Catesengel9826

9 M-1 s-1 and kHSO5-/CET- of 36.6 ± 0.16 M-1 s-1. The addition of 100 μM Fe(II) promoted OH mediated degradation of H1-antihistamines and their N-oxide products. This study demonstrated selective transformation with the potential for extensive degradation employing both the direct and catalytic PMS oxidative processes.The mechanistic role of green copper nanoparticles (CuNPs) in cadmium (Cd) toxicity alleviation in plants is poorly understood. Here, the CuNPs, synthesized by using a bacterium Shigella flexneri SNT22, were confirmed through UV-vis spectroscopy with a characteristic peak at 334.50 nm. Moreover, FT-IR, XRD, SEM, and TEM techniques revealed that the spherical shaped crystals of CuNPs with a size range of 17.24 nm to 38.03 nm were stabilized by coating proteins. Diff ;erent levels of CuNPs (e.g., 25, 50, and 100 mg kg-1 of soil) were examined in pots having Cd-mixed soil to evaluate their effect on wheat plants in a growth chamber under optimal environmental conditions. Treatment of soil with 100 mg kg-1 of CuNPs increased plant length by 44.4 %, shoot dry weight by 28.26 %, nitrogen contents by 41.60 %, and phosphorus contents by 58.79 %, whereas decreased the acropetal Cd translocation by 49.62 %. An increase in the N, P, K+, Ca2+, K+/Na+, and Ca2+/Na+ contents and decrease in the Na+ concentration in wheat plants treated with CuNPs was also recorded. Overall, the results are valuable to establish a green CuNPs-based approach for sustainable wheat growth in metal-contaminated soils.In this work, polyvinyl chloride (PVC) and paper mill sludge (PMS) were co-pyrolyzed under two environments of N2 and CO2. The pyrolysis process was assessed by conducting thermogravimetric analysis (TGA) and monitoring the evolution of gaseous products. The resulting solid composites were characterized using XRD, XPS, BET, and Raman analyzers, and their ability to catalytically activate persulfate (S2O82-) was tested by conducting methyl orange (MO) degradation experiments. Co-pyrolysis of PVC and PMS at the same mass ratio (11) in CO2 resulted in the highest production of H2 and CO (0.36 mol % H2 at 480 °C & 1.53 mol % CO at 700 °C). The characterization results revealed that the composite consisted of Fe3O4, highly graphitic carbon, and mesoporous structure. In MO oxidation experiments, the co-pyrolyzed composite actively generated OH and SO4- by activating S2O82- to achieve complete removal of 5 mg L-1 of MO during 100 min at acidic-neutral pH condition. The composite was also able to complete 3 successive cycles of MO oxidation without deactivation. Consequently, the feasibility of achieving the simultaneous production of energy resources and catalyst via industrial wastes utilization in pyrolytic process was demonstrated.TiO2-embedded expanded polystyrene (TiO2EPS) balls were produced in large quantities using continuous manufacturing plants and four processes (i.e., fixing-coating-freeze drying-air drying). Two mesocosms [i.e., a photocatalytic zone (PZ) vs. a control zone (CZ)] and in-situ real-time monitoring device were installed to monitor the water quality within the hypereutrophic stream and to elucidate the long-term effect of TiO2EPS balls on the growth inhibition of harmful algae for two years (i.e., 2016-2017). The difference in the concentrations of both Chl-a and phycocyanin between CZ and PZ was temporally variable and was significant from August to October with higher solar irradiation levels. Although the effective depth of TiO2EPS balls varied as a complex function of the photocatalytic reactions of TiO2EPS balls and various environmental factors, the photooxidation effect of TiO2EPS balls decreased with the increase in water depth and the effective water depth for growth inhibition was less than 0.5 m. Compare to bimodal distributions in concentrations of both Chl-a and phycocyanin in CZ, both shifted and lowered peaks were mainly due to the photocatalytic degradation and irradiation shading under natural solar irradiation by applying TiO2EPS balls in hypereutrophic water body. Consequently, the TiO2EPS balls developed in this study can prevent both growth and reproduction of harmful algae in hypereutrophic water body, regardless of the environmental factors.Poly-γ-glutamic acid (γ-PGA) could efficiently stabilize heavy metals in the environment. This study characterized the effects of two plant growth-promoting and γ-PGA-producing bacteria Bacillus subtilis W7 and Bacillus amyloliquefaciens W25 on Cd immobilization and γ-PGA production in soil filtrate and on the biomass and Cd uptake by lettuce in Cd-contaminated soil, the impact of these strains on the rhizosphere soil bacterial community was also evaluated. The strains reduced Cd concentration (16-75 %) in soil filtrate and strain W25 had a higher ability of producing γ-PGA and immobilizing Cd than strain W7. Compared with the control, the strains significantly increased the biomass (41-85 %) and reduced Cd uptake (19-41 %) by lettuce, reduced available Cd content (25-37 %) and increased the relative abundance of γ-PGA-producing bacteria (24-30 %) in Cd-contaminated soil, among which the effects of strain W25 were better than that of strain W7. Besides, these isolates also increased soil pH value, urease activity and the relative abundance of plant growth-promoting and metal-immobilizing bacteria such as Sphingomonas and Bacillus. https://www.selleckchem.com/products/Celastrol.html In summary, the two strains reduced soil available Cd and lettuce Cd uptake by increasing the pH value, urease activity and the abundance of γ-PGA-producing bacteria, and regulating bacterial community structure in rhizosphere soil.This study discloses the morphological and chemical-structural modifications that occur during thermal degradation of amphibole asbestos. Low-iron tremolite and iron-rich crocidolite were heated at temperatures ranging from r.t. to 1200 °C. Heating promoted a complex sequence of iron oxidation, migration and/or clustering and, finally, the formation of brittle fibrous pseudomorphs consisting of newly formed minerals and amorphous nanophases. The effects of the thermal modifications on toxicologically relevant asbestos reactivity were evaluated by quantifying carbon- and oxygen-centred, namely hydroxyl (OH), radicals. Heating did not alter carbon radicals, but largely affected oxygen-centred radical yields. At low temperature, reactivity of both amphiboles decreased. At 1200 °C, tremolite structural breakdown was achieved and the reactivity was further reduced by migration of reactive iron ions into the more stable TO4 tetrahedra of the newly formed pyroxene(s). Differently, crocidolite breakdown at 1000 °C induced the formation of hematite, Fe-rich pyroxene, cristobalite, and abundant amorphous material and restored radical reactivity. Our finding suggests that thermally treated asbestos and its breakdown products still share some toxicologically relevant properties with pristine fibre. Asbestos inertization studies should consider morphology and surface reactivity, beyond crystallinity, when proving that a thermally inactivated asbestos-containing material is safe.The carbon nanomaterials and congeners, e.g., graphene or graphene oxide (GO), dispose of numerous unique properties, which are not necessarily intrinsic but might be related to a content of impurities. The oxidation step of GO synthesis introduces a considerable amount of metallic species. Therefore, large-scale purification is an actual scientific challenge. Here we describe new purification technique (salt‑washing), which is based on three consecutive steps (a) aggregation of GO sheets with NaCl (b) washing of the aggregates and (c) removing of the salt to afford purified GO (swGO). The considerably improved purity of swGO was demonstrated by ICP and EPR spectroscopy. The microscopic methods (TEM with SEAD, AFM) proved that the salt-washing does not affect the morphology or concentration of defects, showing the aggregation of GO with NaCl is fully reversible. The eligibility of swGO for biomedical applications was tested using fibroblastic cell cultures. The determined IC50 values clearly show a strong correlation between the purity of samples and cytotoxicity. Although the purification decreases cytotoxicity of GO, the IC50 values are still low proving that cytotoxic effect is not only impurities-related but also an intrinsic property. These findings may represent a serious limitation for usage of GO in biomedical applications.The utilization of metallurgical sludge waste as a 10-30 % replacement of natural sand has been investigated in this paper for its effect on the initial setting time and hydration heat evolution of cement and the mechanical properties of mortars. link2 The results revealed that the addition of metallurgical sludge waste increased the water demand by up to 30 %, delayed the initial setting time by 3 h for 10 %, to over 25 h for 30 % sand replacement, decreased the hydration heat evolution rate by 30 % for 30 % sand replacement, and negatively affected the mortars' mechanical properties from 5 to 40 % for 20 % sand replacement, and from 30 to 50 % for 30 % sand replacement. For 10 % of sand replacement compressive strength was similar to the reference mortar. In order to obtain a shorter initial setting time, decrease the shrinkage and accelerate hydration heat evolution, part of the Portland cement (CEM I) was replaced by calcium sulphoaluminate cement (CSA). It was found that this method was effective for 20-30 % of CEM I replacement by 10 % of CSA and 10-30 % of CEM I replacement by 20-30 % of CSA in the case of setting acceleration, and for 10 % replacement in case of hydration heat evolution.High performance biopolymer films are of great interest as effective alternatives to non-biodegradable and petroleum-based polymer films. However, most natural biopolymer films possess weak mechanical and poor gas barrier properties, limiting their applicability. In this work, we developed all-cellulose nanocomposite films through a simple vacuum filtration process, using cellulose nanocrystals (CNCs) and 2,2,6,6-tetramethylpiperidine-1-oxy-oxidized cellulose nanofibers (TEMPO-CNFs). The TEMPO-CNFs were employed to construct a transparent, free-standing substrate matrix and the CNCs were used as a coating material to improve the mechanical and water vapor barrier properties of the final material. We have demonstrated that the top and bottom CNCs-coated TEMPO-CNF substrates (CNC/TEMPO-CNF/CNC) have excellent mechanical and good water vapor barrier properties. link3 The resulting CNC/TEMPO-CNF/CNC films revealed a high tensile strength of 114 MPa and a low specific water vapor transmission rate (SWVTR) of 19 g∙mm/m2∙day. In addition, the CNC/TEMPO-CNF/CNC films were resistant to various solvents including water, ethanol, tetrahydrofuran (THF), and acetone. This type of high performance cellulose nanocomposite can be used as a renewable material for a broad range of potential applications.This study mechanistically addressed for the first time, the contradiction between the application of many biochars to paddy soil and increased arsenic (As) release as employed by most of previous studies. Three types of biochar containing natural and chemical forms of Si (i) unmodified rice husk biochar (RHBC), (ii) RHBC modified with Si fertilizer (Si-RHBC), and (iii) RHBC modified with nanoparticles of montmorillonite clay (NM-RHBC) were applied in As-contaminated paddy soil to examine their potential to control the mobility of As in the soil-microbe-rice system. Both Si-RHBC and NM-RHBC decreased As concentration in porewater by 40-65 %, while RHBC decreased by 30-44 % compared to biochar unamended soil from tillering to maturing stage. At tillering stage, RHBC, Si-RHBC and NM-RHBC amendments significantly decreased As(III) concentration in the rice rhizosphere by 57, 76 and 73 %, respectively compared to the control soil. The immobilization of As is due to (i) lowering of microbe mediated As release from iron minerals, (ii) oxidation of As(III) to As(V) by aioA gene, and (iii) adsorption on a Si-ferrihydrite complex.