Ramirezsvenningsen7462

Collectively, 2,3,6,7-TeCBP, because of its toxicity, concentration and persistence, is a crucial compound in the evaluation of the health effects correlated with fires of electrical systems. Pyrolysis technology is advised to dispose nonmetallic particles of waste printed circuit boards to produce oils and gases. During pyrolysis, brominated flame retardants in nonmetallic particles are converted into small-molecular Br-containing substances. They disperse into oil and gas so as to cause secondary pollution. Then, CaCO3 is suggested to be employed to capture the small-molecular Br-containing substances. However, too much CaCO3 will produce over solid wastes. Less CaCO3 might not capture the total Br-containing substances. How to ration the mass of adsorbent for capturing pollutant has not been detailed investigated. This paper found HBr was the main Br-containing substances during high temperature pyrolysis of nonmetallic particles. The capture process of HBr was detailed investigated by the method of computational chemistry. At the condition of 973 K and 100 Pa, HBr was captured by chemical reaction and physical absorption of CaCO3. Unit cell of CaCO3 reacted with two HBr to form CaBr2, and the generated unit cell of CaBr2 can adsorb 0.011 HBr. 0.0106 g CaCO3 can absorb all HBr produced by high temperature vacuum pyrolysis of 1 g nonmetallic particles. This paper contributes a novel approach to accurately ration the mass of adsorbents employed for capturing pollutants. Perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) have attracted global attention due to their chemical durability, wide distribution, biotoxicity and bioaccumulative properties. Persulfate is a promising alternative to H2O2 for advanced oxidation processes and effective for organic removal. In this review, persulfate activation methods and operational factors in persulfate-based PFOA / PFOS degradation are analyzed and summarized. Moreover, the decomposing mechanisms of PFOA and PFOS are outlined in terms of molecular structures based a series of proposed pathways. PFOS could be converted to PFOA with the attack of SO4- and OH. And then PFOA defluorination occurs with one CF2 unit missing in each round and the similar procedure would occur continuously with sufficient SO4- and OH until entire decomposition. In addition, several knowledge gaps and research needs for further in-depth studies are identified. This review provides an overview for better understanding of the mechanisms and prospects in persulfate-based degradation of PFOA and PFOS. Nanozymes, which display the bifunctional properties of nanomaterials and natural enzymes, are useful tools for environmental remediation. Fluspirilene In this research, nano-MnO2 was selected for its intrinsic enzyme-like activity to remove 17β-estradiol (E2). Results indicated that nano-MnO2 exhibited laccase-like activity (7.22 U·mg-1) and removed 97.3 % of E2 at pH 6. Humic acid (HA) impeded E2 removal (only 72.4 %) by competing with E2 for the catalytic sites of the MnO2 nanozyme surface, and there was a good linear correlation between the kinetic constants and HA concentrations (R2 = 0.9489). Notably, the phenolic -OH of E2 interacted with HA to yield various polymeric products via radical-driven covalent coupling, resulting in ablation of phenolic -OH but increase of ether groups in the polymeric structure. Intermediate products, including estrone, E2 homo-/hetero-oligomers, E2 hydroxylated and quinone-like products, as well as aromatic ring-opening species, were identified. Interestingly, HA hindered the extent of E2 oxidation, homo-coupling, and decomposition but accelerated E2 and HA hetero-coupling. A reasonable catalytic pathway of E2 and HA involving MnO2 nanozyme was proposed. These findings provide novel insights into the influence of HA on MnO2 nanozyme-driven E2 radical polymerization and decomposition, consequently favoring the ecological water restoration and the global carbon cycle. Remediation of organochlorine pesticides (OCPs)-contaminated soils is urgently required especially in China. Surfactants have emerged as reliable and efficient co-solvent for the treatment of hardly soluble organic pollutants in contaminated soil. Here, we report the use of TritonX-100 (TX-100) in advanced oxidation under electrokinetic technology (EK) for OCPs removal from a historically contaminated soil from a former pharmaceutical industrial wasteland. Result shows that TX-100 (10%) played a key role in soil remediation. In effect, after a treatment period of 15 days, pollutants washed ranged from 50.68% (4,4'-DDT) to 76.07% (HCB), when TX-100 was used as the electrolyte (EK-TX-100). A simple advanced oxidation of the soil using sodium persulfate (PS) under EK approach (EK-PS) was limited to achieve good removal efficiency of the pollutants; as the result of OCPs' hardly dissolvable nature. The achieved removal efficiency were comprised between 22.62% (2,4-DDT) and 55.78% (1,2,4,5-TCB). With the application of TX-100 as co-solvent (EK-TX-100/PS), the pollutants removal efficiency significantly improved (p  less then  0.05). The treatment efficiency was shifted and up to 88.05% (1,2,4-TCB) was achieved, while the lowest removal efficiency was 56.36% (4,4'-DDE). We come to the conclusion that the use of TX-100-enhanced advanced oxidation (EK-TX-100/PS) as a reliable treatment for remediating organochlorine contaminated soil. A method combining g-C3N4 and potassium peroxydisulfate (PDS) under simulated sunlight was put forward to effectively degrade sulfamethoxazole (SMX). The SMX removal efficiency was substantially improved compared with the processes involving only g-C3N4 or PDS. The kinetic constants for the g-C3N4, PDS and g-C3N4/PDS systems were 0.0023, 0.0239 and 0.068 min-1, respectively. The g-C3N4/PDS process reached an SMX removal rate of 98.4 % after 60 min of simulated sunlight; in addition, the proposed system showed desirable efficiency for SMX degradation in two different actual water samples as well. The reaction mechanism was illustrated by trapping experiments, which showed that g-C3N4 can promote S2O82- to transfer SO4-, S2O82- favored the generation of O2-, and O2-, SO4- and holes (h+) were the main oxidative species for the SMX degradation in the combined reaction process under simulated sunlight. Then, to further explore this mechanism, the intermediates generated during the combined reaction process were analyzed by LC/MS and possible degradation pathways were proposed. The result showed that the breaking of the SN and C-S bonds, the hydroxylation of the benzene ring and the oxidation of the amino group were identified as the main pathways in the SMX degradation process by the g-C3N4/PDS system under simulated sunlight. Thallium is an emerging pollutant reported in wastewater along with the increasing mining and smelting of thallium-containing ores in recent years. The complete removal of Tl(I) from wastewater is of significant emergency due to its high toxicity and mobility, however, Tl(I) removal is always confronted with numerous technical difficulties because of the extremely low Tl(I) concentration in wastewater and the disturbances of many accompanying impurity ions. Adsorption is currently the most widely used method for Tl(I) removal on industrial scale and varied kinds of adsorbents such as Prussian blue analogues, biosorbents, and metal oxides have been developed. However, the adsorption process of Tl(I) is always affected by the co-existing cations, resulting in low Tl(I) removal efficiency. Recently, the development of a variety of novel adsorbents or ion sensors based on macrocyclic compounds for enrichment and accurate determination of trace Tl(I) in aqueous solutions exhibits great potential for application in Tl(I) removal from wastewater with high selectivity and process efficiency. This paper provides an overview of the adsorption methods for Tl(I) removal from wastewater with emphasis on complexation properties between varied types of adsorbents and Tl(I). Future directions of research and development of adsorptive Tl(I) removal from industrial wastewater are proposed. Lead (Pb) contamination in soils is becoming one of the most serious environmental issues in recent years. For this reason, amendment induced immobilization of Pb in contaminated soils has been considered as an eco-friendly and cost-effective technique to minimize soil Pb availability. This study aims at evaluating efficacy of the newly discovered Aspergillus niger strain, SANRU in bioimmobilization of Pb in contaminated mine soil. To conduct bioimmobilization, phosphate rock (PR) at various P/Pb ratios of 0 (T1), 2 (T2), 4 (T3), or 6 (T4) molars was inoculated with the A. niger strain SANRU and subsequently introduced into the soil. The soil sample inoculated with A. niger SANRU and P/Pb molarity ratio of 0 (T1) in this study showed the highest Pb bioimmobilization efficiency, as well as a significant reduction up to 65 % in the unimmobilized Pb concentration and an increase in residual Pb fraction. Our in-depth Fourier transform infrared spectra (FTIR) and X-ray diffraction (XRD) studies revealed that the successful Pb bioimmobilization in this sample was attributed to Pb oxalate formation in the soil. In T2 treated soil with A. niger and P/Pb molarity ratio of 2, the Pb oxalate was precipitated solely as Pb minerals in spite of the presence of available phosphate. In the samples with A. niger and higher amounts of PR (T3 and T4) the Pb bioimmobilization efficiency was significantly lower than T1 but hydroxypyromorphite was formed in these samples. Our data thus propose that A. niger SANRU alone suffice to bioimmobilize Pb in contaminated soil. Appropriate chelator may increase plant tolerance and accumulation for Cd in soil, but its molecular mechanism is unclear. In this experiment, the technology of isobaric tags for relative and absolute quantitation (iTRAQ) was used to compare the differential expression proteins (DEPs) and differential expression genes (DEGs) characteristics of poplar accumulating Cd combined with EDTA and/or EGTA. The results showed that the Cd concentrations, biomasses and activities of antioxidant enzymes of poplar were significantly increased in the treatments of chelator addition compared to the TCd. The number of co-intersecting specific proteins of TCd/CK, TCd+EDTA/TCd, TCd+EGTA/TCd and TCd+EDTA+EGTA/TCd was 49. Using the GO function and KEGG analysis, it was found that EDTA and EGTA might improve some main metabolic pathways of poplar leaves, which were involved in the enhancement of the expression of carbohydrate and energy metabolism-related proteins, regulation of cell energy metabolism, complementing and cooperating with each other in various ways, and dynamic regulation of energy metabolism. Particularly, chelator might induce the regulation of protein synthesis, folding and transport, and degradation of abnormal proteins in response to Cd toxicity. These results provided a theoretical basis for further elucidation of molecular mechanisms of poplar response to Cd stress. Vanadium slag/CaO diffusion couples were prepared to study the diffusion characteristics of the vanadium slag/CaO interface at 1083 K in the air. The generated phases at different regions were characterized by EPMA, EDS, XRD, and element maps analysis. At the vanadium slag surface that the diffused Ca dose not reached, the main generated phases were Mn2O3 and Fe2O3. V3+ was oxidized to V5+ and reacted with the Ca2+ to form a small amount of Ca2V2O7. Cr was at a disadvantage compared with V in occupying the original Ca2+ of the slag. At the vanadium slag surface that the diffused Ca had reached, the main generated phases were Ca2V2O7. At the CaO surface, the main generated phases were Ca2V2O7 and Ca3V2O8. The interdiffusion coefficients were calculated by a new approach that modified from the Boltzmann-Matano method including the determination of the Matano surface, calculation of the integral and differential using the raw data of the concentration profiles. As the molar fraction of Ca was in the range of 0.15 to 0.