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The lack of stable electrode materials for water-based electrolytes due to the intercalation and conversion reaction mechanisms encourage scientists to design new or renovate existing materials with better cyclability, capacity, and cost-effectiveness. Ag4[Fe(CN)6] is a material belonging to the Prussian blue family that can be used, as its other family members, as an electrode material with the intercalation/deintercalation reaction or conversion-type mechanism through Ag oxidation/reduction. However, due to the instability of this material in its dry state, it decomposes to AgCN and a Prussian blue residual complex. A possible reason for Ag4[Fe(CN)6] decomposition is discussed. Nevertheless, it is shown that the decomposition products of Ag4[Fe(CN)6] have electrochemical activity due to the reversible oxidation/reduction of Ag atoms in water-based electrolytes.Poly(styrene-co-divinylbenzene)-based monoliths were prepared from the polymerisation of water-in-monomer high internal phase emulsions, where the water-soluble monomers acrylamide (AAm) or poly(ethylene glycol) diacrylate (PEGDA) (M w 258) were also included in the 90 vol% internal phase. Both AAm and PEGDA were found to act as co-surfactants, resulting in the obtainment of monoliths with greater homogeneity in some cases. As a result these materials demonstrated significantly improved chromatographic performance for the separation of a standard mixture of proteins using reversed-phase liquid chromatography, in comparison to monoliths prepared with no internal phase monomer. In particular, the columns grafted with PEGDA were capable of separating a more complex mixture consisting of seven components. The inclusion of monomers in the internal phase also allowed for the functionalisation of the monolith's surface where the degree of polymerisation that occurred in the internal phase, which was governed by the monomer content in the internal phase and initiation location, determined whether polymeric chains or a hydrogel were grafted to the surface. A monolith grafted with AAm was also found to be capable of retaining polar analytes as a result of the increase in surface hydrophilicity.Catalytic pyrolysis of vegetable oil is one of the potential routes to convert oil to drop-in biofuels, known as renewable hydrocarbons. In this paper, we explored catalytic pyrolysis of coconut oil using SBA-15 impregnated with Ni in proportions of 1% to 5% to produce sustainable aviation fuel. The catalysts were synthesized, calcined and then characterized by XRD, FTIR, SEM, and EDS. In order to better understand the behavior of this process, thermal and kinetic studies were carried out by thermogravimetry. The TG curves of vegetable oil with (10%) and without catalysts were obtained at heating rates of 5, 15 and 20 °C min-1, in the temperature range between 30 and 600 °C. The kinetic parameters were calculated by the Ozawa-Flynn-Wall (OFW) and Kissinger-Akahira-Sunose (KAS) methods. In the kinetic study, lower heat rates promoted higher conversions and the KAS model suits the process. The results calculated for the OC sample using the two kinetic models showed an increase in the E a energy as the conversion progressed to a certain point. Catalytic pyrolysis experiments were performed in a one-stage tubular reactor at 500 °C with a catalyst loading of 10 wt% on the basis of mass of oil. The catalyst with 5% Ni showed greater presence of hydrocarbons and greater formation of water, indicating that the deoxygenation process occurred through decarbonylation. With this, the present study was successful in the development of methodologies for obtaining hydrocarbons with a composition close to that of drop-in fuels, compared to the process carried out with vegetable oil in the absence of catalysts.Natural product synthesis remains a field in which new synthetic methods and reagents are continually being evaluated. Due to the demanding structures and complex functionality of many natural products, only powerful and selective methods and reagents will be highlighted in this proceeding. Since its introduction by Henri Kagan, samarium(ii) iodide (SmI2, Kagan's reagent) has found increasing use in chemical synthesis. Over the years, many reviews have been published on the application of SmI2 in numerous reductive coupling procedures as well as in natural product total synthesis. This review highlights recent advances in SmI2-mediated synthetic strategies, as applied in the total synthesis of natural products since 2004.Owing to the large dynamic adsorption performance and excellent mechanical strength, spherical activated carbon (SAC) has been widely applied in the field of biochemical protection. [https://www.selleckchem.com/products/wnt-agonist-1.html Wnt agonist 1 in vitro] However, the adsorbed chemical warfare agent molecules might easily escape from the pores of SAC due to the impact of ambient temperature and humidity, resulting in secondary pollution. Herein, to improve the adsorption performance of SAC, an excessive impregnation method was used to fabricate nano-silver functionalized spherical activated carbon (Ag-SAC). The surface physicochemical structure of the obtained Ag-SAC was extensively studied, and dipropyl sulfide (DPS), a simulant of sulfur mustard (HD), was employed as the adsorbate to evaluate its adsorption capability. The effects of AgNO3 impregnation concentration, reaction time, initial concentration and temperature on the adsorption performance, were investigated. The equilibrium adsorption capacity of Ag-SAC towards DPS increased by 13.41% compared with that of pristine SAC. Kinetic models, adsorption isotherm models, and adsorption thermodynamics were used to study the adsorption mechanism. The results revealed that the adsorption of DPS by Ag-SAC is a mixed synergistic process, which includes chemical adsorption and physical adsorption. Moreover, the Ag-SAC exhibited good antibacterial characteristics, with an antibacterial rate over 99.28% against Escherichia coli. We anticipate that the Ag-SAC could be a promising material for the development of high performance breathable biochemical protection clothing.A novel bio-based thermoplastic vulcanizate (TPV) material consisting of poly(lactic acid) (PLA) and a novel polymeric slide ring material (SeRM) was fabricated via isocyanate-induced dynamic vulcanization. The microscopic morphology, thermal properties, biocompatibility, and mechanical properties of the SeRM/PLA TPV material were comprehensively investigated, in turn by transmission electron microscopy, differential scanning calorimetry, in vitro cytotoxicity test, electron tension machine, and molecular dynamics simulations. Phase inversion in TPV was observed during the dynamic vulcanization, and TEM images showed that SeRM particles that were dispersed in PLA continuous phase had an average diameter of 1-4 μm. Results also indicated that an optimum phase inversion morphology was obtained at the SeRM/PLA blending ratio of 70/30 w/w. Glass transition temperature of PLA was found to be slightly decreased, owing to the improvement in interface compatibility by chemically bonding the PCL side chains (of SeRM molecules) and PLA chains. The tensile strength and elongation at break of TPVs were approximately 14.7 MPa and 164%, respectively, at SeRM/PLA blending ratio of 70/30, owing to the unique sliding effect of SeRM molecules when subjected to deformations. Cytotoxicity test results proved that the bio-based TPVs were fully non-toxic to L929 cells. In such aspects we believe that the bio-based TPV can be a promising material in the biomedical applications as an alternative of traditional commodity plastics.Spiro-heterocycles containing natural products and synthetic analogues have a broader biomedicinal application due to their rigid 3D conformation and structural implications. In this context, constructing spiro-isoxazoline systems have continued our interest in natural products and synthetic units to investigate their novel biological activities. Herein, a bromo-lactamization mediated neighboring group participation approach has been utilized on various isoxazole-amides to construct an array of spiro-isoxazoline-lactams. The easy synthesis with diverse functionalization in the periphery of a novel 3D framework could be interesting for biomedical investigation.The characteristics of biochar are of great significance to its application in the field of phase change energy storage. The objective of this research was to explore the effects of pyrolysis temperature on the characteristics of a biochar matrix and further on the heat energy storage properties of the promising green biochar-supported shape-stable biocomposite PCMs (ss-BCPCMs). Corn straw biochars (CSBCs) obtained under different pyrolysis conditions were loaded with polyethylene glycol (PEG) by an ultrasound-assisted vacuum impregnation method. The micro-morphology, specific surface area, pore structure and surface properties of biochar have been characterized and analyzed by scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) method and Fourier transform infrared spectroscopy (FTIR). The thermal properties (chemical stability, latent heat storage, thermal conductivity, thermal stability, and thermal insulation) of PEG/CSBC composites have been characterized by FTIR, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and laser flash analysis (LFA). The study revealed that both pore structure and surface activity of biochar are key factors affecting the energy storage performance of biochar-based ss-BCPCMs. The obtained PEG/CSBC composite showed a high latent heat storage up to 100.2 J g-1, good shape stability and leakage resistance, suggesting its high thermal storage stability that is beneficial for thermal energy storage applications. In addition, its excellent photothermal conversion efficiency (68.95%) provides application potential in photothermal energy storage.Nafion was investigated for its compatibility in the preparation of hybrid composites with electrospun Polybenzoxazine (PBz) surface-modified fibers by evaluating the effects on the surface and structure of the composite. A PBz fiber mat was first crosslinked by thermal treatment after electrospinning to enhance the mechanical integrity of the fibers prior to modification. Further surface modification via free radical ozonation was carried out by potentiating oxygen-based functional groups of hydroxyl radicals (-OH) onto fibers' exposed surfaces. The sequential modifications by crosslinking and ozone treatment were evaluated by analyzing surface properties using XPS, ATR-FTIR and water contact angle which determined the enhanced properties of the fibers that were beneficial to the target functionality. Electron spectroscopy confirmed that fibers' surfaces were changed with the new surface chemistry without altering the chemical structure of PBz. The presence of higher oxygen-based functional groups on fibers' surfaces based on the resulting atomic compositions was correlated with the change in surface wettability by becoming hydrophilic with contact angle ranging from 21.27° to 59.83° compared to hydrophobic pristine PBz fibers. This is due to electrophilic aromatic substitution with hydroxyl groups present on the surfaces of the fibers endowed by ozonation. The resulting surface-modified fiber mat was used for the preparation of composites by varying two process parameters, the amount of Nafion dispersion and its homogenization and curing time, which was evaluated for compatibility and interaction as fillers to form hybrid composites. The analyses of SEM images revealed the effects of shorter homogenization and curing time on composites with rougher and wrinkled surfaces shown on the final hybrid composite's structure while decreasing the amount of Nafion at the same homogenization time but longer curing time showed its influence on improvement of compatibility and surface morphology.