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Passivation is one of the most promising concepts to heal defects created at the surface and grain boundaries of polycrystalline perovskite thin films, which significantly deteriorate the photovoltaic performance and stability of corresponding devices. Here, 1,10-phenanthroline, known as a bidentate chelating ligand, is implemented between the methylammonium lead iodide (MAPbI3) film and the hole-transport layer for both passivating the lead-based surface defects (undercoordinated lead ions) and converting the excess/unreacted lead iodide (PbI2) buried at interfaces, which is problematic for the long-term stability, into "neutralized" and beneficial species (PbI2(1,10-phen)x, x = 1, 2) for efficient hole transfer at the modified interface. The defect healing ability of 1,10-phenanthroline is verified with a set of complementary techniques including photoluminescence (steady-state and time-resolved), space-charge-limited current (SCLC) measurements, light intensity dependent JV measurements, and Fourier-transform photocurrent spectroscopy (FTPS). In addition to these analytical methods, we employ advanced X-ray scattering techniques, nano-Fourier transform infrared (nano-FTIR) spectroscopy, and high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) to further analyze the structure and chemical composition at the perovskite surface after treatment at nanoscale spatial resolution. On the basis of our experimental results, we conclude that 1,10-phenanthroline treatment induces the formation of different morphologies with distinct chemical compositions on the surface of the perovskite film such that surface defects are effectively passivated, and excess/unreacted PbI2 is converted into beneficial complex species at the modified interface. As a result, an improved power conversion efficiency (20.16%) and significantly more stable unencapsulated perovskite solar cells are obtained with the 1,10-phenanthroline treatment compared to the MAPbI3 reference device (18.03%).Na-ion batteries (NIBs) have been considered as potential candidates for large-scale energy storage, where O3-type Na-based layered oxide cathodes have attracted great attention due to their high capacity and low cost. However, O3-NaxTMO2 materials still suffer from insufficient air stability, which could lead to deteriorative electrochemical properties and thus hinder their practical application. In this work, a series of Al-doped O3-NaFe(1/3-x)Ni1/3Mn1/3AlxO2 cathodes prepared by a co-precipitation method were investigated to enhance their electrochemical performance and air stability through stabilizing their structural and interface chemical properties. The Al-doped O3-NaFe(1/3-0.01)Ni1/3Mn1/3Al0.01O2 (NFNMA0.01) cathode delivers a comparable capacity of 138 mAh g-1 and keeps a capacity retention of 85.88% after 50 cycles at 0.2 C, while the undoped O3-NaFe1/3Ni1/3Mn1/3O2 (NFNM) can only keep a capacity retention of 71.02%, although with an initial capacity of 141 mAh g-1 at 0.2 C. For the air stability, the capacity decay rates are 58.87 and 5.07% for the undoped NFNM and Al-doped NFNMA0.01 after the air exposure for 30 days, respectively. The greatly decaying electrochemical performance could be due to the formation of carbonates during air exposure, which can be efficiently suppressed by Al doping. The doped Al3+ has been confirmed to be inserted into the NFNM crystal lattice, inducing the reduced values of lattice parameters a and c due to the smaller ionic radius of Al3+ (53.5 pm) vs Fe3+ (55.0 pm). This study demonstrates that Al doping plays an important role in the air stability and cycling stability for layered cathode materials, which offers an efficient strategy to optimize the material design for their practical application in NIBs.In this work, photothermal materials are integrated with a temperature-sensitive hydrogel and structural color for visually detecting solar intensity. Inspired by the functional performance of beetles, the photothermal layer is constructed by depositing candle soot on a film of Cu nanoparticles, while the temperature-sensitive colored hydrogel is fabricated by self-assembling colloidal photonic crystals on poly(N-isopropylacrylamide) (PNiPAM). [https://www.selleckchem.com/products/fps-zm1.html buy FPS-ZM1] The deposition of candle soot not only improves the photothermal performance but also leads to a superhydrophobic surface with a self-cleaning function. The photothermal layer absorbs sunlight and converts it into heat, which is then transferred to the hydrogel. The structural color of the hydrogel changes due to the heat-induced volume shrinkage. As the solar intensity increases from 0.62 to 1.27 kW/m2, the structural color conspicuously changes from red to orange, yellow, green, cyan, and blue, with reflection peaks shifting from 640 to 460 nm accordingly. The color change is highly apparent, which can be easily observed by the naked eye, suggesting that the solar intensity can be easily detected by reading out the structural color. This power-free and self-cleaning solar sensor can work for a long period without maintenance, which is suitable for a wide application prospect, such as smart home and agriculture.The development of appropriate methods to correlate the structure and optical properties of colloidal photonic structures is still a challenge. Structural information is mostly obtained by electron, X-ray, or optical microscopy methods and X-ray diffraction, while bulk spectroscopic methods and low resolution bright-field microscopy are used for optical characterization. Here, we describe the use of reflectance confocal microscopy as a simple and intuitive technique to provide a direct correlation between the ordered/disordered structural morphology of colloidal crystals and glasses, and their corresponding optical properties.<br /><br /> Lots of research has been conducted to fight COVID-19 since the outbreak of the pandemic in 2020. The role of 'cytokine storm' in the pathogenesis of COVID-19 pneumonia is well known. Relationship between interleukins and depression is still subject matter of the research, but a correlation between interleukin-6 and depressive disorders is proven by now. The aim of this study is to verify differences among interleukin-6 blood levels of inpatients treated with SSRI and/or SNRI before and during hospitalization and of inpatients not treated with these drugs.<br /><br /> This is an observational study performed during the first wave of SARS Cov-2 pandemic in Italy for three months. The hospitalized patients of Internal Medicine wards and Infectious and Tropical Diseases ward of Azienda Ospedaliero-Universitaria Careggi of Florence for COVID-19 pneumonia have been divided into two subgroups (treated / not treated with antidepressants). Patients admitted to Intensive Care Unit previously have been excluded. Each patient has been evaluated concerning demographic, clinical and therapeutic features.