Fieldsstephenson2282

igh productivity of the Antarctic marine ecosystem may facilitate foraging niche overlap of sympatrically living species. V.Although the majority of river networks across the world are intermittent or ephemeral, afforestation management of these catchments is mostly founded on studies in perennial catchments. The hydrological model CATHY (CATchment HYdrology) was used here to simulate the effects that different degrees of progressive conversion from pasture to plantation have on the streamflow generation in intermittent streams. The model was applied to two rural catchments with different size and topographic features in southwest Victoria, Australia. Simulated scenarios included different levels of plantation establishment in pasture areas planting gradually from downslope to upslope and vice versa. Different models for root water uptake were compared to account for water stress, oxygen stress, and root water compensation. A function of root growth over time was also explored to see how it affected model results. The model results show that complex interactions between topographic features and afforestation patterns are crucial in controlling catchments hydrological behavior. In particular, results show that planting in the prone-saturation areas has the largest effects on streamflow. Oxygen stress has a more significant impact than root water compensation on streamflow changes. A time dependent root growth results in smaller streamflow reduction on average, although with different impacts on the two catchments, also due to the interplay between topography and plantation patterns. Overall, our results show that there are multiple factors affecting the water balance when a catchment is partially or completely afforested and those must be taken into account when implementing forestry management strategies. This paper explores the extent to which enzymatic and bacterial biodelignification systems can breakdown lignocellulose in model wastes to potentially enhance biogas generation. Two representative lignocellulosic wastes (newspaper and softwood) commonly found largely undegraded in old landfills were used. A fungal peroxidase (lignin peroxidase) enzyme and a recently isolated lignin-degrading bacterial strain (Agrobacterium sp.) were used. Tests were conducted in stirred bioreactors with methanogens from sewage sludge added to produce biogas from breakdown products. Addition of lignin peroxidase resulted in ~20% enhancement in cumulative methane produced in newspaper reactors. It had a negative effect on wood. Agrobacterium sp. strain enhanced biodegradation of both wood (~20% higher release of soluble organic carbon and enhanced breakdown) and newspaper (~2-fold biogas yield). The findings of this paper have important implications for enhanced breakdown in old landfills that are rich in these wastes, and anaerobic operations utilising lignocellulosic wastes for higher degradation efficiencies and biogas production. Gray water constitutes an important fraction of total wastewater. Some of the most problematic compounds in gray water are the anionic surfactants used as an ingredient for domestic and industrial soaps and detergents. The alkylbenzene sulfonates used in commercially available formula are highly complex mixtures of linear (LAS) and branched (BAS) molecules. LAS are classified generally as biodegradable, although their widespread use generates accumulation in the environment. Docking tools, widely used in recent years in the bioremediation field, allow molecular modeling of the ligand-enzyme interaction, which is key to understanding and evaluating the possibility of biodegradation. In this work, molecular details that allow us to establish a biodegradation pattern for some alkylbenzene sulfonates were elucidated. Two hydrogen bonds, key for the anchorage of surfactants to the monooxygenase active site involved in the initial biodegradation, were found. These bonds determine the way surfactants locate in the hydrophobic pocket of the enzyme affecting the biodegradation rate in a structurally dependent manner. For C10 to C12 linear isomers, the degradation rate increased together with the length of the hydrocarbon chain. For C13 and C14 isomers, steric difficulties to accommodate the surfactant molecule in the catalytic site were observed. For branched chain isomers, little or no biodegradation was found. In addition, biodegradation was lower in mixtures than for the pure isomers. These results will allow an intelligent design of this family of anionic surfactants to attenuate their contaminating effects in waters and soils. This study constitutes, to the best of our knowledge, a novel contribution towards the design of environmentally friendly surfactants with higher probabilities of being biodegraded to complete mineralization. The paper presents the application of a low-cost system for monitoring the current level of road traffic participants' exposure to PM10 air pollution. The research was carried out from the end of August 2017 to the beginning of October 2017 on the central section of one of the main roads in Bielsko-Biała, Poland. In the analysed period, significant changes in the daily distribution of road traffic both into and out of the city centre were observed. The average travel time depended on the direction of traffic, and the difference between directions being almost 50%. The PM10 urban background concentration was also subject to daily changes, and in the fifth week of observation, it reached a value more than twice as high as in the first week of observation. The maximum level of road traffic participants' exposure was observed at a relatively low urban background PM10 concentration. ARRY-382 cell line It was observed that a significant slowdown in traffic in conditions of acceptable urban air quality led to a comparable level of exposure to that of standard traffic conditions and poor urban air quality. It was also found that the slowdown in traffic increased the exposure time of traffic participants travelling towards the city centre by an average of 24% and, for those travelling in the opposite direction, by as much as 50%. In an extreme case of traffic delay, exposure to PM10 concentration in the vicinity of the road was two and a half times as long.