Udsenalmeida8206

The autonomic movement process and heartbeat rate of the zebrafish larvae showed significant differences as the exposure concentration of iohexol increased. The catalytic ozonation process with α-Fe0.9Mn0.1OOH can decrease the toxicity of iohexol containing water.Se is a beneficial nutrient for some plant species, while As is considered a toxic element, even at low concentrations. This study investigated the interaction between As and Se on golden flaxseed (Linum usitatissimum L.) seedlings to better understand the extent of Se in the mitigation of As uptake and translocation. In addition, co-exposure experiments allowed to determine how As and Se affected absorption and distribution of the essential micronutrients Fe, Zn and Mn. Seedlings were cultivated in a 10 % v v-1 Hoagland solution supplemented with AsV, SeIV, SeVI or AsV + SeIV at different concentrations. SeVI presented the highest toxicity and translocation factor. The toxicity of AsV was attenuated by SeIV, which stimulated As uptake and translocation. SeIV reduced As accumulation, establishing a tolerance mechanism. Only a high concentration of As (200 μmol L-1) led to leaf chlorosis or seedling death, independently of co-exposure with Se species. Co-exposure also altered the uptake of Fe, Zn and Mn, without affecting As translocation from roots to shoot. In general, the interaction of As with Se was beneficial for golden flaxseed seedlings, when compared to the effects of As solely.Production of multi-functional zinc oxide nanoparticles (ZnO-NPs) for wastewater treatment through green-approaches is a desirable alternative for conventional synthesis routes. Biomass waste valorization for nanoparticles synthesis has received increased research attention. The present study reports date pulp waste (DPW) utilization as an effective bio-reductant for green-synthesis of ZnO-NPs. A simple and eco-friendly process with low reaction time and calcination temperature was adopted for DPW mediated ZnO-NPs (DP-ZnO-NPs) synthesis. Microscopic investigations of DP-ZnO-NPs confirmed the non-agglomeration and spherical nature of particles with mean diameter of 30 nm. EDX and XPS analysis defined the chemical composition and product purity of DP-ZnO-NPs. UV and photoluminescence studies exhibited surface plasmonic resonance at 381 nm and fluorescent nature of DP-ZnO-NPs. FTIR studies established a formation mechanism outline for DP-ZnO-NPs. XRD and Raman investigations confirmed the crystalline and hexagonal wurtzite phase of DP-ZnO-NPs. DSC/TG analysis displayed the thermal stability of DP-ZnO-NPs with less then 10 wt% loss upto 700 °C. Photocatalytic degradation of hazardous methylene blue and eosin yellow dyes using DP-ZnO-NPs, showed rapid decomposition rate with 90 % degradation efficiency. Additionally, DP-ZnO-NPs demonstrated significant antibacterial effects on various pathogenic bacteria in terms of zone-of-inhibition measured by disc-diffusion method. Thus, the as-prepared DP-ZnO-NPs is suitable for industrial wastewater treatment.Sulfate radical-advanced oxidation processes (SR-AOPs) are emerging technologies for decomposing organic pollutants in water. This study investigated the efficiency of UV/persulfate (UV/S2O82-) process to degrade lindane in water, showing 93.2% lindane removal ([lindane]0 = 3.43 μM, [S2O82-]0 = 100 μM) at a UV fluence of 720 mJ/cm2. The lindane degradation followed first order kinetics and mechanistic studies suggested H-abstraction by SO4•- and Cl removal via C-Cl bond cleavage by UV-C light. Toxicity assessment using ECOSAR program showed toxicity gradually decreased and eventually no significant toxicity remained when all by-products vanished at high UV dose. Removal efficiency of lindane decreased from 93.2% to 38.4, 45.5, 56.0, 84.3 and 88.6%, by adding 1.0 mg/L humic acid or 1.0 mM CO32-, HCO3-, Cl- or SO42-, respectively. Coupling of H2O2 with UV/S2O82- showed a significant synergistic effect with 99.0% lindane removal at a UV fluence of 600 mJ/cm2, using [S2O82-]0 = [H2O2]0 = 50 μM while UV/H2O2 resulted in only 36.6% lindane removal ([lindane]0 = 3.43 μM, [H2O2]0 = 100 μM) at a UV fluence of 720 mJ/cm2. The results indicate that SR-AOP has potential for consideration as a remedial technology to treat persistent chlorinated pesticides such as lindane in contaminated water.Bifunctional photoelectrochemical (PEC) process for simultaneous hydrogen production and mineralisation of humic acid in water using TiO2-1 wt% Au@TiO2/Al2O3/Cu2O multi-layered p-type photoelectrodes is demonstrated. The newly designed bifunctional PEC system leads to a high degradation efficiency of dissolved humic compounds, the target pollutant, by up to 87% during 2 h reaction time. Simultaneously, humic acid is also served as a sacrificial electron donor in the proposed system, contributing to a high photocurrent density of the multi-layered p-type Cu2O photoelectrodes up to -6.32 mA cm-2 at 0 V vs. Reversible Hydrogen Electrode (RHE) under the AM 1.5 simulated 1-Sun solar illumination. The Z-scheme feature of this bifunctional PEC devices exhibiting a short-circuit photocurrent density of -0.45 mA cm-2 and solar-to-hydrogen conversion (STH) of 0.5 % in the presence of humic acid sheds light on the new bias-free artificial photosynthesis PEC system.An efficient, environment-friendly and economical catalyst to control contaminants of environment is an enduring interest in recent years. In this study, a new composite, DyxMnFe2-xO4nanoparticles decorated over mesoporous silica was synthesized and utilized for removal of organic pollutant. Highly crystalline nature of DyxMnFe2-xO4 nanoparticles and amorphous nature of material was confirmed by XRD (X-ray diffraction) technique. Infrared spectra of fabricated material before and after adsorption of dye molecules evidenced the successful adsorption of dye molecules by fabricated adsorbent. From field emission scanning electron microscopic (FESEM) images of Dy3+ substituted MnFe2O4 composite with mesoporous silica, it was clearly observed that ferrite particles of size 20-30 nm were decorated on the surface of mesoporous silica particles and distributed well over spherical silica balls homogeneously. Its magnificent mesoporous nature was revealed from BET (nitrogen adsorption-desorption measurements) analysis. Surface area, pore volume and average pore size was found 387.95 m2/g, 0.390 cm3/g and 4.02 nm respectively. Tri-modal pore size distribution showed its effective utilization in adsorption. The abundant (SiOH) hydroxyl groups of mesoporous silica, the broad diffraction hump of silica depicted its superior loading capacity of target molecular specie inside its porous network. From band gap analysis, a red shift of 2.43 eV exhibited semiconductor photocatalysis of DyxMnFe2-xO4 nanoparticles. Degradation efficiency of bare MnFe2O4, DyxMnFe2-xO4 and mesoporous silica-based composite was tested using crystal violet dye. Its explored adsorption-photocatalysis synergy, degradation mechanism, kinetic investigation, easily recovery and remarkable recycling ability suggested that the new fabricated composite is best for environmental remediation.Maize has to avoid excess tissue accumulation of Cl- to withstand conditions of Cl--salinity. Restriction of loading of Cl- into the root xylem is one mechanism to keep shoot Cl--concentrations low. The proportion of Cl- that reaches the shoot has to be stored away from the primary site of photosynthesis and growth. We tested whether or not maize is able to re-translocate significant amounts of Cl- from shoot back to root and out into the rooting media. Ion analysis revealed that maize cannot re-translocate Cl-; however, it is stored in sheaths of the old leaves and, surprisingly, in roots. Sequestration of Cl- in the roots might be a strategy to keep concentrations low in young growing shoot tissues and in leaf blades where photosynthesis is running.Nitric oxide (NO) is a key signaling molecule that instigates significant changes in plant metabolic processes and promotes tolerance against various environmental stresses including drought. In this study, we focused on NO-mediated physiological mechanisms and enzymatic activities that influence the nutrient concentrations and yield in maize under drought stress. The drought-tolerant (NK-8711) and sensitive (P-1574) maize hybrids were sown in lysimeter tanks and two levels of water stress (well-watered at100% field capacity and drought stress at 60% field capacity) were applied at three-leaves stage of maize. selleck Foliar treatment of sodium nitroprusside (SNP), the donor of NO was applied at the cob development stage. The results showed that the foliar spray of NO regulated water relations by increasing proline content and improved drought tolerance in water stressed maize plants. In addition, it stimulated the activity of antioxidative enzymes which reduced the production of free radicals and lipid peroxidation. The activities of nitrate assimilation enzymes were considerably increased by NO spray which, in turn, increased nutrient accumulation and yield in maize under water deficit conditions. These results acknowledge the importance of NO as a stress-signaling molecule that positively regulates defense mechanisms in maize to withstand water-limited conditions.Developing superwetting membranes with interconnected pore and multi-scale roughness for efficient oily water separation is significant but challenging owing to the limitations of low water flux and membrane fouling. Herein, we report a scalable method to develop superwetting membranes with superhydrophilicity and underwater superoleophobicity for oily water separation. This novel approach, composed of electrospinning/electrospraying of polyacrylonitrile (PAN), was to fabricate rough sphere membrane substrate, followed by in-situ polymerization of dopamine/polyethyleneimine (DA/PEI) to positively charge the fiber skin and then subsequent immersed into the negatively charged Ludox solution to construct rough membrane surface via electrostatic attraction. Benefiting from the rough sphere surface of the fibrous skin layer, the resultant membrane displayed micro/nanostructured surfaces with intriguing in-air superhydrophilicity of 0° and underwater superoleophobicity of 166° as well as robust oil-proof pressure of 83.55 kPa. As a proof-of-concept, the resultant membrane achieved high water flux and oil rejection efficiency as well as fantastic durability and antifouling performance toward the separation of highly emulsified oily water. The integration of electrospinning/electrospraying with bioinspired method is also expected to fabricate superwetting sphere surface membrane with interconnected pores for other selective separation applications.Three experiments were conducted to determine influence of the bovine corpus luteum (CL) on morphometric and functional characteristics of oocytes, and subsequent embryonic development. Cumulus-oocyte complexes were aspirated from two types of cows 1) with a CL in one ovary (CL+) and without a CL in the contralateral ovary (CL-), 2) and from cows without CL in either ovary (C). Intracellular activity of the enzyme glucose-6-phosphate dehydrogenase (G6PDH), oocyte diameter and thickness of the zona pellucida were determined (Experiment 1). Then, the rate of in vitro oocyte maturation for each ovarian category was evaluated and oocyte diameter and zona pellucida thickness were measured after maturation (Experiment 2). In Experiment 3, in vitro embryo production and cryotolerance were assessed. The oocyte diameter was greater (P 0.05) or C (P = 0.0131) ovaries. Activity of G6PDH was lower in oocytes from CL+ than CL- (P less then 0.01) and C (P = 0.0148) ovaries. Rate of oocyte maturation, oocyte diameter and thickness of the zona pellucida after maturation did not differ among groups.