Mirandaskovsgaard6344

Globally, the introduction of Zr in the polymer had several effects on the temperature fragmentation mechanisms of the organometallic polymeric structures (i) instead of stepwise mass losses, continuous fragment release prevailed; (ii) the stability of preceramic polymers was impacted, with relatively good ceramic yields; (iii) it modulated the chemical composition of the generated composites as it led, inter alia, to the consumption of free carbon.The analysis of hundreds of SFRC mixtures compiled from papers published over the last 20 years is reported. This paper is focused on the relationships between the size and dosage of steel fibers and the relative amounts of the constituents of SFRC mixtures. Multiple linear regression is applied to the statistical modeling of such relationships, leading to four equations that show considerable accuracy and robustness in estimating SFRC mixture proportions as a function of fiber content and dimensions, maximum aggregate size, and water-to-cement ratio. The main trends described by these equations are discussed in detail. The importance of the interactions between aggregates, supplementary cementitious materials, and fibers in proportioning SFRC mixtures, as well as implications for workability and stability, are emphasized. The simplicity of these data-driven equations makes them a valuable tool to guide the proportioning of SFRC mixtures. Their predictive performance when used together as a data-driven mix design methodology is confirmed using a validation dataset.Magnesium oxychloride cement (abbreviated as MOC) was prepared using magnesium residue obtained from Li2CO3 extraction from salt lakes as raw material instead of light magnesium oxide. The properties of magnesium residue calcined at different temperatures were researched by XRD, SEM, LSPA, and SNAA. The preparation of MOC specimens with magnesium residue at different calcination temperatures (from 500 °C to 800 °C) and magnesium chloride solutions with different Baume degrees (24 Baume and 28 Baume) were studied. Compression strength tests were conducted at different curing ages from 3 d to 28 d. The hydration products, microstructure, and porosity of the specimens were analyzed by XRD, SEM, and MIP, respectively. The experimental results showed that magnesium residue's properties, the BET surface gradually decreased and the crystal size increased with increasing calcination temperature, resulting in a longer setting time of MOC cement. Additionally, the experiment also indicated that magnesium chloride solution with a high Baume makes the MOC cement have higher strength. The MOC specimens prepared by magnesium residue at 800 °C and magnesium chloride solution Baume 28 exhibited a compressive of 123.3 MPa at 28 d, which met the mechanical property requirement of MOC materials. At the same time, magnesium oxychloride cement can be an effective alternative to Portland cement-based materials. In addition, it can reduce environmental pollution and improve the environmental impact of the construction industry, which is of great significance for sustainable development.The influence of bath hydrodynamics on the resultant micromechanical properties of electrodeposited nickel-cobalt alloy system is investigated. The bath hydrodynamics realized by magnetic stirring is simulated using COMSOL Multiphysics and a region of minimum variation in velocity within the electrolytic cell is determined and validated experimentally. Nickel-cobalt alloy and nickel coating samples are deposited galvanostatically (50 mA/cm2) with varying bath velocity (0 to 42 cm/s). The surface morphology of samples gradually changed from granular (fractal dimension 2.97) to more planar (fractal dimension 2.15) growth type, and the according average roughness decreased from 207.5 nm to 11 nm on increasing the electrolyte velocity from 0 to 42 cm/s for nickel-cobalt alloys; a similar trend was also found in the case of nickel coatings. MDM2 inhibitor The calculated grain size from the X-ray diffractograms decreased from 31 nm to 12 nm and from 69 nm to 26 nm as function of increasing velocity (up to 42 cm/s) for nickel-cobalt and nickel coatings, respectively. Consecutively, the measured Vickers microhardness values increased by 43% (i.e., from 393 HV0.01 to 692 HV0.01) and by 33% (i.e., from 255 HV0.01 to 381 HV0.01) for nickel-cobalt and nickel coatings, respectively, which fits well with the Hall-Petch relation.This study aimed to investigate different types of glasses based on the 46V2O5-46P2O5-(8-x) B2O3-xCuO system in terms of their nuclear radiation shielding properties. Accordingly, five different CuO-doped vanadate glasses were investigated extensively to determine the necessary gamma shielding parameters along with effective conductivity at 300,000 and buildup factors. Phy-x PSD software was used for determination of these vital parameters. Furthermore, these parameters, such as half value layer, tenth value layer, and mean free path were investigated in a broad energy range between 0.015 and 15 MeV. The results revealed that the amount of CuO reinforced in each sample plays an essential role in determination of the shielding abilities of the samples. The sample with the highest CuO content had the highest linear attenuation coefficient and mass attenuation coefficient values. Additionally, the lowest mean free path, half value layer, and tenth value layer values were recorded for glass sample VPCu8. There wae prospective characteristics of CuO-doped glass systems and related glass compositions. CuO-doped glass systems and associated glass compositions have a wide range of properties.The paper presents the experimental results of shrinkage, creep, and prestress loss in concrete with lightweight aggregate obtained by sintering of fly ash. Two concrete mixtures with different proportions of components were tested. Concrete with a density of 1810 and 1820 kg/m3, and a 28-day strength of 56.9 and 58.4 MPa was obtained. Shrinkage and creep were tested on 150 × 250 × 1000 mm3 beams. Creep was tested under prestressing load for 539 days and concrete shrinkage for 900 days. The measurement results were compared with the calculations carried out according to the Eurocode 2 as well as with the results of other research. A very low creep coefficient and lower shrinkage in relation to the calculation results and the results of other research were found. It was also revealed that there is a clear correlation between shrinkage and creep, and the amount of water in the concrete. The value of the creep coefficient during the load holding period was 0.610 and 0.537, which is 56.0 and 49.3% of the value determined from the standard.