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Both the amount and intensity of rainfall positively influenced TSS concentrations in runoff regardless of land use. Using the collected data, this study developed a generic equation for predicting the loading of a pollutant as a function of rainfall depth. This equation was verified by comparing its predictions with the simulations of a sufficiently-calibrated water quality model in terms of TSS, TP, and TN loadings from various land uses in another coastal catchment for a period of ten years. Average TSS, TN, and TP loadings from the catchment were estimated to be 0.86, 0.03, and 0.01 kg ha-1 cm-1, respectively.Cabled observatories are marine infrastructures equipped with biogeochemical and oceanographic sensors as well as High-Definition video and audio equipment, hence providing unprecedented opportunities to study marine biotic and abiotic components. Additionally, non-invasive monitoring approaches such as environmental DNA (eDNA) metabarcoding have further enhanced the ability to characterize marine life. Although the use of non-invasive tools beholds great potential for the sustainable monitoring of biodiversity and declining natural resources, such techniques are rarely used in parallel and understanding their limitations is challenging. Thus, this study combined Underwater Video (UV) with eDNA metabarcoding data to produce marine fish community profiles over a 2 months period in situ at a cabled observatory in the northeast Atlantic (SmartBay Ireland). By combining both approaches, an increased number of fish could be identified to the species level (total of 22 species), including ecologically and economically important species such as Atlantic cod, whiting, mackerel and monkfish. The eDNA approach alone successfully identified a higher number of species (59%) compared to the UV approach (18%), whereby 23% of species were detected by both methods. The parallel implementation of point collection eDNA and time series UV data not only confirmed expectations of the corroborative effect of using multiple disciplines in fish community composition, but also enabled the assessment of limitations intrinsic to each technique including the identification of false-negative detections in one sampling technology relative to the other. This work showcased the usefulness of cabled observatories as key platforms for in situ empirical assessment of both challenges and prospects of novel technologies in aid to future monitoring of marine life.Dimethyl disulfide (DMDS), a soil fumigant, is an effective, broad-spectrum compound that often replaces bromomethane (MB) in the prevention and treatment of soil-borne diseases. However, the disadvantages of DMDS include toxicity, volatility, pungent odor, risk of human exposure, and environmental pollution. Cyclodextrin (CD) has been widely used as a carrier of chemicals in many industries due to its functional advantages and safety. In this study, a DMDS-controlled release formulation was developed by encapsulating DMDS in the cavity of 2-hydroxypropyl-β-cyclodextrin (HP-β-CD). This formulation reduced DMDS usage and production costs. Orthogonal experimental design, Fourier transform infrared (FT-IR), Scanning electron microscopy (SEM), Thermal gravity analysis (TGA) characterization, efficacy comparison, safety, and other aspects of the evaluation showed that under the best preparation conditions, the encapsulation rate was 81.49%. The efficacy of DMDS@HP-β-CD was similar to unformulated DMDS. The efficacy duration of the formulation was about two times longer than DMDS, and it was safer to use. This study reveals a cyclodextrin-DMDS formulation with reduced toxicity, longer duration, environmental safety and sustainability.The atmospheric oxidation capacity (AOC) and photochemical reactivity are of increasing concern owing to their roles in photochemical pollution. The AOC and OH reactivity were evaluated based on simultaneous measurements of volatile organic compounds (VOCs), trace gases and photolysis frequency during summer and winter campaigns at a suburban site in Xianghe. The AOC exhibited well-defined seasonal and diurnal patterns, with higher intensities during the summertime and daytime than during the wintertime and nighttime, respectively. The major reductants contributing to the AOC during the summertime were CO (41%) and alkenes (41%), whereas CO (40%) and oxygenated VOCs (OVOCs) (30%) dominated the AOC during the wintertime. The dominant oxidant contributor to the AOC during the daytime was OH (≥93%), while the contributions of O3 and NO3 (≥75%) to the AOC increased during the nighttime. High values during the wintertime and an increase at night were features of the speciated OH reactivity. Inorganic compounds (NOarities and differences in the AOC and speciated OH reactivity during summer and winter campaigns.Converging data would indicate the existence of possible relationships between climate change, environmental pollution and epidemics/pandemics, such as the current one due to SARS-CoV-2 virus. Each of these phenomena has been supposed to provoke detrimental effects on mental health. Therefore, the purpose of this paper was to review the available scientific literature on these variables in order to suggest and comment on their eventual synergistic effects on mental health. The available literature report that climate change, air pollution and COVID-19 pandemic might influence mental health, with disturbances ranging from mild negative emotional responses to full-blown psychiatric conditions, specifically, anxiety and depression, stress/trauma-related disorders, and substance abuse. The most vulnerable groups include elderly, children, women, people with pre-existing health problems especially mental illnesses, subjects taking some types of medication including psychotropic drugs, individuals with low socio-economic status, and immigrants. [https://www.selleckchem.com/products/GDC-0941.html Pictilisib concentration] It is evident that COVID-19 pandemic uncovers all the fragility and weakness of our ecosystem, and inability to protect ourselves from pollutants. Again, it underlines our faults and neglect towards disasters deriving from climate change or pollution, or the consequences of human activities irrespective of natural habitats and constantly increasing the probability of spillover of viruses from animals to humans. In conclusion, the psychological/psychiatric consequences of COVID-19 pandemic, that currently seem unavoidable, represent a sharp cue of our misconception and indifference towards the links between our behaviour and their influence on the "health" of our planet and of ourselves. It is time to move towards a deeper understanding of these relationships, not only for our survival, but for the maintenance of that balance among man, animals and environment at the basis of life in earth, otherwise there will be no future.In the recent decades, the role of wastewater treatment plants has been entrenched for the dissemination of antibiotic resistant bacteria into the environment. The present study explores the dynamics of earthworms-microorganisms interactions involved in the high treatment efficacy of vermifiltration technology along with reduction of antibiotic resistant bacteria (ARB). This study is the first of its kind to investigate the performance efficacy of vermifilter (VF) for clinical laboratory wastewater treatment. The results of the study showed that earthworms and VF associated microbial community had a significant effect on Biochemical Oxygen Demand (BOD) and Chemical Oxygen Demand (COD) reduction (78-85%), coliforms and pathogen removal (&gt;99.9%) and caused a significant shift in the prevalence pattern of ARB. Molecular profiling of resistance causing genes such as ESBL (blaSHV, blaTEM and blaCTX-M), MRSA (mec-A) and Colistin (mcr-1) confirmed the probable mechanisms behind the resistance pattern. The microbial community diversity in the influent, earthworm's coelomic fluid and gut and filter media layers associated with the VF assists in the formation of biofilm, which helps in the removal of pathogens from the wastewater. This biofilm formation further results in a paradigm shift in the resistance profile of ARB and ARG, specifically most effective against drugs, targeting cell wall and protein synthesis inhibition such as Ampicillin, Ticarcillin, Gentamicin and Chloramphenicol. These findings further validate vermifiltration technology as a sustainable and natural treatment technology for clinical laboratory wastewater, specifically for the removal of pathogens and antibiotic resistance.Emission factors (EFs) are crucial for establishing emission inventory and subsequent health risk assessment of pollutants. However, the EFs of environmentally persistent free radicals (EPFRs) in PM2.5 have not been well investigated. We measured EPFRs in PM2.5 from burning of different solid fuels in a traditional stove widely used in rural China and calculated the EFs of EPFRs (EFEPFRs). The characteristics of EPFRs varied greatly with PM2.5 depending on the feedstock, and the EFEPFRs of crop residue, firewood and bitumite was 2.13 ± 1.04, 1.40 ± 0.76 and 1.08 ± 0.39 (1020 spins·kg-1), respectively. The estimated results of EPFRs emission associated with PM2.5 showed that the crop residue was the main contributor to the top four provinces with high EPFRs emissions in China in 2010. A wide range (0.03-4.89 cig·person-1·day-1) of equivalent cigarette number converted by inhaling EPFRs in PM2.5 was observed. Provinces with higher equivalent cigarette number were mainly agricultural provinces, because the rural residents tend to use readily available fuels. Additionally, EPFRs in collected PM2.5 during 2 - month photoaging were more stable in particles with higher organic carbon contents. Our findings provided a new insight into the risk assessment of PM2.5 from different sources by taking EPFRs into consideration.Air quality is one of the major issues within an urban area that affect people's living environment and health conditions. Existing observations are not adequate to provide a spatiotemporally comprehensive air quality information for vulnerable populations to plan ahead. Launched in 2017, TROPOspheric Monitoring Instrument (TROPOMI) provides a high spatial resolution (~5 km) tropospheric air quality measurement that captures the spatial variability of air pollution, but still limited by its daily overpass in the temporal dimension and relatively short historical records. Integrating with the hourly available AirNOW observations by ground-level discrete stations, we proposed and compared two deep learning methods that learn the relationship between the ground-level nitrogen dioxide (NO2) observation from AirNOW and the tropospheric NO2 column density from TROPOMI to downscale the daily NO2 to an hourly resolution. The input predictors include the locations of AirNOW stations, AirNOW NO2 observations, boundary layer height, other meteorological status, elevation, major roads, and power plants. The learned relationship can be used to produce NO2 emission estimates at the sub-urban scale on an hourly basis. The two methods include 1) an integrated method between inverse weighted distance and a feed forward neural network (IDW + DNN), and 2) a deep matrix network (DMN) that maps the discrete AirNOW observations directly to the distribution of TROPOMI observations. We further compared the accuracies of both models using different configurations of input predictors and validated their average Root Mean Squared Error (RMSE), average Mean Absolute Error (MAE) and the spatial distribution of errors. Results show that DMN generates more reliable NO2 estimates and captures a better spatial distribution of NO2 concentrations than the IDW + DNN model.