Beckeregholm2036
This paper investigates the effects of Ta content on the microstructures, hardness and corrosion behavior of as-cast CoCrFeNiTax alloys. The results indicate that the addition of Ta can change the microstructures of these alloys to dual-phased structures (FCC + HCP), as well as increasing their hardness. #link# This study uses constant galvanostatic/potentiometric methods to measure the polarization curves of CoCrFeNiTa0.1, CoCrFeNiTa0.3 and CoCrFeNiTa0.5 alloys in deaerated 1 M sodium chloride solution at different temperatures. Electrochemical impedance spectroscopy is also used to analyze these alloys in sodium chloride solution. The results indicate that the CoCrFeNiTa0.5 alloy has a eutectic structure and the highest hardness. Furthermore, although the CoCrFeNiTa0.5 alloy has the best corrosion resistance, the CoCrFeNiTa0.3 alloy has the best pitting resistance among these alloys.The restoration and prosthetic rehabilitation of missing teeth are commonly performed using dental implants, which are extremely effective and long-lasting techniques due to their osteointegration ability with the preimplant tissues. Quercetin is a phytoestrogen-like flavonoid well known for its several positive effects on human health, mostly linked to the anti-inflammatory, antioxidant, and antibacterial activities against both Gram-positive and Gram-negative bacteria. Moreover, many studies in dentistry and the maxillofacial fields have highlighted the positive effects of quercetin on osteogenesis, acting on osteoblast activity and angiogenetic process, and promoting soft and hard tissue regeneration. Elafibranor focuses on the role of quercetin on the healing and restoration of bony defects, considering the experimental findings of its application both in vitro and in vivo as a mere compound or in association with scaffolds and dental implants having functionalized surfaces.We present a mean field theory to describe cholesteric elastomers and gels under an external field, such as an electric or a magnetic field, along the helix axis of a cholesteric phase. We study the deformations and volume phase transitions of cholesteric gels as a function of the external field and temperature. Our theory predicts the phase transitions between isotropic (I), nematic (N), and heliconical cholesteric (ChH) phases and the deformations of the elastomers at these phase transition temperatures. We also find volume phase transitions at the I-ChH and the N-ChH phase transitions.Mono-allelic dominant mutations in the desmoplakin gene (DSP) have been linked to known cardiac disorders, such as arrhythmogenic right ventricular cardiomyopathy and dilated cardiomyopathy. During the course of DSP cardiomyopathy, episodes of acute myocardial injury may occur. While their mechanisms remain unclear, myocarditis has been postulated as an underlying cause. We report on an adolescent girl with arrhythmogenic biventricular cardiomyopathy and three acute myocarditis-like episodes in whom we found a novel truncating DSP variant accompanied by a known low penetrance R490K variant in the NLRP3. Upon family screening, other carriers of the DSP variant have been identified in whom only mild cardiac abnormalities were found. We hypothesized that the uncommon course of cardiomyopathy in the proband as well as striking discrepancies in the phenotype observed in her family may be explained by the co-existence of her low penetrance genetic autoinflammatory predisposition.The demands for wearable technologies continue to grow and novel approaches for powering these devices are being enabled by the advent of new energy materials and novel manufacturing strategies. In addition, decreasing the energy consumption of portable electronic devices has created a huge demand for the development of cost-effective and environment friendly alternate energy sources. Energy harvesting materials including piezoelectric polymer with its special properties make this demand possible. Herein, we develop a flexible and lightweight nanogenerator package based on polyvinyledene fluoride (PVDF)/LiCl electrospun nanofibers. The piezoelectric performance of the developed nanogenator is investigated to evaluate effect of the thickness of the as-spun mat on the output voltage using a vibration and impact test. link2 It is found that the output voltage increases from 1.3 V to 5 V by adding LiCl as additive into the spinning solution compared with pure PVDF. link3 The prepared PVDF/LiCl nanogenerator is able to generate voltage and current output of 3 V and 0.5 μA with a power density output of 0.3 μW cm-2 at the frequency of 200 Hz. It is found also that the developed nanogenerator can be utilized as a sensor to measure temperature changes from 30 °C to 90 °C under static pressure. The developed electrospun temperature sensor showed sensitivity of 0.16%/°C under 100 Pa pressure and 0.06%/°C under 220 Pa pressure. The obtained results suggested the developed energy harvesting textiles have promising applications for various wearable self-powered electrical devices and systems.In order to create greener polyurethane (PUR) foams, modified used cooking oils (UCO) were applied as starting resources for the synthesis of bio-polyols. The bio-polyols were produced using transesterification of UCO with diethylene glycol (UCO_DEG) and triethanolamine (UCO_TEA). Next, open-cell PUR foams were synthesized by replacing 20, 40, 60, 80 and 100% of the petrochemical polyol with the bio-polyol UCO_DEG or UCO_TEA. It was observed that an increasing bio-polyol content (up to 60%) led to an increase of the closed cell content. However, a further increase in the bio-polyol content up to 100% resulted in foam cell opening. The bio-foams obtained in the experiment had an apparent density of 13-18 kg/m3. The coefficient of thermal conductivity was determined at three different average temperatures 10, 0 and -10 °C. The PUR bio-foams modified with bio-polyol UCO_TEA had lower values of thermal conductivity, regardless of the average temperature (35.99-39.57 mW/m·K) than the foams modified with bio-polyol UCO_DEG (36.95-43.78 mW/m·K). The compressive strength of most of the bio-foams was characterized by a higher value than the compressive strength of the reference material (without bio-polyol). Finally, it was observed that the bio-materials exhibited dimensional stability at 70 °C.Parthenium weed has been invading native and managed Australian grasslands for almost 40 years. This study quantified the potential of selected plant mixtures to suppress the growth of parthenium weed and followed their response to grazing and their impact upon plant community diversity. The first mixture consisted of predominantly introduced species including Rhodes grass, Bisset bluegrass, butterfly pea and green panic. This mixture produced biomass rapidly and showed tolerance to weed species other than parthenium weed. However, the mixture was unable to suppress the growth of parthenium weed. The second mixture of predominantly native pasture species (including forest bluegrass, Queensland bluegrass, Buffel grass and siratro) produced biomass relatively slowly, but eventually reached the same biomass production as the first mixture 12 weeks after planting. This mixture suppressed parthenium weed re-establishment by 78% compared to the control treatment. Its tolerance to the invasion of other weed species and the maintenance of forage species evenness was also superior. The total diversity was five times higher for the mixture communities as compared to the plant community in the control treatment. Therefore, using the suppressive pasture mixtures may provide an improved sustainable management approach for parthenium weed in grasslands.Piezoelectric polymers characterized by flexibility are sought for applications in microelectronics, medicine, telecommunications, and everyday devices. The objective of this work was to obtain piezoelectric polymeric composites with a cellular structure and to evaluate their usefulness in practice. Composites based on polyolefins (isotactic-polypropylene and polyethylene) with the addition of aluminosilicate fillers were manufactured by extrusion, and then polarized in a constant electric field at 100 V/µm. The content of mineral fillers up to 10 wt% in the polymer matrix enhances its electric stability and mechanical strength. The value of the piezoelectric coefficient d33 attained ~150 pC/N in the range of lower stresses and ~80 pC/N in the range of higher stresses, i.e., at ~120 kPa. The materials exhibited high durability in time, therefore, they can be used as transducers of mechanical energy of the human motion into electric energy. It was demonstrated that one shoe insert generates an energy of 1.1 mJ after a person walks for 300 s. The miniaturized integrated circuits based on polyolefin composites may be applied for the power supply of portable electronics. Due to their high sensitivity, they can be recommended for measuring the blood pulse.The novel severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) has spread to nearly every continent, registering over 1,250,000 deaths worldwide. The effects of SARS-CoV-2 on host targets remains largely limited, hampering our understanding of Coronavirus Disease 2019 (COVID-19) pathogenesis and the development of therapeutic strategies. The present study used a comprehensive untargeted metabolomic and lipidomic approach to capture the host response to SARS-CoV-2 infection. We found that several circulating lipids acted as potential biomarkers, such as phosphatidylcholine 140_226 (area under the curve (AUC) = 0.96), phosphatidylcholine 161_226 (AUC = 0.97), and phosphatidylethanolamine 181_204 (AUC = 0.94). Furthermore, triglycerides and free fatty acids, especially arachidonic acid (AUC = 0.99) and oleic acid (AUC = 0.98), were well correlated to the severity of the disease. An untargeted analysis of non-critical COVID-19 patients identified a strong alteration of lipids and a perturbation of phenylalanine, tyrosine and tryptophan biosynthesis, phenylalanine metabolism, aminoacyl-tRNA degradation, arachidonic acid metabolism, and the tricarboxylic acid (TCA) cycle. The severity of the disease was characterized by the activation of gluconeogenesis and the metabolism of porphyrins, which play a crucial role in the progress of the infection. In addition, our study provided further evidence for considering phospholipase A2 (PLA2) activity as a potential key factor in the pathogenesis of COVID-19 and a possible therapeutic target. To date, the present study provides the largest untargeted metabolomics and lipidomics analysis of plasma from COVID-19 patients and control groups, identifying new mechanisms associated with the host response to COVID-19, potential plasma biomarkers, and therapeutic targets.The tobacco epidemic is one of the most serious public health issues in the world. Tobacco use starts and becomes established primarily during adolescence, and nearly 9 out of 10 cigarette smokers first tried smoking by age 18, with 99% first trying by age 26. This study employed a 2 (advertising appeal emotional vs. rational) by 2 (self-referencing analytical vs. narrative) factorial design in Study 1; and a 2 (relational-interdependent self-construal high and low) by 3 (social relational cue self, friend, and family) factorial design in Study 2. The behavior intention of anti-smoking acted as the measured dependent variable. Samples of 192 (Study 1) and 222 (Study 2) were collected from one of the biggest high schools in northern Taiwan. The results showed advertising appeal and self-referencing had a significant interaction effect on behavior intention (p = 0.040). The results also showed rational appealing advertising is suitable for analytical self-referencing (p = 0.022) and emotional appealing advertising is suitable for narrative self-referencing (p = 0.