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Rational excogitation of microstructure and chemical constituents is a superior means of constructing electromagnetic wave (EMW) absorption materials with high performance. [https://www.selleckchem.com/products/r428.html Bemcentinib mw] In this study, a kind of honeycomb-like NiFe2O4@Ni@C composite is prepared via an uncomplicated polymerization, pyrolysis and etching. Porous structure and internal cavity of NiFe2O4@Ni@C contribute to the numerous reflection and scattering of EMW. The strong ferromagnetic resonance of NiFe2O4 core and the multiple relaxation processes of porous carbon shell strongly promote the EMW loss. Additionally, the synergistic effect can improve impedance matching. The results demonstrate that the minimum reflection loss (RL) of honeycomb-like NiFe2O4@Ni@C composites is -65.33 dB at 13.63 GHz. The effective absorption bandwidth (EAB) is 3.68 GHz when the matching thickness is 4.95 mm. The mechanism of EMW dissipation of the honeycomb-like NiFe2O4@Ni@C composites is attributed to multiple reflections and scattering, conductive loss, interfacial polarization and ferromagnetism resonance. This work provides a tactic for the excogitation and synthesis of a low cost, light weight and efficient EMW absorber.Magnetic graphene foams with three-dimensional (3D) porous structure, low bulk density and multiple electromagnetic loss mechanisms have been widely recognized as the potential candidates for lightweight and high-efficiency microwave attenuation. Herein, zinc ferrite hollow microspheres decorated nitrogen-doped reduced graphene oxide (NRGO/ZnFe2O4) composite foams were prepared via a solvothermal and hydrothermal two-step method. Results demonstrated that the attained magnetic composite foams possessed the ultralow bulk density (12.9-13.5 mg·cm-3) and 3D hierarchical porous netlike structure constructed through stacking of lamellar NRGO. Moreover, the microwave dissipation performance of binary composite foams could be notably improved through annealing treatment and further elaborately regulating the annealing temperature. Remarkably, the attained composite foam with the annealing temperature of 300.0 °C presented the integrated excellent microwave attenuation capacity, i.e. the strongest reflection loss reached -40.2 dB (larger than 99.99% absorption) and broadest bandwidth achieved 5.4 GHz (from 12.4 GHz to 17.8 GHz, covering 90.0% of Ku-band) under an ultrathin thickness of only 1.48 mm. Furthermore, the probable microwave dissipation mechanisms were illuminated, which derived from the optimized impedance matching, strengthened dipole polarization, interfacial polarization and multiple reflection, notable conduction loss, natural resonance and eddy current loss. Results of this work would pave the way for developing graphene-based 3D lightweight and high-efficiency microwave absorption composites.Current technologies for removal of Cr(VI) are generally fit for acidic wastewater. In this study, a new ferrite process for removal and recycling of Cr(VI) from alkaline wastewater to produce the valuable chromium ferrite has been developed. The results show that this new ferrite method is a one-step process which can be divided into two successive reactions including Cr(VI) reduction to form coprecipitation (Cr0.25Fe0.75(OH)3) and subsequently magnetic conversion of Cr0.25Fe0.75(OH)3 induced by Fe2+ under the same alkaline condition. The total Fe/Cr mole ratio of 51 is at least required for the chromium ferrite transformation. Increasing temperature and pH can enhance the interaction of Fe2+ with Cr0.25Fe0.75(OH)3 and further promote the formation of chromium ferrite, while suppressing the generation of nonmagnetic by-product goethite. Almost pure chromium ferrite is formed under proposed optimum conditions (Fe/Cr = 71, 65 °C and pH of 9) with Cr(VI) removal ratio around 100%. The Cr(VI) remained in the filtrate can be reduced to 0.01 mg/L which is much lower than the limits concentration for surface water (≤0.05 mg/L). The chromium ferrite product whose molecular formula can be expressed as Cr0.5-xFe2.5+xO4 (where 0 ≤ x less then 0.5) presents good magnetic properties and has the potential to be recycled as a useful material.Constructing floating photocatalysts with highly efficient visible-light utilization is a promising approach for practical photocatalytic wastewater treatment. In this study, we anchored bismuth oxybromo-iodide (BiOBrxI1-x (0 ≤ x ≤ 1)) on flexible electrospun polyacrylonitrile (PAN) nanofiber mats to create BiOBrxI1-x@PAN nanofibers with tunable light absorption properties as floating photocatalysts at room temperature. As x increased, the photocatalytic activity of the BiOBrxI1-x@PAN nanofibers with similar loading content initially increased, and then decreased, for the degradation of bisphenol A (BPA) and methyl orange (MO) under visible-light irradiation (λ &gt; 420 nm) conditions. The BiOBrxI1-x@PAN (0 less then x less then 1) nanofibers exhibited better photocatalytic performance compared to the BiOBr@PAN and BiOI@PAN nanofibers. Under visible-light irradiation, the BPA degradation rate of the BiOBr0.5I0.5@PAN nanofibers was 1.9 times higher than that of the BiOI@PAN nanofibers, while the BiOBr@PAN nan visible light during the photocatalytic reaction. link2 Therefore, these solid-solution-based floatable nanofiber photocatalysts are good potential candidates for wastewater treatment applications.Rechargeable aqueous zinc-ion batteries (RAZIBs) have received increasing attention due to cost-effectiveness and inherent safety. A wide variety of advanced cathode materials have been revealed with promising performance in RAZIBs. However, these materials usually require sophisticated procedures at high temperatures, which greatly limit further practical application. Herein, a chimie douce approach is adopted to prepare vanadium oxides from V2O5 suspension with the addition of various transition metal cations (Mn2+, Zn2+, Ag+, and Fe3+) by simple liquid-solid mixing under ambient conditions. For the cases of Mn2+ and Zn2+, the dissolution-recrystallization process takes place leading to layered Mn0.31V3O7·1.40H2O (MnVO) and Zn0.32V3O7·1.52H2O (ZnVO). The use of Ag+ forms tunneled Ag0.33V2O5 (AgVO), and the present of Fe3+ stays mainly unreacted V2O5. The underlying reaction chemistries are proposed, for which the pH values of precursor solutions are found to be a key factor. Among the prepared materials, layered vanadium oxides exhibit promising battery performance. Particularly, MnVO delivers 340 and 217 mAh g-1 at 1 and 8 A g-1, respectively. A specific capacity of 164 mAh g-1 can be retained after 500 cycles at 1 A g-1. By contrast, AgVO and FeVO demonstrate inferior performance with retaining only 89 and 20 mAh g-1 after 500 cycles.Rapid heat loss and fast charge carrier recombination constitute two crucial issues that hinder the development of efficient solar energy utilization and conversion over the semiconductor in a photothermal catalytic system. Inspired by energy production from waste water, we designed an advanced 3D C@TiO2 multishell nanoframe (MNF) photocatalyst. Its unique structural features of heat confinement and vibrant photocarrier kinetics lead to excellent photo-thermal conversion for synchronous superior photocatalytic H2 evolution (503 μmol g-1h-1) and 98.2% RhB removal without the use of any co-catalyst and sacrificial reagent under simulated sunlight irradiation (AM 1.5G). Mechanism exploration reveals that the difference between the inner and outer gas pressure formed inside C@TiO2 precursor facilitates the selective cleavage of outer TiO2 layers at selected temperatures during calcination. Synergistic effects between residual carbon core and multi-shelled TiO2 framework endow C@TiO2 MNF with excellent heat confinement and vibrant photocarrier kinetics. Such MNF photo-thermocatalyst concept provides a novel strategy for effective utilization of solar energy, and this work may open a novel avenue towards advanced nanostructures for efficient waste-to-energy conversion.P-nitrophenol (PNP), a widely used compound, is harmful to the environment and human health. In this study, four iron-based Prussian blue analogs (PBAs) were prepared by coprecipitation (Co-Fe PBA, Mn-Fe PBA, Cu-Fe PBA and Fe-Fe PBA). The Co-Fe PBA exhibited high peroxymonosulfate (PMS) activation performance for PNP degradation, removing over 90% of PNP in 60 min at an optimal pH of 7, temperature at 30 ℃, initial concentration of 20 mg/L, PBA dose of 0.2 g/L and PMS dose of 1 g/L. The physicochemical properties of the Co-Fe PBA were investigated by various characterization methods. link3 The catalytic activity of PBA and the influence of various process parameters and water quality on the catalytic reaction were investigated to elucidate the mechanism of p-nitrophenol degradation by PBA-activated persulfate. Moreover, the mechanism of accelerated degradation of PNP under HCO3- conditions and the role of major reactive oxides were determined by EPR measurement methods and free radical trapping experiments. HCO3- was found to directly activate PMS to produce reactive oxygen species, and 1O2, ∙OH and SO4∙- were all greatly increased. This work presents a promising green heterogeneous catalyst for the degradation of emerging contaminants (ECs) in real wastewater with natural organic matter and coexisting anions by PMS activation.A wide range of organic pollutants in industrial effluents, agricultural runoff, and domestic discharges are exacerbating water scarcity, leading to water-borne ailments, and adversely affecting the marine ecosystem and biodiversity. The efficient, sustainable, and cost-effective materials need to be addressed urgently for the removal of organic pollutants. Herein, ultra-light (0.018 g.cm-3) and highly porous (96.4%) composite aerogel is prepared by gelatinization of graphene oxide with fruit waste-derived cellulose. The macroscopic porosity generated by interconnecting cellulosic skeleton and graphene oxide sheets via hydrogen bonding network provided ample avenues for transport and diffusion of organic dyes-enriched wastewater throughout the cellulose-graphene oxide composite aerogel (CGA). Consequently, organic dyes are efficiently adsorbed by easily accessible surface sites distributed throughout the CGA. The size, charge, and chemical structure of organic dyes along with textural features and accessible surface active sites of CGA governed the adsorption process. The spectroscopic analyses based on FTIR, Raman, and XPS measurements suggest electrostatic, n-π, π-π, cation-π interactions, dipole-dipole hydrogen, and Yoshida hydrogen linkages as major interactive pathways for the adsorption of organic dyes by the CGA. Moreover, the composite aerogel furnished an excellent recyclability for the adsorptive removal of organic pollutants from wastewater. The present work promises the potential of 2D nanostructured layered materials and fruit-waste-derived composite aerogels for sustainable utilization in wastewater treatment, which can be an excellent step towards water security.<br /><br /> The dynamics of colloidal suspension confined within porous materials strongly differs from that in the bulk. In particular, within porous materials, the presence of boundaries with complex shapes entangles the longitudinal and transverse degrees of freedom inducing a coupling between the transport of the suspension and the density inhomogeneities induced by the walls.<br /><br /> Colloidal suspension confined within model porous media are characterized by means of active microrheology where a net force is applied on a single colloid (tracer particle) whose transport properties are then studied. The trajectories provided by active microrheology are exploited to determine the local transport coefficients. In order to asses the role of the colloid-colloid interactions we compare the case of a tracer embedded in a colloidal suspension to the case of a tracer suspended in an ideal bath.<br /><br /> Our results show that the friction coefficient increases and the passage time distribution widens upon increasing the corrugation of the channel.