Bowdenchappell7578

Amongst various individual carbon and nitrogen sources, maximum decolorization was observed in MM supplemented with peptone as carbon and nitrogen source at pH 7 under static condition. Because of its superior physical and chemical properties, MnFe2O4 is regarded as one of the best magnetic material alternatives for Fe3O4. However, MnFe2O4 alone cannot remove heavy metal ions and dyes. Here, we report on a new mesoporous magnetic MnFe2O4@CS-SiO2 microsphere material that was synthesised via the hydrothermal method to remove Zn2+ and methylene blue (MB) in simulated textile wastewater. The composite was characterised using a vibrating sample magnetometer, scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy, X-ray powder diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and a Brunauer-Emmett Teller analysis. The pH, adsorbent dosage, initial adsorbate concentration, and reaction time effects on the removal of Zn2+ and MB were studied under different conditions, and a possible removal mechanism was proposed and discussed. The experimental results show that the suitable pH range for MB adsorption was extremely wide, and the adsorption equilibrium can be reached within 30 min. In addition, the prepared material has excellent stability. With an excellent removal efficiency as high as 56.1% and 93.86% for Zn2+ and MB, respectively, after five consecutive cycles and a superior adsorption capacity compared with other materials, the prepared composite in this paper proved to be a promising and effective magnetic adsorbent for the removal of Zn2+ and MB from textile wastewater. Low recycling rates of rare earth elements (REEs) are a consequence of inefficient, expensive and/or contaminating methods currently available for their extraction from solid wastes or from liquid wastes such as acid mine drainage or industrial wastewaters. The search for sustainable recovery alternatives was the motivation for this study. For the first time, the capabilities of 6 living macroalgae (Ulva lactuca, Ulva intestinalis, Fucus spiralis, Fucus vesiculosus, Osmundea pinnatifida and Gracilaria sp.) to remove REEs (Y, La, Ce, Pr, Nd, Eu, Gd, Tb, Dy) from laboratory-prepared seawater spiked with REE solutions were evaluated. The assays lasted 72 h with REEs concentrations ranging from 10 to 500 μg L-1. The link between REEs uptake and algal metabolism, surface morphology and chemistry were addressed. Kinetics varied among the species, although most of the removal occurred in the first 24 h, with no equilibrium being reached. Lack of mortality reveal that the algae maintained their metabolism in the presence of the REEs. Green alga U. lactuca stood out as the only capable of efficiently removing at least 60% of all elements, reaching removals up to 90% in some cases. The high bioconcentration factors, derived from mass balance analysis (c.a. 2500) support that the REEs enriched algal biomass (up to 1295 μg g-1) may constitute an effective and environmentally friendly alternative source of REEs to conventional extraction from ores. Industrial activities lead to the contamination of large amounts of soils polluted by both inorganic and organic compounds, which are difficult to treat due to different chemical properties. The efficiency of a decontamination process developed to simultaneously remove mixed contamination of industrial soils was evaluated at the pilot-scale, as well as operating costs associated to that process to define the best remediation approach. The results showed that the treatment of the coarse fractions (>0.250 mm) of 40 kg of soil by attrition in countercurrent mode allowed the removal of 17-42% of As, 3-31% of Cr, 20-38% of Cu, and 64-75% of polychlorinated dioxins and furans (PCDD/F). Removals of 60% for As, 2.2% for Cr, 23% for Cu, and 74% for PCDD/F were obtained during the treatment of attrition sludge ( less then 0.250 mm) by alkaline leaching process. However, the results of the techno-economic evaluation, carried out on a fixed plant with an annual treatment capacity of 7560 tons of soil treated (tst), showed that the estimated overall costs for the attrition process alone [scenario 1] (CAD$ 451/tst) were lower than the costs of the process, which additionally includes an alkaline leaching step to treat attrition sludge [scenario 2] (CAD$ 579/tst). This techno-economic evaluation also showed that the process becomes competitive with current disposal options (thermal desorption and landfilling - CAD$ 600/tst) from a certain treatment capacity, which is around of 3465 tst/yr for the scenario 1 and 6930 tst/yr for the scenario 2. On the other hand, the techno-economic evaluations are crucial to selecting feasible decontamination process for a soil remediation project, with considerations of the type of contamination, site characteristics and cost effectiveness. Sewage sludge from municipal wastewater treatment plants in Germany is currently disposed of via thermal treatment and agricultural utilization or used for landscaping. selleck chemicals llc Increasing focus on hygiene, soil protection and most recently on phosphorus recovery combined with the associated legal changes leads to an increased relevance of thermal sewage sludge treatment processes. This article reviews existing technologies for thermal treatment of sewage sludge with a view to the situation in Germany. Thermal sewage sludge treatment can be divided into different processes drying reduces high water contents of mechanically dewatered sewage sludge and often precedes subsequent treatment processes. link2 Today, most of the sewage sludge in Germany is incinerated, about half in mono-incineration, mostly in stationary fluidized beds, and the other half in co-incineration, in particular in coal-fired power plants, cement kilns or, to a lesser extent, waste incineration plants. Some alternative thermal processes, mainly pyrolysis and gasification, but also metallurgical approaches, are tested in bench or pilot scale. Recent amendments to the German Sewage Sludge Ordinance will restrict the disposal route of co-incineration in future. Consequently, a significant increase in mono-incineration capacity is expected. These processes should enable the combination of environmentally friendly disposal and phosphorus recovery. Phosphorous (P) fertigation with high salinity water (HSW) drip irrigation would be an effective measure to relieve soil and water pollution caused by the excessive application of P fertilizer, and achieve synergistic saving of both limited fresh water and non-renewable P resources. However, the emitter clogging issues of drip fertigation systems seriously restricts the utilization of this technology. This study proposes an approach to reduce emitter clogging in HSW drip fertigation systems by choosing the appropriate type and concentration of P fertilizer. The effects of two new types of P fertilizers (ammonium polyphosphate, APP; urea phosphate, UP), and a traditional P fertilizer (monopotassium phosphate, MKP), were assessed at three fertilization concentrations (0, 0.15, and 0.30 g/L) on the clogging behavior of four types flat emitters. The results indicated that the application of MKP aggravated the clogging of emitters in comparison with non-fertilization. While the addition of two new types of P fertilizers (APP and UP) effectively alleviated emitters clogging (the irrigation uniformity of systems increased by 26.2%-74.6%) by inhibiting the formation of carbonate, although precipitation of phosphate, silicate, and quartz increased. Moreover, under the equal application amount of P fertilizer, UP and APP were more effective in relieving clogged when applied at a low-concentration with long-term running and high-concentration with short-term running mode. The results could pave a way for reducing the pollution in agricultural production and conserving freshwater and non-renewable P resources. Water is one of the natural resources most impacted by the development model adopted in Brazil. This is related to the widespread sense that water is abundant in the country, which makes it difficult to fully engage all levels of government. However, this sense of abundance also obscures the real problems of pollution, demand, availability and water resources conflicts. This study aims to strengthen water management and contribute to the evaluation of the processes of development in the northeast region of the state of Pará. This study uses Hydrographic Basin Sustainability Indices to consider the hydrological, environmental, social and water resources management situation of the Moju River Basin and to suggest a payment model for the use of its water resources. The results indicate that the existing framework of water use regulation is characterized by moderate sustainability and governance scores and a low degree of collection of fees for the use of water. In general, with the increase in the number of enterprises authorized to withdraw water from and release effluents into the river, there is a lack of information about water demand and availability. The water governance framework is characterized by poorly integrated environmental and water management common to most Amazonian municipalities. Thus, the Moju River Basin represents a pattern of unsatisfactory water resources management. This pattern highlights the importance of implementing existing water resources and environmental policies to reduce conflicts that involve land and water use. Floating treatment wetlands (FTW)s that can uptake nutrients and metals from water, and/or trap suspended solids in their roots, are becoming viable options to treat urban, agriculture and sewage runoffs. However, current FTW designs favor aerobic processes and short-term storage of metals, which are ineffective in acid mine drainage (AMD) environments. Many also function poorly in northern latitudes with strong seasonality and several months of sub-zero temperatures. In this study, we designed a novel FTWs with 20 cm soil profile to test its ability to sustain anaerobic microbial processes, such as iron and sulfate reduction and remain functional after freezing conditions of winter months. Three different plants, Carex lacustris, Typha latifolia, and Juncus canadensis were used to test in our FTWs, which were deployed in a mining-impacted water in Sudbury, ON, Canada. Porewater samples were acquired using built-in porewater peepers. Low to moderately reducing conditions, along with presence of ferrous iron and hydrogen sulfide in the porewater of all FTWs was prevalent, irrespective of the constituent vegetation type. Moreover, as well as a ~30% increase in sulfate-reducing bacteria (SRB) richness and ~100% increase in SRB abundance between years, was the evidence that anaerobic processes were occurring in these shallow FTWs. From this study we estimated that during its lifetime, one shallow FTW can treat ~61 m3 of sulfate-rich water, thus offering an alternative way to capture sulfate and other metals from mining-impacted waters. Fresh water sources are under pressure globally by the increasing population and consequently increasing production, which increases the water demand day by day. Thus, decreasing the industrial fresh water demand and wastewater production became crucial both for the water availability in the future and for its impact to the environment. link3 This study examined the ozone-based treatments as the possible solution to a refinery to treat the effluent already treated by the traditional techniques to reach the final requirements for reuse and recycle purposes. The screening tests performed by fractional factorial design revealed that the significant parameters for the treatment were ozone feed ratio, H2O2 amount and processing time while pH was found insignificant for this case. Based on the box-Behnken response surface methodology for effluent collected after biological treatment, the significant parameters were optimized as the ozone ratio of 0.9 g/h, H2O2 amount of 47 mg/L and 60 min duration. However, in case of increasing the H2O2 amount to 80 mg/L the duration can be minimized to 37.