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In addition to safety and risk issues, urban resilience research should focus more comprehensive and universal contradictions. Considering the main contradictions of Chinese urban development, and the connotation of urban resilience, a theoretical framework is constructed based on the contradiction between supply and demand of the daily activity-environment system. Furthermore, an assessment index system of urban resilience is also developed that considers both volume and quality of demand and supply and has a grade standard. Finally, utilizing multi-source geographic big data, Nanjing is taken as a case study, the spatial characteristics and optimization path of urban resilience are identified. The main conclusions are as follows (1) The activity-environment system resilience presents a "center-periphery" sprawling spatial structure, and it is mainly at the level of "reluctant resilience" and "almost lack of resilience". (2) The evolution of the activity-environment system resilience is still absolutely volume driven, and the positive drive of relative quality is limited or even reversed. In addition, all the bilateral local spatial autocorrelations are generally represented as "center-periphery" separated spatial structures, but it is not always consistent with the overall trend. (3) For the governance of urban resilience, it is necessary to focus on common improvement and matching of absolute volume and relative quality in contents, orderly flow, accumulation and dispersion of supply and demand in ideas, and the strong support of new ideas and technologies in methods.Ionic liquids (ILs) become emerging pollutants and their toxicities earn increasing attentions. Yet, their effects were seldom explored on reproduction which connects generations and also effects across generations. In the present study, reproductive effects of 1-ethyl-3-methylimidazolium bromide ([C2mim]Br), one representative IL, were studied on C. elegans with 11 continuously exposed generations (F1 to F11). At 8.20E-5 g/L, the effects on the initial reproduction showed oscillatory changes between stimulation (in F1, F3, F4, F6 and F10) and inhibition (in F2, F5, F7, F8 and F11). At 8.20E-3 g/L, the effects on the reproduction over generations also showed such oscillation despite of different stimulation or inhibition levels, and even opposite influences in F4 and F11. The effects of [C2mim]Br on the total reproduction also showed the concentration-dependent oscillation between stimulation and inhibition over generations, though they had less alteration frequencies than those on the initial reproduction. Biochemical and molecular indicators were further measured in F1, F4, F7 and F11 to explore potential mechanisms. Results showed that the effects on spermatocyte protein 8 (SPE8) showed positive correlation with those on reproduction while the influences on major sperm protein (MSP) and sperm transmembrane protein 9 (SPE9) showed negative correlation with SPE8. Moreover, the dysregulation on expressions of acs-2 and akt-1 indicated the involvement of glucolipid metabolism. The changes in expressions of set-2, met-2, set-25 and mes-4 demonstrated that the long-term reproductive impacts of [C2mim]Br over generations also involved histone methylation at H3K4, H3K9 and H3K36, which also connected with the glucolipid metabolism.The lack of long-term observations and satellite retrievals of health-damaging fine particulate matter in China has demanded the estimates of historical PM2.5 (particulate matter less than 2.5 μm in diameter) concentrations. This study constructs a gridded near-surface PM2.5 concentration dataset across China covering 1980-2019 using the space-time random forest model with atmospheric visibility observations and other auxiliary data. The modeled daily PM2.5 concentrations are in excellent agreement with ground measurements, with a coefficient of determination of 0.95 and mean relative error of 12%. Besides the atmospheric visibility which explains 30% of total importance of variables in the model, emissions and meteorological conditions are also key factors affecting PM2.5 predictions. [https://www.selleckchem.com/products/fgf401.html FGFR inhibitor] From 1980 to 2014, the model-predicted PM2.5 concentrations increased constantly with the maximum growth rate of 5-10 μg/m3/decade over eastern China. Due to the clean air actions, PM2.5 concentrations have decreased effectively at a rate over 50 μg/m3/decade in the North China Plain and 20-50 μg/m3/decade over many regions of China during 2014-2019. The newly generated dataset of 1-degree gridded PM2.5 concentrations for the past 40 years across China provides a useful means for investigating interannual and decadal environmental and climate impacts related to aerosols.In this study, the photogeneration of OH and 1O2 and the degradation mechanism of organic pollutants in biochar suspension under the simulated solar light irradiations were investigated. Biochar derived from rice husk with 550 °C of charring temperature (R550) was selected to degrade benzoic acid. It was found that 10 g/L of R550 could degrade 78.7% of benzoic acid within 360 min at pH 3, and the degradation efficiency was promoted to 95.2% as ultraviolet (UV) presented. By checking the production of p-hydroxybenzoic acid, UV accelerated the production of OH, which was confirmed by the enhanced degradation efficiency of 59.2% caused by the evaluated OH as UV appeared. The furfuryl alcohol loss in the R550 suspension under light irradiations testified to the production of 1O2, which contributed to 9.3% of benzoic acid degradation. Oxidization treatment using gradient concentrations of H2O2 was employed to enhance the ageing process of biochar. As the ageing processed, the biochar possessed a declined performance towards OH production from O2 activation and the radical degradation of organic pollutants. As a contrast, the evaluated content of 1O2 and enhanced non-radical degradation of organic pollutants was reached as UV presented. The further study indicated that phenolic hydroxyl groups on biochar facilitated the production of OH via the electron transfer, and quinone like structures (C=O) on biochar boosted the generation of 1O2 via the energy transfer. Moreover, upon eliminating the BA degradation, persistent free radicals were formed on biochar, which was enhanced owing to the presence of UV.