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Antibiotic exposure did not substantially change the stochasticity of the bacterial communities, despite the NST values were significantly increased by ~3% (p less then 0.05) for the rhizosphere soil and lettuce roots and significantly decreased by ~3% (p less then 0.05) for the bulk soil, when comparing treatments with and without antibiotics. The levels of Methylophilaceae and Beijerinckiaceae were significantly different between the antibiotic and antibiotics-free treatments. Antibiotic exposure consistently increased the abundance of mobile genetic elements (MGEs) in the rhizosphere soil, but not in other samples. No consistent changes in ARGs were observed with and without antibiotic exposure. Finally, the correlation network analysis revealed that the rhizosphere soil may be a hotspot for interactions between ARGs, MGEs, bacterial communities, and antibiotic residues.Radionuclide Sr2+ in aqueous solution was removed using a large amount of banana peel (BP). Magnetized BP, mag@BP, was synthesized for recovery after the adsorption process. The synthesis was a very simple process of precipitation of BP with a magnetic substance. The synthesized adsorbent was thoroughly examined by performing Fourier-transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction analysis, and vibration sample magnetometer analysis. Moreover, mag@BP has a Sr2+ maximum adsorption capacity of 23.827 mg/g according to isothermal adsorption, which is the best fit for the Langmuir isotherm model. In the pH effect experiment, the highest Sr2+ adsorption capacity was found at pH 9, and it has a spontaneous adsorption mechanism through experiments on temperature, time, and selectivity, and it reaches adsorption equilibrium within a short time and has high selectivity through competitive adsorption with Na+. In addition, an adsorption mechanism accompanied by ion exchange with K+ on the surface of BP, bonding with various functional groups, and electrical attraction were established. Therefore, mag@BP is suitable for use an environmentally friendly, low cost, and recoverable adsorbent for magnetic removal of Sr2+ from aqueous solutions. Further, unlike other carbon-based adsorbents, it does not cause cytotoxicity.Nitrate (NO3-) is becoming a significant contributor to acid deposition in many cities in China. Based on the chemical compositions and stable isotopes of NO3- in precipitation (δ15N-NO3- and δ18O-NO3-), the NO3- sources and their formation pathways were determined to aid in reducing NOx emissions in Ningbo, an important port city. The acid rain frequency in Ningbo was 67%, and the mean SO42-/NO3- ratio was 1.07. The δ18O-NO3- (49.5‰-82.8‰) and δ15N-NO3- values (-4.3‰-2.7‰) both varied seasonally, with high values during the cold season and low values during the warm season. The seasonal variations in the δ18O-NO3- values were mainly controlled by the NO3- formation pathways, following the OH· pathway during the warm season and N2O5 pathway during the cold season. check details The Monte Carlo simulation results indicated that the contributions of the OH· pathway ranged from 28.3% to 75.4%, with the remainder contributed by the N2O5 pathway. The improved Bayesian model incorporating nitrogen (N) isotopic fractionation (Ԑ = 4‰) indicated that mobile sources, including ship emissions (35.0%) > coal combustion (26.0%) > biomass burning (20.0%) > soil emissions (19.0%), were the major sources of NOx emissions in Ningbo. The results indicate that the influence of isotopic fractionation on source apportionment must be considered in a Bayesian model.The widespread presence of phthalate esters (PAEs) in a variety of agricultural inputs has led to PAE contamination in soils and farm products. The endocrine disruption and carcinogenicity of PAEs have attracted much attention. Our research investigated the characteristics of PAE pollution in the soils of vegetable fields and adjacent stable crop fields in four provinces/municipalities across a major agricultural production area in China. We found that the concentrations of PAEs in vegetable soils were not significantly higher than those in stable crop soils. The noncarcinogenic and carcinogenic risks from bis (2-ethylhexyl) phthalate (DEHP) and dibutyl phthalate (DBP) to humans were calculated to represent the risk posed by PAEs. The results showed that diet was the main route for noncarcinogenic risks from PAEs in crop soil and vegetable soils. link2 Because of the combined effect of the population dietary structure and the concentration of PAEs in soils, the noncarcinogenic risks from PAEs in crop soils were similar to or higher than those in vegetable soils. The same pattern was also applicable to the carcinogenic risk from DEHP. Low noncarcinogenic and carcinogenic risks posed by DEHP and DBP indicated that the current level of PAEs in soils did not decrease the safety of agricultural products in the Huang-Huai-Hai region. Stable crop soil, as a non-negligibly phthalate-polluted area, is worthy of as much attention as vegetable soil. This study provides scientific support for food safety risk assessment and control of PAE pollution in the main agricultural production areas in China.Global dairy and swine production growth has increased significantly over the past decades, resulting in higher manure generation in certain areas and environmental concerns. link3 Therefore, manure management is an essential focus for farmers and environmental regulators. Systematic selection of manure management practices can provide environmental benefits, but accounting for local constraints, economics and farming practices are significant challenges. All these factors drive the selection of appropriate manure management systems (MMSs). MMSs are highly varied for their design, partly due to individual farm settings, geography, and the end-use applications of manure. However, the benefits of technological advancements in MMSs provide higher manure treatment efficiency and co-production of value-added products such as recycled water, fiber, sand bedding, and nutrient-rich bio-solids, among others. To achieve higher environmental benefits, advanced manure treatment technologies have to be implemented, which comes rapidly evaluate the techno-economic feasibility of alternative systems.The adsorption treatment of ammonium-containing wastewater has attracted significant global attention. Most enhanced adsorption methods employ chemical modification, and there are few reports on physical activation. We present a physical activation to explore whether physical ultrasound may enhance the adsorption performance and comprehensive utilisation of a new forestry waste, Caragana korshinskii was used as a feedstock to prepare activated biochar (ACB) by controlling the pyrolysis temperatures and ultrasound parameters. The optimal parameters were determined via batch adsorption of NH4+, and the adsorption characteristics were assessed by 8 kinds of models and influence experiments. Moreover, the physicochemical properties of ACB during the pyrolysis process were investigated, and the ultrasonic activation and adsorption mechanisms were discussed using multiple characterisation techniques. Additionally, the cost analysis, the safety of the ultrasonic process and disposal method also were evaluated. The results showed that the ultrasonic activation significantly enhanced the NH4+ adsorption efficiency of biochar by approximately 5 times. ACB exhibited the best performance at 500 °C with an ultrasonic activation time of 480 min, frequency of 45 kHz, and power of 700 W. The ultrasonic activation reduced the biochar ash and induced pore formation, which increased the specific surface area through cavitation corrosion and micro-acoustic flow mechanism. The NH4+ adsorption mechanisms comprised physicochemical processes, of which physical adsorption was dominant. The preparation cost of 1 kg ACB was about 0.42 US dollar, and no secondary pollution occurred in the activation process. The findings prove that ultrasonic technology is efficient and convenient for enhancing biochar adsorption performance, and thus is suitable for industrial applications and promotion.Lake eutrophication has attracted the attention of the government and general public. Chlorophyll-a (Chl-a) is a key indicator of algal biomass and eutrophication. Many efforts have been devoted to establishing accurate algorithms for estimating Chl-a concentrations. In this study, a total of 273 samples were collected from 45 typical lakes across China during 2017-2019. Here, we proposed applicable machine learning algorithms (i.e., linear regression model (LR), support vector machine model (SVM) and Catboost model (CB)), which integrate a broad scale dataset of lake biogeochemical characteristics using Multispectral Imager (MSI) product to seamlessly retrieve the Chl-a concentration. A K-means clustering approach was used to cluster the 273 normalized water leaving reflectance spectra [Rrs (λ)] extracted from MSI imagery with Case 2 Regional Coast Colour (CR2CC) processor into three groups. The pH, electrical conductivity (EC), total suspended matter (TSM) and dissolved organic carbon (DOC) from three clustce the influence of particle in red bands for Rrs(λ) signal. Our results highlighted the quantification of lake Chl-a concentrations using MSI imagery and SVM, which can realize the large-scale monitoring and more appropriate for medium/low Chl-a level. The remote estimation of Chl-a based on artificial intelligence can provide an effective and robust way to monitor the lake eutrophication on a macro-scale; and offer a better approach to elucidate the response of lake ecosystems to global change.Dissolution-precipitation processes on the surface of brushite (dicalcium phosphate dihydrate, DCPD) control the migration and transformation of potentially harmful elements (PHEs). The incorporation of impurities could affect the properties of DCPD and its interactions with PHEs. In this study, we synthesized Fe3+-bearing DCPD via coprecipitation and investigated the influence of Fe3+ incorporation on the crystal structure, hydrolysis process, and Cd removal performance. Fe-bearing DCPD had lattice expansion due to the coupled substitution of Fe3+ and NH4+ for Ca2+. Therefore, the Cd removal performance of Fe-DCPD was enhanced, with a maximum Cd uptake capacity of 431.6 mg/g, which is 1.77 times that of Fe-free DCPD (244.4 mg/g). Furthermore, Fe-DCPD also exhibited a faster hydrolysis rate, which was up to 2.67 times that of Fe-free DCPD and accelerated Cd's transfer to the stable host mineral, hydroxylapatite. Cd was first caught by the DCPD surface in a weakly crystalline form and then incorporated into the hydroxylapatite structure during crystallization. Based on the X-ray photoelectron spectroscopy and thermogravimetric analysis results, we concluded that the decrease in interstitial water due to Fe incorporation was responsible for accelerating hydrolysis and enhancing Cd immobilization. In all, the incorporation of Fe3+ into DCPD could promote its transformation and improve its Cd uptake capacity. Our results suggest that Fe-DCPD could be a promising candidate for environmental remediation.