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Furthermore, Co and Ag augmented the antioxidant defense system against CuO NP-induced toxicity. Contrary to that, all oxidative damage attributes were further enhanced exogenous application of ethylene biosynthesis precursor [1-aminocyclopropane-1-carboxylic acid (ACC)] in the presence of CuO NPs. In addition, ACC could increase the CuO NP-induced stomatal and ultrastructural damages by reducing the ROS-scavenging ability in rice seedlings. Taken together, these results indicate the involvement of ethylene in CuO NP-induced toxicity in rice seedlings.In the current research work, local clay-alginate beads loaded with sodium dodecyl sulfate (SDS) surfactant were prepared for efficient adsorption of methylene blue (MB). FTIR, SEM-EDX, and TGA instruments were used to examine the surface functional groups, morphology, elemental analysis, and thermal stability of beads, respectively. The adsorption efficiency of native clay for MB increases from 124.78 to 247.94 mg/g when loaded in alginate and SDS in beads form. The impacts of adsorbent dosage, initial pH, contact time, initial MB concentration, and temperature were investigated and optimized. The maximum adsorption capacity of beads for MB was 1468.5 mg/g. The process followed a pseudosecond order kinetic and Freundlich adsorption isotherm model. Thermodynamic study confirmed that MB adsorption on beads is endothermic and spontaneous in nature. The beads were recycled and reused for five times. According to the findings, local clay-alginate beads impregnated with SDS proved to be a promising and efficient adsorbent for extracting MB from aqueous solution.In this study, an N-ZnO/g-C3N4 (g-N-Z) Z-scheme photocatalyst was constructed using hydrothermal and high-temperature calcination. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and other tests were employed to characterise the catalytic material. The results showed that after N-ZnO modification, the separation efficiency of the photoinduced charge pairs and the utilisation of sunlight in the composites were improved. The kinetics experiments indicated that the degradation of atrazine (ATZ) in the g-N-Z/PDS/solar system was significantly better than that in the PDS/solar system. Under the action of the g-N-Z/PDS/solar system, the degradation rate of ATZ reached 83.88%, whereas in the PDS/solar system, it was only 31.76%. In addition, it was found that increasing the PDS concentration, g-N-Z dosage, and solution acidity effectively accelerated the removal of ATZ. The presence of HCO3-/CO32-, Cl-, and natural organic matter (NOM) inhibited the oxidation efficiency of the g-N-Z/PDS/solar system. Moreover, the presence of multiple reactive oxygen species (ROS) was confirmed using radical scavenging experiments to determine the contribution of each active component. Twelve oxidation intermediates of ATZ were obtained via liquid chromatography-tandem mass spectrometry (LC-MS/MS), and the mechanism of enhanced ATZ degradation in the g-N-Z/PDS/solar system was proposed. Actual water and cyclic photocatalytic experiments further suggest that g-N-Z has good application value in water treatment.Along with the steady worsening of environmental contamination, improving environmental governance performance (EGP) is an urgent issue that needs to be addressed. This study adopts panel data from 275 Chinese cities to examine the holistic relationship between the digital economy (DE) and urban EGP in multiple dimensions. The relationship is tested using fixed-effects models, mediated effects models, panel threshold models, and the spatial Durbin models. Results indicated that (1) the DE can effectively improve urban EGP. The findings still hold after robustness tests using instrumental variable estimation and the introduction of exogenous policy shocks. (2) The analysis of mediating effects shows that green technology innovation and industrial structure optimization are critical transmissions. (3) The panel threshold regression results indicate a nonlinear incremental phenomenon of the significant impact of the DE on urban EGP when nighttime lighting data is used as the threshold. (4) Spatial spillover analysis shows a positive spatial spillover effect of DE development on EGP in the surrounding cities. (5) Spatial heterogeneity analysis states that the enhancement effect of DE development on EGP is more significant in eastern China. Furthermore, areas located within urban agglomerations are more influenced by the DE. These findings provide a policy reference for fully exploiting the environmental enhancement effects of the DE.With the growth of global food demand, agricultural carbon emissions caused by agricultural production have become a major challenge in controlling global warming. However, a systematic and visual literature review of food security and carbon emissions (FSCE) is still lacking, and there is a lack of exploration on the balanced path between ensuring food security and realizing carbon emission reduction. Based on 872 articles related to FSCE in the Web of Science (WOS) core database, this paper used CiteSpace and VOSviewer bibliometric software to analyze the relevant research focus and trends. This study found that developed countries dominated the research in this field, and the quantity, quality, and intensity of their authors, institutions, and cooperation among countries are higher than those of developing countries. Although the intensity of interdisciplinary cooperation has increased, it remains at a low level. Since 2007, the number of papers published in this field has increased significantly, and the research perspectives have diversified. Moreover, the research theme continues to expand with the core of "food security," involving the impact of climate change, crop production and food security, soil carbon sequestration, and farmers' livelihood sustainability. In addition, food production, food transportation, and food loss reduction are key paths that need to be balanced to ensure global food security and realize carbon emission reduction, and how to promote "economic growth" under the constraints of FSCE will be a future research hotspot.The aim of the work was to investigate the possible biodegradation of such stable plastics as fluorated acrylic copolymer Protacryl-M and polytetrafluoroethylene-teflon (PTFE)-that are widely applied in medicine for prosthetics in dentistry and orthopedics. Our tasks were as follows 1. To select a suitable marine biological object (multicellular invertebrate) 2. To develop a method for delivering microplastic particles (MP) of selected plastics to the gastrointestinal tract (GIT) of an experimental animal 3. To develop a technique for separating MP particles from animal feces 4. To develop a technology for multiple passages of MP particles through the gastrointestinal tract of an animal 5. To select methods and techniques for determining the degradation of the surface of MP particles after passing through the gastrointestinal tract of the animal The effect of a biological agent on the types of plastic above is considered using marine gastropods of the genus Littorina (in particular, the periwinkle L. brevicula) as a model organism widely distributed in the marine intertidal zone.This paper empirically examines the effects of energy, natural resources, agriculture, political constraint and regional integration on CO2 emissions in four ASEAN (Association of Southeast Asian Nations) countries of Cambodia, Malaysia, Indonesia and Thailand. We distinguish between renewable and fossil fuel energy consumption to see their individual impacts on CO2 emissions. The study employed a panel data from 1990 to 2019 derived from sources such as World Development Indicators, which were then analysed using Common-Correlated Effect Mean Group (CCEMG) and Augmented Mean Group (AMG) estimates. The findings show that renewable energy consumption has a negative impact on CO2 emissions while fossil fuel energy degrades the environment. The role of natural resources was found to be favourable for environmental quality with the impact of agriculture being found to be detrimental. For regional trade integration, its influence was not significant enough to offset CO2 emission. Furthermore, we discovered that political constraint induces CO2 emission. Based on the result, it is recommended that the selected ASEAN countries promote the use of renewable energy and clean technologies in their manufacturing processes, conserve natural resources, adopt eco-friendly political policies and intensify regional integration to accelerate the achievement of the SDGs.The novelty of this research is shading position in the transparent cover of partially shaded pyramid solar still. The square pyramid transparent cover is used as top cover of partially shaded pyramid solar still. The square pyramid has four sides and each side named as per the direction. Each one of the sides is shaded in the square pyramid transparent cover. The single side or direction shaded is known as 25% of shading in the transparent cover. Similarly, two sides are 50%, and three sides are 75%. Totally, fourteen configurations of experiments are conducted in the partially shaded pyramid solar still for improving the freshwater yield. Fifty per cent of shading in the transparent cover produced higher freshwater yield compared to 25 and 75%. The partial shading increased productivity of freshwater yield by reducing 4 °C of transparent cover temperature compared to conventional pyramid solar still. The north and south direction shaded (50% of shading) produced 4% higher freshwater yield compared to conventional pyramid solar still. The embodied analysis is studied for partially shaded pyramid solar still. The lifecycle conversation efficiency is around 38%, and CO2 mitigation is 34.1 for 50% shading of partially shaded pyramid solar still.In Mikawa Bay, where hypoxia occurs in the bottom layer during summer, six shipboard observations were conducted from the mouth to the head of the bay from May to August 2014 to investigate the spatiotemporal variation in the bottom layer oxygen consumption rate (OCR). The OCR was determined from the dark incubation of sample waters using an optical oxygen sensor, which showed a range of 5.7-38.3 mmol m-3 days-1. A high OCR was observed at the inner-most station, where higher concentrations of nutrients and chlorophyll a (Chl a) than at the other stations were found, and bottom hypoxic water appeared during the observation period after late June. These OCRs can deplete the oxygen dissolved in water within a week. The OCR showed a highly significant positive correlation with particulate organic carbon concentrations in the bottom water. Considering the relatively low carbon-to-nitrogen mole ratio (~ 6.4-7.6) and high carbon isotope ratio (between approximately - 20.2 and - 18.8‰) of particulate organic matter at the stations, the supply of fresh organic matter produced in the bay as opposed to the land may have affected the OCR by acting as a substrate for microbial aerobic respiration. High temporal resolution data from two automated observation buoys near the bay mouth and the inner area captured increases in Chl a at both sites in response to typhoon events, along with the subsequent appearance of bottom hypoxic water at the inner site and its expansion at the mouth. Selleck PEG300 This supports our hypothesis that enhanced organic matter production due to nutrient input to the surface layer through vertical mixing would increase the bottom OCR, resulting in hypoxia. The apparent oxygen decline in the bottom layer from the buoy data was consistent with incubation-based OCRs during the observation period. Therefore, it is essential to model the OCR in numerical simulations of hypoxia, to which the variability characteristics that we revealed made significant contributions.