Mckinleyhong9363

The overburden waste should be considered for use in removing heavy metals in-situ.Cenospheres (CS) are spherical shaped inorganic frameworks present in with fly ash which is generated from coal-fired thermal power plants. These spherical structures were functionalized with imidazole and amine moieties to capture CO2 selectively from flue gases at elevated temperature. The functionalized CS have shown a high selectivity for CO2 adsorption (4.68 mmol g-1) over N2 (0.46 mmol g-1) at 333 K/1 bar from a simulated flue gas (0.15 CO2 and 0.85 N2, v%) composition of thermal power plants. When the moisture content reached to 30 vol% the adsorption capacity of CS materials was reduced to 20 vol% as compared to dry flue gas. The functionalized CS can be used repeatedly for 50 cycles without losing its adsorption capacity. The cost estimate for CO2 capture by using the proposed adsorption system would be $12.01/ton of CO2 which is lower as compared to amine absorption system and zeolite-based adsorption system reported in the literature. The CS materials are prepared from solid wastes reduce the cost of production and their large scale manufacturing is technically feasible to capture CO2 from industrial flue gases efficiently in near future.Low-temperature selective catalytic reduction of NOx by NH3 (NH3-SCR) for diminishing SO2 poisoning remains an issue in flue gas denitrification (DeNOx). Herein, A novel CNTs functionalized low temperature NH3-SCR catalyst CeO2/CNTs-GAC was prepared, which showed high NO conversion activity (100% at 150 °C) and SO2 resistance. The addition of CNTs restrained SO2 adsorption but improved the selective adsorption of NO, which restricted the deposition of (NH4)2SO4 and/or Ce2(SO4)3, and resulted in high SO2 resistance. The addition of CNTs facilitated the diffusion and transportation of NH3 and NO, and the electron transfer on CeO2/CNTs-GAC, leading to higher content of Ce3+ and adsorbed O species on the CeO2/CNTs-GAC surface and promoted formation of surface-adsorbed oxygen OA. Therefore, CeO2/CNTs-GAC provided abundant NO adsorption and activation sites, facilitating "fast SCR" reaction and enhancing the NH3-SCR reaction. The proposed CeO2/CNTs-GAC catalyst exhibited higher NH3-SCR activity, N2 selectivity, catalytic durability and SO2 resistance than CeO2/GAC.This research study investigated the synthesis of environmentally benign green emulsion liquid membrane (GELM) employing waste cooking oil (WCO) as diluent. The emulsion was prepared using D2EHPA as the carrier, Span 80 as surfactant, and sulphuric acid as internal/stripping agent. The influence of nine operating variables namely, Span 80 concentration, D2EHPA concentration, shaking time, shaking speed, pH of the feed, treat ratio (TR), H2SO4 concentration, lead concentration in feed, and volume ratio of organic phase to aqueous phase (O/A) on the performance of lead extraction was studied. Plackett Burman design (PBD), was employed for the screening of variables. The Pareto analysis shows that six variables were the most significant variables at the confidence level of 95%. The selected variables were then screened applying Box-Behnken design (BBD). The optimum values of the variables were D2EHPA concentration - 4.6 (v/v%), Span 80 concentration - 2.14 (v/v%), pH of the feed - 4.4, internal phase (H2SO4) concentration - 2 M, initial lead concentration - 173 ppm, phase ratio (O/A) - 1.3. At these optimum conditions, a maximum lead extraction of 97.39% was obtained. The mechanism for the extraction of lead was analyzed. Reuse and recycling of membrane phase show that the GELM can be recycled for 7 cycles without reduction in lead extraction efficiency. Kinetic analysis of lead extraction was performed using zero, first, and second-order model at optimum condition. The experimental data fitted well with first-order (R2 - 0.9653). Thermodynamic studies indicated that the extraction procedure is endothermic, spontaneous in nature.In this study, wasted sediment (sludge waste from shipping docks) was coupled with titanium isopropoxide by the thermal and sol-gel method as a new photocatalyst. The sediment-titanate catalyst alongside ultrasonic and UV was activated hydrogen peroxide to produce OH radicals and decompose cephalexin (CEP). The photocatalyst was crystalline with 52.29 m2/g BET area. The best destruction rate of 87.01% based on COD test was achieved at optimal conditions (pH 8, cephalexin concentration 100 mg/L, H2O2 1.63 mg/L, UV 15 W/m2, ultrasonication time 100 min at 40 kHz, photocatalyst quantity 1.5 g/L). The trend of anions effect was NO3- ≤ SO42- ≤ Cl-. Decomposition of cephalexin in water solution followed the first-order kinetics (k > 0.01 min-1, R2 > 0.9). The percentage of cephalexin removal from urban water (76%) and hospital wastewater (63%) has decreased compared to the distilled water solution (87%), which is probably due to the presence of radical inhibitors. The consumed electrical energy of the studied system was calculated by 0.031 kW/h. The developed system is a promising and economical method to remove cephalexin.Although Tween-20 was used as an important catalyst to increase chalcopyrite bioleaching rate by acidophiles, the effect of Tween-20 on initial adhesion and biofilm development of acidophiles on chalcopyrite has not been explored until now. Herein, the role of Tween-20 in early attachment behaviors and biofilm development by Acidianus manzaensis strain YN-25 were investigated by adhesion experiments, adhesion force measurement, visualization of biofilm assays and a series of analyses including extended Derjaguin Landau Verwey Overbeek (DLVO) theory, scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The bacterial adhesion experiments showed that 2 mg/L of Tween-20 increased the adhesion percentage (by 8%) of A. manzaensis YN-25. Tween-20 could promote the early adhesion of A. manzaensis YN-25 by changing the Lewis acid-base interaction and electrostatic force to increase total interaction energy and adhesion force. Besides, the functional groups on the surface of cells (carboxyl, hydroxyl and amino functional groups) contributed to the adhesion of A. manzaensis YN-25 on chalcopyrite. Furthermore, the promotion of biofilm formation by Tween-20 was mainly attributed to the reduction of S0 passivation layer formation and complexing more Fe3+ on chalcopyrite surface, contributing to the erosion of chalcopyrite and creating more corrosion pits. Live/dead staining showed low live/dead ratio (ranged from 0.35 to 1.32) during the biofilm development process. This report offers a better understanding of the effects of Tween-20 on attachment and biofilm development of acidophilic microorganisms and would lay a theoretical foundation for the better application of catalyst in bioleaching.Long-lived environmentally persistent free radical (EPFR) exposures have been shown in toxicology studies to lead to respiratory and cardiovascular effects, which were thought to be due to the persistence of EPFR and their ability to produce reactive oxygen species. To characterize EPFR exposure and resulting health impacts, it is necessary to identify and systematize analysis protocols. Both direct measurement and solvent extraction methods have been applied to analyze environmental samples containing EPFR. The use of different protocols and solvents in EPFR analyses makes it difficult to compare results among studies. In this work, we reviewed EPFR studies that involved solvent extraction and carefully reported the details of the extraction methodology and retrieval recovery. EPFR recovery depends on the structure of the radical species and the solvent. For the limited number of studies available for review, the polar solvents had superior recovery in more studies. Simvastatin Radicals appeared to be more oxygen-centered following extraction for fly ash and particulate matter (PM) samples. Different solvent extraction methods to retrieve EPFR may produce molecular products during the extraction, thus potentially changing the sample toxicity. The number of studies reporting detailed methodologies is limited, and data in these studies were not consistently reported. Thus, inference about the solvent and protocol that leads to the highest EPFR extraction efficiency for certain types of radicals is not currently possible. Based on our review, we proposed reporting criteria to be included for future EPFR studies.Composting could be applied to dispose various organic solid wastes and liquid wastes. Literature suggested that reusing a nitrogen-rich wastewater as a composting moisture conditioning agent could promote the maturity and nitrogen content of compost. However, it's unclear whether a nitrite-rich wastewater could be eliminated by composting because of the toxicity of nitrite. In this study, a nitrite-rich wastewater (STL, pH = 7.9) was reused as a composting moisture conditioning agent. The influence of STL reusing period (i.e., adding STL from the first day of mesophilic, thermophilic, and cooling period, and the addition lasted for 10 days) on composting performance was also discussed. Results revealed that organic matter decomposition was strongly suppressed by high concentration of free nitrous acid when STL was added in mesophilic period, whereas the organic matter hydrolysis was prompted when STL was added in thermophilic and cooling period. STL addition enhanced nitrification at high temperatures during composting, thus increasing the nitrate content of compost by 2-10 times compared with that of the control group (using tap water as a moisture conditioning agent). Nitrite addition also stimulated nitrous oxide emissions yielded by biotic or chemical processes during STL addition, especially under the transient condition at 50°C-55 °C, and resulted in a 28%-39% increase in greenhouse gas emissions compared with that of the control group. Therefore, the composting could be a solution of eliminating a nitrite-rich wastewater by reusing it as a moisture conditioning agent when nitrous oxide emission issue was properly addressed.Chromium is an insidious ecological pollutant that is of huge value for its toxicity. The existing ecological objective to lower the heights of toxic materials in marine systems and to stimulate the existing water to recycle after suitable treatment of wastewater. Chromium is a hazard element that appears in discharges of numerous industries that must be diminished to accomplish the goals. Nearly all of the findings described in the literature related to the usage of various materials such as fungal, algal, bacterial biomass, and nanomaterials for chromium adsorption. The current work evaluates the findings of research commenced in the preceding on the use of a variety of adsorbents to decrease chromium concentrations in contaminated waters. This review article focuses on the issue of chromium contamination, its chemistry, causes, consequences, biological agent remediation techniques, and the detailed process of chromium detoxification in microbial cells. It also lists a description of the in situ and ex situ chromium bioremediation methods used. This can help design more effective Cr(VI) removal methods, thus bridging the difference between laboratory discoveries and industrial chromium remediation applications.