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3&nbsp;mL/g). These results confirm that sludge morphology is not necessarily a reflection of the cell morphology of the bacteria, but is highly influence by reactor operation. It also reiterates the fact that compact biofilms are formed when the substrate consumption rate is lower than the substrate transport rate. Wetting by fouling is phenomenon specific to membrane distillation (MD) and are regarded as challenges to the seawater membrane distillation (SWMD) process. To understand fouling and wetting, the influence of Mg and Sr crystals, which can potentially cause scaling, as well as Ca crystals deposited on the membrane surface were investigated. Mg(OH)2 and CaSO4 had significant impact on fouling and wetting. Even if CaCO3 and SrSO4 had no effects on fouling and wetting as single salts, CaCO3 and CaSO4 were dominant in synthetic seawater without Mg(OH)2. However, the occurrence of Mg(OH)2 scales became a cause for concern if Ca ion was removed from seawater for the prevention of fouling and wetting. Therefore, Mg as well as Ca should be removed for proper fouling and wetting control. [https://www.selleckchem.com/products/Bleomycin-sulfate.html read more] NaOH/Na2CO3 softening was used for the removal of Ca and Mg ions. In addition, based on the inhibition effects of Mg ions on Ca scales, a new pretreatment method involving the injection of MgCl2 to increase the Mg /Ca ratio was examined. Metalimnetic oxygen minima are observed in many lakes and reservoirs, but the mechanisms behind this phenomena are not well understood. Thus, we simulated the metalimnetic oxygen minimum (MOM) in the Rappbode Reservoir with a well-established two-dimensional water quality model (CE-QUAL-W2) to systematically quantify the chain of events leading to its formation. We used high-resolution measured data to calibrate the model, which accurately reproduced the physical (e.g. water level and water temperature), biogeochemical (e.g. nutrient and oxygen dynamics) and ecological (e.g. algal community dynamics) features of the reservoir, particularly the spatial and temporal extent of the MOM. The results indicated that around 60% of the total oxygen consumption rate in the MOM layer originated from benthic processes whereas the remainder originated from pelagic processes. The occurrence of the cyanobacterium Planktothrix rubescens in the metalimnion delayed and slightly weakened the MOM through photosynthesis, although its decaying biomass ultimately induced the MOM. link2 Our research also confirmed the decisive role of water temperature in the formation of the MOM since the water temperatures, and thus benthic and pelagic oxygen consumption rates, were higher in the metalimnion than in the hypolimnion. Our model is not only providing novel conclusions about the drivers of MOM development and their quantitative contributions, it is also a new tool for understanding and predicting ecological and biogeochemical water quality dynamics. Insect-borne parasite Trypanosoma brucei plagues humans and other animals, eliciting the disease Human African trypanosomiasis, also known as African sleeping sickness. This disease poses the biggest threat to the people in Sub-Saharan Africa. Given the high toxicity and difficulties with administration of currently available drugs, a novel treatment is needed. Building on known Human African trypanosomiasis structure-activity relationship (SAR), we now describe a number of functionally simple diphenyl ether analogs which give low micromolar activity (IC50&nbsp;=&nbsp;0.16-0.96&nbsp;μM) against T. b. rhodesiense. The best compound shows favorable selectivity against the L6 cell line (SI&nbsp;=&nbsp;750) and even greater selectivity (SI&nbsp;=&nbsp;1200) against four human cell lines. The data herein provides direction for the ongoing optimization of antitrypanosomal diphenyl ethers. This study examines the projected precipitation extremes for the end of 21st century (2081-2100) over Southeast Asia (SEA) using the output of the Southeast Asia Regional Climate Downscaling/Coordinated Regional Climate Downscaling Experiment - Southeast Asia (SEACLID/CORDEX-SEA). Eight ensemble members, representing a subset of archived CORDEX-SEA simulations at 25&nbsp;km spatial resolution, were examined for emission scenarios of RCP4.5 and RCP8.5. The study utilised four different indicators of rainfall extreme, i.e. the annual/seasonal rainfall total (PRCPTOT), consecutive dry days (CDD), frequency of extremely heavy rainfall (R50mm) and annual/seasonal maximum of daily rainfall (RX1day). In general, changes in extreme indices are more pronounced and covering wider area under RCP8.5 than RCP4.5. The decrease in annual PRCPTOT is projected over most of SEA region, except for Myanmar and Northern Thailand, with magnitude as much as 20% (30%) under RCP4.5 (RCP8.5) scenario. The most significant and robust changes were noted in CDD, which is projected to increase by as much as 30% under RCP4.5 and 60% under RCP8.5, particularly over Maritime Continent (MC). The projected decrease in PRCPTOT over MC is significant and robust during June to August (JJA) and September to November (SON). During March to May (MAM) under RCP8.5, significant and robust PRCPTOT decreases are also projected over Indochina. The CDD changes during JJA and SON over MC are even higher, more robust and significant compared to the annual changes. At the same time, a wetting tendency is also projected over Indochina. The R50mm and RX1day are projected to increase, during all seasons with significant and robust signal of RX1day during JJA and SON. BACKGROUND Waterpipe tobacco smoking has grown in popularity worldwide, with the prevalence of use increasing in Spain from 6.2% to 10.8% in the last decade, despite the smoking ban enacted in 2010 for all hospitality premises. OBJECTIVE To assess exposure to second-hand smoke from waterpipes based on the concentrations of airborne nicotine and particulate matter ≤2.5&nbsp;μm in diameter (PM2.5) in a sample of waterpipe cafés in the city of Barcelona (Spain). METHODS This cross-sectional study included a sample of 20 waterpipe cafés. Airborne nicotine and PM2.5 were sampled for 30&nbsp;min in each venue using a nicotine sampling device connected by a tube to a pump and a TSI SidePak Personal Aerosol Monitor. Five outdoor control locations were also measured. We computed medians, interquartile ranges (IQRs), and maximum values and compared them according to venues' and sampling characteristics using the Kruskall-Wallis and U-Mann Whitney tests. Nicotine and PM2.5 were correlated by calculating the Spearman-rank correlation coefficient. RESULTS The median concentration of nicotine and PM2.5 were 1.15 and 230.50&nbsp;μg/m3 in waterpipe cafés and 0.03 and 10.00&nbsp;μg/m3 in control locations (p8 waterpipes/100&nbsp;m2, and a ratio of 2 users per waterpipe or less had significantly higher nicotine concentration. DISCUSSION Despite the current smoking ban, which includes hospitality venues, we found nicotine and PM2.5 levels in Barcelona waterpipe cafés that exceeded the threshold recommended by the World Health Organization. This exposure poses serious risks to the health of both workers and customers and constitutes a non-compliance of the legislation. Autism spectrum disorder (ASD) is a complex neurodevelopmental pathology characterized by altered verbalizations, reduced social interaction behavior, and stereotypies. Environmental factors have been associated with its development. link3 Some researchers have focused on pesticide exposure. Chlorpyrifos (CPF) is the most used Organophosphate. Previous developmental studies with CPF showed decreased, enhanced or no effect on social outcomes eminently in mice. The study of CPF exposure during preweaning stages on social behavior is sparse in mice and non-existent in rats. d stressors could be at the basis of ASD development, and around postnatal day 10 in the rat is equivalent to the human birthday in neurodevelopmental terms. We explored the effects of exposure to low doses (1mg/kg/mL/day) of CPF during this stage regarding sociability, dominance gut microbiome and plasma metabolomic profile, since alterations in these systems have also been linked to ASD. There was a modest influence of CPF on social behavior in adulthood, with null effects during adolescence. Dominance and hierarchical status were not affected by exposure. Dominance status explained the significant reduction in reaction to social novelty observed on the sociability test. CPF induced a significant gut microbiome dysbiosis and triggered a hyperlipidemic, hypoglycemic/hypogluconeogenesis and a general altered cell energy production in females. These behavioral results in rats extend and complement previous studies with mice and show novel influences on gut metagenomics and plasma lipid profile and metabolomics, but do not stablish a relation between the exposure to CPF and the ASD phenotype. The effects of dominance status on reaction to social novelty have an important methodological meaning for future research on sociability. Azithromycin (AZ) and ciprofloxacin (CIP) are commonly prescribed antibiotics frequently detected in municipal biosolids and identified by the USEPA as contaminants of emerging concern. The land application of municipal biosolids is an agronomically beneficial practice but is also a potential pathway of CIP and AZ release into the environment. Understanding retention-release behavior is crucial for assessing the environmental fate of and risks from land-applied biosolids-borne target antibiotics. Here, we used batch equilibrations to assess retention and release of environmentally relevant concentrations of CIP and AZ in ten different biosolids. The biosolids included Class A and Class B materials with a range of physiochemical characteristics (e.g. pH, cation exchange capacity (CEC), organic matter content (OM), and iron (Fe) and aluminum (Al)) expected to influence retention and release of AZ and CIP. Retention was linear (R2&nbsp;&gt;&nbsp;0.99 for AZ and &gt;0.96 for CIP) and sorption coefficients (Kd) ranged from 52 to 370&nbsp;L&nbsp;kg-1 for AZ and 430-2300&nbsp;L&nbsp;kg-1 for CIP. Desorption also varied but was highly hysteretic, with hysteresis coefficients (H) ranging 0.01 to 0.15 for AZ and ≤0.01 for CIP, suggesting limited bioaccessibility. The penalized and shrinkage method least absolute shrinkage and selection operator (LASSO) was used to produce models describing AZ and CIP sorption behavior based on any given biosolids physiochemical characteristics. Multiple linear regression analysis linked AZ sorption behavior to total Fe content, likely due to a predisposition of AZ to participate in reactions with in situ Fe species. CIP sorption behavior was linked to oxalate extractable Al and total phosphorus (P) content, suggesting CIP bonding with amorphous forms of Al and a potential relationship between CIP sorption to biosolids and biosolids production processes, as manifested by correlation of CIP sorption with total P content. Eutrophication which caused by excessive phosphorus in aquatic environment is a worldwide problem. Phosphorus is a nonrenewable resource widely used in agriculture and industry. Therefore, the development of economical methods for phosphorus capture and reuse from wastewater is urgently needed. In this study, a novel granule chitosan inlaid with γ-AlOOH on its structure (γ-AlOOH@CS) was prepared for phosphate removal with a recycle manner. Results showed that γ-AlOOH@CS exhibited a fast phosphate removal of 0.5&nbsp;h for half adsorption capacity. The material presented a high adsorption capacity of 45.82&nbsp;mg/g, the adsorption capacity maintained stability at pH 4-6, and favorable selectivity was observed when compared with other common anions. Column experiment was also performed well in treatment of the simulated wastewater. Isotherms and thermodynamics studies indicated that phosphate adsorption onto γ-AlOOH@CS was heterogeneous, spontaneous and exothermic. In material recycle experiment, by using NaOH solution as solvent and phosphoric acid as precipitant under hydrothermal reaction conditions, the products of chitosan, aluminum phosphate and sodium dihydrogen phosphate were obtained, with their purity reaching the industrial standard.