces the aluminum pedal by at least half, but also improves the strength and hardness of the fibers by adjusting the orientation of the fibers in all directions. Injection factors include filling time, filling pressure, melt temperature, cooling time, injection time, etc. https://www.selleckchem.com/products/Rapamycin.html For the optimization process influencing factors, herein, we focus on warpage analyzed via flow simulation, and setting warpage parameters and cycle time as discussed by setting different cooling distributions, pressures and temperature schemes. The multi-objective optimization design was mainly used to describe the relationship between cycle time and warpage, and the Pareto boundary was used for cycle time and warpage to identify the deviation function and radial-basis-function network. We worked with a small DOE for building the surface to run SAO programming-which improved the accuracy of the response surface by adding sampling points-terminating the time when the warpage value met the solution requirements, to find out the global optimal solution of the warpage value under different cooling times. Finally, the results highlighted four influencing parameters that match the experimental image of the actual production.The defect and N-doping engineering are critical to developing the highly efficient metal-free electrocatalysts for oxygen reduction reaction (ORR), mainly because they can efficiently regulate the geometric/electronic structures and sur-/interface properties of the carbon matrix. Herein, we provide a facile and scalable strategy for the large-scale synthesis of N-doped porous carbon nanosheets (NPCNs) with hierarchical pore structure, only involving solvothermal and pyrolysis processes. Additionally, the turnover frequency of ORR (TOFORR) was calculated by taking into account the electron-transfer number (n). Benefiting from the trimodal pore structures, high specific surface area, a higher pore volume, high-ratio mesopores, massive vacancies/long-range structural defects, and high-content pyridinic-N (~2.1%), the NPCNs-1000 shows an excellent ORR activity (1600 rpm, js = ~5.99 mA cm-2), a selectivity to four-electron ORR (~100%) and a superior stability in both the three-electrode tests (CP test for 7500 s at 0.