Mccrackenbrodersen8235
The measure of the energy efficiency of the non-adiabatic two-phase condensation process of refrigerants in mini-channels is both the value of the heat transfer coefficient α and the flow resistance expressing the external energy input required to realize the flow. The modelling of this very complex process is effective if the condensation mechanism in mini-channels is correctly identified. It has been proven that the effects of changes in the condensation mechanism are the different structures of the two-phase flow resulting from process interactions both in the channel cross-section and along the flow path. The research aimed to connect the value of the heat transfer coefficient with the flow structures occurring during condensation. Thermal and visualization studies of the condensation process of low-pressure refrigerants were carried out Novec649, HFE7100 and HFE7000 in tubular mini-channels with diameters dh = 0.5; 0.8; 1.2; 2.0 mm. Based on visualization studies, flow structures were proposed to be divided into 3 main groups dispersive, stratified and intermittent. Based on this, a computational correlation was derived for determining the heat transfer coefficient and frictional resistance depending on the type of flow structure. The research shows that the highest values of the heat transfer coefficient occur during the mist flow and the lowest during the bubble flow.To investigate the dynamic compressive properties of concrete after high temperature and rapid cooling, an experimental study was carried out by considering five temperatures and four strain rates. The coupling effect of high temperature and strain rate on concrete damage morphology and mechanical parameters was comparatively analyzed. The main conclusions are as follows the compressive damage morphology of concrete is affected by strain rate development trends of significant variability under different temperature conditions. As the strain rate increases, the compressive stress and elastic modulus of concrete are gradually increased. As the temperature increases, the increase in compressive stress is gradually reduced by the strain rate. For the temperatures of 20 °C and 800 °C, the increase in compressive stress by the strain rate is 38.69% and 7.78%, respectively. Meanwhile, SEM and CT scanning technology were applied to examine the mechanism of the effect of high temperature and strain rate on the mechanical properties of concrete from the microscopic perspective, and the corresponding constitutive model was proposed.The addition of Mn in bioceramic formulation is gaining interest in the field of bone implants. Mn activates human osteoblast (h-osteoblast) integrins, enhancing cell proliferation with a dose-dependent effect, whereas Mn-enriched glasses induce inhibition of Gram-negative or Gram-positive bacteria and fungi. In an effort to further optimize Mn-containing scaffolds' beneficial interaction with h-osteoblasts, a selective and specific covalent functionalization with a bioactive peptide was carried out. The anchoring of a peptide, mapped on the BMP-2 wrist epitope, to the scaffold was performed by a reaction between an aldehyde group of the peptide and the aminic groups of silanized Mn-containing bioceramic. SEM-EDX, FT-IR, and Raman studies confirmed the presence of the peptide grafted onto the scaffold. In in vitro assays, a significant improvement in h-osteoblast proliferation, gene expression, and calcium salt deposition after 7 days was detected in the functionalized Mn-containing bioceramic compared to the controls.We investigated the superconductivity of (TMTTF)2TaF6 (TMTTF tetramethyl-tetrathiafulvalene) by conducting resistivity measurements under high pressure up to 8 GPa. A cubic anvil cell (CAC) pressure generator, which can produce hydrostatic high-pressure, was used for this study. Since the generalized temperature-pressure (T-P) diagram of (TMTCF)2X (C = Se, S, X monovalent anion) based on (TMTTF)2PF6 (TCO = 70 K and spin-Peierls SP, TSP = 15 K) was proposed by Jérome, exploring superconductivity states using high-pressure measurement beyond 4 GPa has been required to confirm the universality of the electron-correlation variation under pressure in (TMTTF)2X (TMTTF)2TaF6, which has the largest octahedral-symmetry counter anion TaF6 in the (TMTTF)2X series, possesses the highest charge-ordering (CO) transition temperature (TCO = 175 K) in (TMTTF)2X and demonstrates an anti-ferromagnetic transition (TAF = 9 K) at ambient pressure. A superconducting state in (TMTTF)2TaF6 emerged after a metal-insulator transition was suppressed with increasing external pressure. We discovered a superconducting state in 5 ≤ P ≤ 6 GPa from Tc = 2.1 K to 2.8 K, whose pressure range is one-third narrower than that of X = SbF6 (5.4 ≤ P ≤ 9 GPa). In addition, when the pressures with maximum SC temperatures are compared between the PF6 and the TaF6 salts, we found that (TMTTF)2TaF6 has a 0.75 GPa on the negative pressure side in the T-P phase diagram of (TMTTF)2PF6.This review focuses on the Na wetting challenges and relevant strategies regarding stabilizing sodium-metal anodes in sodium-metal batteries (SMBs). The Na anode is the essential component of three key energy storage systems, including molten SMBs (i.e., intermediate-temperature Na-S and ZEBRA batteries), all-solid-state SMBs, and conventional SMBs using liquid electrolytes. We begin with a general description of issues encountered by different SMB systems and point out the common challenge in Na wetting. We detail the emerging strategies of improving Na wettability and stabilizing Na metal anodes for the three types of batteries, with the emphasis on discussing various types of tactics developed for SMBs using liquid electrolytes. We conclude with a discussion of the overlooked yet critical aspects (Na metal utilization, N/P ratio, critical current density, etc.) in the existing strategies for an individual battery system and propose promising areas (anolyte incorporation and catholyte modifications for lower-temperature molten SMBs, cell evaluation under practically relevant current density and areal capacity, etc.) that we believe to be the most urgent for further pursuit. Comprehensive investigations combining complementary post-mortem, in situ, and operando analyses to elucidate cell-level structure-performance relations are advocated.High-strength steels are used more than general structural steel due to their combination of properties such as high strength, good toughness and weldability. They are mainly used in the manufacture of heavy vehicles for the mining industry, cranes, transportation, etc. However, welding these grades of steel brings new challenges. find more Also, a simulation for welding high-strength steel is required more often. To insert a material database into the simulation program, it is necessary to conduct investigations using CCT (Continuous Cooling Transformation) diagrams, welded joints research, and more. To investigate the behavior of S960MC steel during heating and cooling, we used dilatometry analysis supported by EBSD (Electron Backscatter Diffraction) analysis. A CCT diagram was constructed. The transformation temperatures of Ac1 and Ac3 increase with increasing heating rate. The Ac1 temperature increased by 54 °C and the Ac3 temperatures by 24 °C as the heating rate increased from 0.1 °C/s to 250 °C/s. The austenite decomposition temperatures have a decreasing trend in the cooling phase with increasing cooling rate. As the cooling rate changes from 0.03 °C/s to 100 °C/s, the initial transformation temperature drops from 813 °C to 465 °C. An increase in the cooling rate means a higher proportion of bainite and martensite. At the same time, the hardness increases from 119 HV10 to 362 HV10.Reducing the loose-layer-to-dense-layer ratio in PEO coatings on aluminum and its alloys is the key to improving their corrosion resistance and expanding their applications in the aerospace industry and other fields. In this paper, we describe the discharge evolution during the PEO process in exhaustive detail and report the appearance of a novel "chain-like" discharge for the first time. We investigated the microstructure and composition of PEO coatings using a scanning electron microscope (SEM) equipped with an energy-dispersive spectrometer (EDS) and an X-ray diffractometer (XRD). The results reflected that the coating composition changed from amorphous Al2O3 to crystalline γ-Al2O3 and α-Al2O3 phases with the evolution of the plasma spark discharge state. We evaluated the electrochemical behavior of the coatings using a potentiodynamic polarization curve and electrochemical impedance spectroscopy (EIS) in 3.5 wt.% NaCl solution. Under "chain-like" discharge, the icorr of the coating on Al was 8.564 × 10-9 A∙cm-2, which was five orders of magnitude lower than that of the sample without the PEO coating. Moreover, we evaluated the adhesion strength of the coatings at different stages using a pull-off test. The adhesion strength of the PEO coatings at stage V reached 70 MPa. Furthermore, the high content of α-Al2O3 increased the hardness of the coating to 2000 HV. Therefore, the "chain-like" discharge promoted the formation of a single dense layer with 2.8% porosity and that demonstrated excellent properties. We also propose a mechanism to explain the influence of the plasma spark discharge state on the microstructure and composition of the PEO coatings.Deformation and heat treatment are important means to strengthen aluminum alloys. However, the influence mechanism of pre-strain on aging precipitation kinetics and its effect on mechanical properties are still not clear. In this work, uniaxial isothermal tensile tests with different strains and artificial aging treatments for Al-Zn-Mg-Cu alloys have been carried out. Then, a model describing the precipitates kinetic behavior has been developed to investigate the effect of thermal pre-strain on subsequent aging precipitation kinetics and peak aging microhardness based on the microstructure characterization by TEM, SAXS and XRD tests. In addition, the role of dislocations on the aging precipitation kinetics is also explored. The experimental results show that the peak aging microhardness of the Al-Zn-Mg-Cu alloy reveals a tendency to decrease and increase and then the peak aging time firstly decreases and then keeps almost constant with the increase in the strain. The calculations demonstrate that the precipitate average size almost remains unchanged, while the precipitate volume fraction decreases and then increases with the increase in strain, which is consistent with the change in peak aging microhardness. It also indicates that dislocations can promote precipitate nucleation and growth, while the actual effect depends on the dislocation density, which is closely dependent on the pre-deformation condition, especially for the precipitate nucleation. In particular, when the dislocation density after thermal pre-deformation is not enough, it will slightly inhibit precipitate nucleation but promote precipitate growth, which could shorten the peak aging time, with the peak aging strength being guaranteed.In this article, the static response of a functionally graded material (FGM) plate is studied via hybrid higher-order shear deformation theory which uses hyperbolic and polynomial shape functions and includes the effect of thickness stretching. The composition of the plate comprises metallic and ceramic phases. The ceramic volume fraction varies gradually along with the thickness following the power law. The mechanical properties of the FGM plate are determined by the rule of mixtures and the Mori-Tanaka homogenization scheme. The displacement fields are defined to satisfy the requirement of traction-free boundary conditions at the bottom and top surfaces of the plate surface removing the need for determination of shear correction factor. A C0 continuity FE model is developed for the present mathematical model. Nine-node isoparametric elements with eight nodal unknowns at each node are developed. The present model comparison with existing literature is completed and found to be coherent. Inhouse MATLAB code is developed for the present work.