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Interestingly, the abundance of fecal indicator bacteria and pathogens were shifted dramatically according to high-streamflow and low-streamflow seasons in the Bay. The data are useful to construct the model of risk assessment in coastal estuaries system and predict the effects of extreme flooding events in the future.Cadmium (Cd) is a toxic heavy metal pollutant. Various industrial activities, especially metal smelting, are the main sources of Cd pollution. Cd isotopes have exhibited the ability to be excellent source tracers and can be used to assess the pollution contributions from different sources. Herein, in a typical lead-zinc smelter, Shaoguan, China, significant Cd isotopic fractionation was found during the high temperature smelting process and followed a Rayleigh distillation model. The heavier Cd isotopes were concentrated in the slag, while the lighter Cd isotopes were concentrated in the dust. In the downstream sediment profile of the smelter, sediments have extremely high Cd concentrations that far exceed the Chinese background sediment, indicating severe pollution levels. The ε114/110Cd of the sediment core, ranged from - 0.62 ± 0.5-1.73 ± 0.5, are found between slag (ε114/110Cd=10.42) and dust (ε114/110Cd=-5.68). The binary mixture model suggests that 88-93% of the Cd in sediment profile was derived from the slag, and 7-12% from the deposition of dust. The findings demonstrate the great potential to apply Cd isotopes as a new geochemical tool to distinguish anthropogenic sources and quantify the contribution from various sources in the environment.Rational design of fiber-shaped gas sensors with both excellent mechanical properties and sensing performance is of great significance for boosting future portable and wearable sensing electronics, however, it is still a challenge. Herein, we develop a novel fiber-shaped hydrogen (H2) sensor by directly electrochemically growing palladium (Pd) sensing layer on conductive poly(3,4-ethylenedioxythiophene)poly(styrene sulfonate) (PEDOTPSS) fiber electrode. This approach produces free-standing functional fiber (PEDOTPSS@Pd) with promising mechanical features of flexibility, light weight, knittability and high mechanical strength, and good H2 sensing performance at room temperature. The PEDOTPSS@Pd fiber sensor exhibits short response time of 34 (± 6) s@1% and 19 (± 4) s@4% H2 and excellent cycling stability. In addition, the fiber sensor remains good sensing behavior under different mechanical bending states, showing potential for constructing wearable sensor devices for timely H2 leak detection. Therefore, this work has provided a smart design strategy of fiber-based gas sensor, offering an effective sensing platform and is believed to stimulate the development of wearable electronics.This work reports the electrochemical detection of highly hazardous material 4-Nitroaniline (4-NA) based on the metal oxide-rGO composite materials. The potassium intercalated MnO2-rGO composite material was prepared by a simple one-pot reduction method. The K+ intercalation on K-MnO2-rGO was confirmed by X-ray photoelectron spectroscopy (XPS) and Raman analysis. The amorphous nature of prepared material was scrutinized by high-resolution transmission electron microscopy (HRTEM) and selected area electron diffraction (SAED) pattern analysis. The elemental compositions are done by energy dispersive X-ray Analysis (EDX) mapping. The prepared composite material K-MnO2-rGO was used to determine the 4-NA by differential pulse voltammetry (DPV). The electroanalytical performances of fabricated K-MnO2-rGO/SPCE were compared with the K-MnO2 and rGO in pH 7. The developed 4-NA sensor showed good sensitivity (2.85 µA µM-1 cm-2), linear range (0.001-10.53 µM), and LOD (0.7 nM). Furthermore, the K-MnO2-rGO/SPCE exhibited high selectivity with the other potential interfering nitro compounds in river water and pond water samples. Therefore the developed sensor can be applied for the determination of noxious pollutants in real-time monitoring devices.Wearing face masks has become the new normal worldwide due to the global spread of the coronavirus disease 2019. The inhalation of microplastics due to the wearing of masks has rarely been reported. The present study used different types of commonly used masks to conduct breathing simulation experiments and investigate microplastic inhalation risk. Microplastic inhalation caused by reusing masks that underwent various treatment processes was also tested. Results implied that wearing masks considerably reduces the inhalation risk of particles (e.g., granular microplastics and unknown particles) even when they are worn continuously for 720 h. Surgical, cotton, fashion, and activated carbon masks wearing pose higher fiber-like microplastic inhalation risk, while all masks generally reduced exposure when used under their supposed time ( less then 4 h). N95 poses less fiber-like microplastic inhalation risk. [https://www.selleckchem.com/products/cl-amidine.html check details] Reusing masks after they underwent different disinfection pretreatment processes can increase the risk of particle (e.g., granular microplastics) and fiber-like microplastic inhalation. Ultraviolet disinfection exerts a relatively weak effect on fiber-like microplastic inhalation, and thus, it can be recommended as a treatment process for reusing masks if proven effective from microbiological standpoint. Wearing an N95 mask reduces the inhalation risk of spherical-type microplastics by 25.5 times compared with not wearing a mask.<br /><br /> Cancellation of university classes during the coronavirus disease 2019 pandemic challenges teaching inperson sexual history-taking skills to medical, physician assistant, and nursing students. We used commercial online electronic services for medical students to learn sexual history-taking skills.<br /><br /> A total of 174 medical students viewed a lecture on sexual history taking and the PLISSIT model (Permission, Limited Information, Specific Suggestion, Intensive Therapy) and were then randomized into dyads. They arranged a time to meet online on Zoom with their partner, chose a simple sexual history case-history (male or female) from a small selection, and recorded the 5- to 6-minute sexual history within a 1-week time frame. Each student played a "provider" or "patient" and then switched roles with a new case. One of the course tutors, all sexual health practitioners, downloaded 10 videos randomly assigned to them asynchronously and viewed and commented on the interaction of each "provider" along with comments on what to improve in the sexual history.