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The body mass index (BMI) change during pregnancy was also related to the FM-ratio. The physicochemical properties associated with lipophilicity and molecular size were also related to the FM-ratio. Even though the results should be interpreted with caution, the preliminary MLR models illustrate that feto-maternal partitioning is governed by transplacental transporting mechanisms, toxicokinetics, and the molecular physicochemical properties of POPs. Overall, the new approach used in this study can improve our understanding of the partitioning behavior in the feto-maternal system.Various kinds of vanadium (V) ore mining areas produced serious contamination have been widely recognized, while less relevant research was about the associated health risk and V distribution level for farmland soils around. This study assessed the contamination characteristics and associated human health risk of V in the surface farmland soils near various V ore mining areas. The bioremediation of V contamination by indigenous microbes from them was also evaluated. The farmland soils near stone coal area (Hunan province, China) showed the highest mean concentration of V (543.91 mg/kg), posing high non-carcinogenic risks, with high hazard quotient (HQ) value of 1.29 for children. While, V values of sampled soils near V titanomagnetite, petroleum associated minerals and uvanite areas were lower than that near stone coal area, also with lower HQ values ( less then 1.00). Within 60 h, the removal efficiency of V(V) reached 98.4% with farmland soils near uvanite area, suggesting feasibility of V bioremediation via indigenous microbes. Bacterial communities after long-term cultivation (240 d) with V(V) were dominated by native microbes able to tolerate or reduce the toxicity of V(V), such as Ruminococcaceae_incertae_sedis, Trichococcus and Comamonas. This work is helpful for calling attention to V pollution of farmland near various V ore mining areas and formulating effective strategies for V(V) contamination bioremediation.Collembolans comprise one of the most abundant groups of soil invertebrates within the arthropods. The parthenogenetic species Folsomia candida (Willem, 1902) is the most well-studied representative, being used since the beginning of the 1960s as a model organism for assessing toxicity of chemicals in soil. In this paper we aimed at answering three questions by exposing four different species of springtails (F. [https://www.selleckchem.com/products/vps34-inhibitor-1.html selleck] candida, Folsomia fimetaria, Sinella curviseta and Heteromurus nitidus) to the neonicotinoids imidacloprid and thiacloprid i) How representative as a model organism is F. candida for species of springtails that reproduce sexually? (ii) How suitable are other species of springtails to be used as model organisms for ecotoxicological testing? (iii) Is it possible to use the life history of these species to extrapolate the impact of neonicotinoids on the population level? Our results showed that F. candida is a good model organism, despite being the most sensitive species tested, when analysing both endpoints - survival and reproduction. The tests performed with S. curviseta and H. nitidus showed that they could be used as surrogates in ecotoxicity tests, and also to predict how their population might be affected after being exposed to chemicals. The adjustments made to the test performed with F. candida introducing adults (20-22 days old) into the test jars and exposing them for 21 days instead of 28 days, proved to be as efficient as the standardized test guideline (OECD 232, 2009).Photocatalytic remediation of industrial water pollution has courted intense attention lately due to its touted green approach. In this respect, Keggin-based polyoxometalates (POMs) as green solid acids in photocatalytic reaction possess superior qualities, viz. unique photoinduced charge-transfer properties, strong photooxidative-photoreductive ability, high chemical and thermal stability, and so forth. Unfortunately, it suffers from a large bandgap energy, low specific surface area, low recoverability, and scarce utilization in narrow absorption range. Therefore, the pollutant degradation performance is not satisfactory. Consequently, multifarious research to enhance the photocatalytic performance of Keggin-based POMs were reported, viz. via novel modifications and functionalizations through a variety of materials, inclusive of, inter alia, metal oxides, transition metals, noble metals, and others. In order to advocate this emerging technology, current review work provides a systematic overview on recent advancement, initiated from the strategized synthetic methods, followed by hierarchical enhancement and intensification process, at the same time emphasizes on the fundamental working principles of Keggin-based POM nanocomposites. By reviewing and summarizing the efforts adopted global-wide, this review is ended with providing useful outlooks for future studies. It is also anticipated to shed light on producing Keggin-based POM nanocomposites with breakthrough visible- and solar-light-driven photocatalytic performance against recalcitrant organic waste.Trace elements and heavy metals concentrate in aquatic sediments, potentially endangering benthic organisms. Comparing the concentration of metals in different aquatic bodies will help evaluate their accumulation and distribution characteristics within these systems. Metal pollution and enrichment indices in sediments from diverse aquatic systems in Southern USA, including agricultural ponds, man-made reservoir, river, swamp, and coastal environment were investigated. Following total digestion of the sediments, the concentrations of chromium (Cr), cobalt (Co), copper (Cu), zinc (Zn), arsenic (As), selenium (Se), cadmium (Cd), antimony (Sb), lead (Pb), and uranium (U) were measured using inductively coupled plasma-mass spectrometry (ICP-MS). Pb was found to be highly enriched in the sediment samples from all five environments. The samples from coastal and agricultural ponds showed highest degree of anthropogenic modification (enrichment factor &gt;10), especially with Se, U, and Pb. Agricultural ponds, previously unknown as a metal hotspot, had the most deteriorated sediment quality as determined by high pollution load index (&gt;1) and contamination factor (&gt;6) for Cd and U.